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List of Undesirable Substances

O

Organo-tin compounds

 

Organo-tin compounds

 
Product groups: Paints
PVC
Anti-fouling products
Impregnated wood
Reason for selection: Problematical substances in the waste cycle.
High priority in the marine environment.
Goals: High priority is assigned to special action on these substances.
Restrictions on these substances are desired because of the concentrations found, and because of their impact on the health and the environment in connection with the use of residuals, such as slags, compost and sludge.
Restrictions on these substances are desired because of their harmful effects on the health and/or the environment. No knowledge of substitution alternatives is available for certain areas of application, and work is needed to find technically and economically feasible alternatives in the future.
Classification /37/: Bis(tris(2-methyl-2-phenylpropyl)tin) oxide: harmful to the health (R21) and local irritatant (R36/38).
Cyhexatin (trichlohexyltin hydroxide): harmful to the health (R20/21/22).
Tin(II) methane sulphonate: sensitising (R43), harmful to the health (R22) and corrosive (R34).
Tributyltin compounds: harmful to the health (R21), toxic (R25-48/23/25) and local irritatant (R36/38).
Tricyclohexyltin hydroxide: harmful to the health (R20/21/22).
Tricyclohexyltin compounds, miscellaneous: harmful to the health (R20/21/22) down to 1%.
Triethyltin compounds: very toxic (R26/27/28) harmful to the health down to 0.05%.
Trihexyltin compounds: harmful to the health (R20/21/22) down to 1%.
Trimethyltin compounds: very toxic (R26/27/28), harmful to the health down to 0.05%.
Trioctyltin compounds: local irritatant (R36/37/38) down to 1%.
Tripentyltin compounds: harmful to the health (R20/21/22) down to 1%.
Triphenyltin acetate: very toxic (R26), toxic (R24/25), local irritatant (R36/38), sensitising (R43) and harmful to the environment (R50/53).
Triphenyltin compounds, miscellaneous: toxic (R23/24/25), harmful to the health down to 0.025%.
Tripropyltin compounds, miscellaneous: toxic (R23/24/25). Harmful to the health down to 0.1%.
Present regulation: Restrictions on use: /34/, /40/, /41/
Quality criteria/limit values: /12/, /17/, /39/
Working environment: /2/, /8/, /9/
Miscellaneous:
Activities: Organic tin is included in the proposal for the revised national surveillance programme for the aquatic environment, in the following media: selected industrial effluents and groundwater.
The project on the environmental impact of organo-tin compounds in connection with anti-fouling paints on ships has been started. Expected date of completion: 1998.
Environmental assessment of organo-tin compounds as an extension of mass stream analysis.
Prohibition or restrictions on the use of bis(tributyltin) oxide (CAS No. 56-35-9) are under consideration in the EU.
 

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