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List of undesirable substances 2000 5. List of Undesirable Substances5.1 Alkylphenols, e.g. nonylphenol, octylphenolCAS Nos. Product groups: Lubricant oils/products Reason for selection: Adverse effects in the aquatic environment. Goals: Restrictions on these substances are desired because of their concentrations found in and their impact on the environment, in connection with the use of residuals, such as sludge. Classification: Present regulation: /4/ (Danish EPA Statutory Order on detergents and cleaning products), /16/ (Danish EPA Statutory Order on Classification, etc.), /25/ (EU Dir. on restriction of the marketing and use of certain dangerous products) Quality criteria/limit values: /3/ (Danish EPA Statutory Order on waste products intended for agricultural purposes), /29/ (Plant Department, on the inspection of waste-water sludge) Working environment: Miscellaneous regulations: /6/ (European Commission on high-priority substances), /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /120/ (Danish EPA Statutory Order on ships' stowage logs), /134/ (Water Framework Directive), /64/ (Danish EPA guideline on tannery sites), /65/, (Danish EPA guideline on boring control at waterworks), /135/ (Danish EPA guideline on soil analyses), /136/ (HELCOM) Activities: Risk assessments of nonylphenol and nonylphenolethoxylates have been carried out in the EU. A risk reduction strategy is being drafted. Reporting state: England. A draft for an EU Directive is being prepared. Work is in progress in OSPAR on initiatives aimed at reducing discharges and losses of nonylphenol, with a view to reducing their presence in marine areas to concentrations close to zero before 2020 /57/. Nonylphenol is included in the national programme for monitoring of the aquatic environment 1998-2003, also called NOVA 2003 /20/. Octylphenol (CAS No. 27193-28-8) is included in the national programme for monitoring of the aquatic environment 1998-2003, also called NOVA 2003 /20/. Mapping the occurrence and fate of a selected substance (nonylphenol) in all media of the environment within a geographically demarcated area. National Environmental Research Institute project on substances alien to the environment. Expected date of completion: 2000. A strategic plan for phase-out expected to be ready during 2000. Projects concerned with the development of alternatives to the use of alkylphenols in chemical products within the field of painting and building materials are in progress. These projects receive funding from the Cleaner Products Support Programme, etc., (Danish EPA). 5.2 Alkylphenol ethoxylates, e.g. nonylphenol ethoxylate, octylphenol ethoxylateCAS Nos.: Product groups: Paints and varnishes Cosmetics Ancillary substances in pesticides Reason for selection: Hazardous to the aquatic environment. Goals: Restrictions on these substances are desired because of their concentrations found in and their impact on the environment, in connection with the use of residuals, such as sludge. Classification: Present regulation: /4/ (Danish EPA Statutory Order on detergents and cleaning products), /8/ (European Commission on ecolabels for textile products), /9/ (European Commission on ecolabels for bed linen and T-shirts), /10/ (European Commission on ecolabels for detergents), /11/ (voluntary agreement between the Danish EPA and the Association of Danish Cosmetics, Toiletries, Soap and Detergent Industries), /116/ (Danish EPA Statutory Order on sludge etc., for agriculture) Quality criteria/limit values: /3/ (Danish EPA Statutory Order on waste products intended for agricultural purposes), /29/ (Plant Department, on the inspection of waste-water sludge) Working environment: Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM). Activities: Risk assessments of nonylphenol and nonylphenol ethoxylates have been carried out in the EU. A risk reduction strategy is being drafted. Reporting state: England. A draft for an EU Directive is being prepared. Nonylphenol ethoxylate is included in the national programme for monitoring of the aquatic environment 1998-2003, also called NOVA 2003 /20/. The use of alkylphenols in spraying products is being phased out. Mapping the occurrence and fate of a selected substance (nonylphenol ethoxylate) in all media of the environment within a geographically demarcated area. National Environmental Research Institute project on substances alien to the environment. Expected date of completion: 2000. Work is in progress in OSPAR on initiatives aimed at reducing discharges and losses of nonylphenol ethoxylates, with a view to reducing their presence in marine areas to concentrations close to zero before 2020 /57/. Octylphenol ethoxylate (CAS No. 9002-93-1) is included in the national programme for monitoring of the aquatic environment 1998-2003, also called NOVA 2003 /20/. A strategic plan for phase-out expected to be ready during 2000. Projects concerned with the development of alternatives to the use of alkylphenols in chemical products within the field of painting and building materials are in progress. These projects receive funding from the Cleaner Products Support Programme, etc., (Danish EPA). 5.3 3-Aminomethyl-3,5,5-trimethyl cyclohexylamineCAS No.: EINECS No.: Synonym: Product groups: Paints and undercoats Flooring materials Construction materials and casting/moulding compounds/materials High-pressure cleaning agents High-pressure additives (to coolants and lubricants) Surface-treatment agents (for paper, cardboard and other non-metals) Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instructions governing suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers is to be launched during 2000. This campaign will give information on the precautions to be taken when using such products as paints and varnishes. 5.4 Antimony trioxideCAS No.: EINECS No.: Product groups: Adhesives Casting/moulding compounds/materials, including fillers Fire-retarding additives to textiles, plastics, etc. Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /18/ National Consumer Agency of Denmark Statutory Order on safety requirements for toys and products, /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instructions governing suppliers' instructions for use of products) Miscellaneous regulations: /7/ (EU regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Is undergoing classification as an environmental hazard in the EU. Is undergoing risk assessment in the EU. Reporting state: Sweden. The project on environmental and health screening of alternatives to antimony trioxide is expected to be completed during 2000. 5.5 Azo dyes, which can split off carcinogenic arylaminesCAS/EINECS Nos.:
Classification: The following two dyes are examples of azo dyes that are associated with a risk of splitting off one of the above-mentioned 21 arylamines. Azo dyes Direct brown 95 (CAS No. 16071-86-6: carcinogenic (Carc2; R 45). Solvent yellow 3 (CAS No. 97-56-3): carcinogenic (Carc2; R 45) and sensitising (R 43). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /30/ (Danish EPA guideline on quality requirements on waters), /31/ (Danish EPA Statutory Order, the "Risk" Statutory Order), /61/ (EU regulation on the export and import of dangerous chemicals), /89/ (EU Directive on chemical agents) Quality criteria/limit values: /8/ (European Commission on ecolabels for textile products), /22/ (National Working Environment Authority instruction on limit values), /36/ (Danish EPA information on B values), /50/ (European Commission on ecolabels for footwear), /52/ (European Commission on ecolabels for bed matresses) Working environment: /5/ (Directorate of Labour Inspection instructions governing suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /75/ (EU Directive on the protection of employees) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /91/ (EU Regulation on List 1), /109/ (DEPA guideline on industrial waste water) Activities: Many azo dyes are included in the national programme for monitoring of the aquatic environment 1998-2003, also called NOVA 2003 /20/. Presentations and information for the manufacturers of textile products, for buyers and designers and in conjunction with the revision and reprinting of the brochure Håndbog om kemikalier i tøj ("Chemicals in Textiles - Manual," Danish-language only). Directives on restrictions on use are being drafted in the EU (due to the cancer risk). 5.6 BiphenylCAS No.: EINECS No.: Product groups: Preservatives Road-surfacing materials Heat-transfer media Sealing compounds Impregnation products Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Included in the national programme for monitoring of the aquatic environment 1998-2003, also called NOVA 2003 /20/. 5.7 2,2-Bis(p-(2,3-epoxy-propoxy) phenyl)-propane and bisphenol-A-diglycidyl ether reaction productCAS No.: 2. 25068-38-6 (Bisphenol-A-diglycidylether reaction product) EINECS No.: 2. 500-033-5 Product groups: Undercoats Binding agents for paints, adhesives, etc. Adhesives Flooring materials Paint and varnishes hardeners Reason for selection: Classification: Bisphenol-A-diglycidylether reaction product (homologous to an average molecular weight of 700)(CAS No. 25068-38-6): local irritant (R 36/38) down to 5%, sensitising (R 43) and harmful to the environment (R 51/53). Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instructions governing suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /92/ (Directorate of Labour Inspection Statutory Order on epoxy resins and isocyanates) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: 2,2-Bis(p-(2,3-epoxypropoxy)phenyl)-propane must also be assessed with a view to classification as an environmental hazard. An information campaign being launched during 2000 is aimed at consumers. This campaign will give information on the precautions to be taken when using such products as paints and varnishes. 5.8 Lead and lead compoundsCAS Nos.: Product groups: Plastics Glass Paints, glazes and pigments Building materials and cable sheathing Solder and fishing tackle Reason for selection: Certain substances have been systematically selected because of their classifications. Goals: Restrictions on heavy metals are desired because of their harmful effects on the health and environment. No knowledge of substitution alternatives is available for certain areas of application, and work is needed to find technically and economically feasible alternatives in the future. Restrictions on these substances are desired because of their concentrations found in and their impact on the environment and on the health, in connection with the use of residuals, such as slags, compost and sludge. Classification: Lead alkyls: toxic to reproduction (Rep1, R 61; Rep3, R 62), very toxic (R 26/27/28), danger of cumulative effects after repeated use (R 33) and harmful to the environment (R 50/53). Lead azide (CAS No. 13424-46-9): toxic to reproduction (Rep1, R 61; Rep3, R 62), explosive (R 3), harmful to the health (R 20/22) and danger of cumulative effects after repeated use (R 33). Lead chromate (CAS No. 7758-97-6): toxic to reproduction (Rep1, R 61; Rep3, R 62), carcinogenic (Carc3, R 40), danger of cumulative effects after repeated use (R 33) and harmful to the environment (R 50/53). Lead chromate molybdate sulphate red (CAS No. 12656-85-8): toxic to reproduction (Rep1, R 61; Rep3, R 62), carcinogenic (Carc3, R 40) and danger of cumulative effects after repeated use (R 33). Lead di(acetate) (CAS No. 301-04-2): toxic to reproduction (Rep1, R 61; Rep3, R 62), danger of cumulative effects after repeated use (R 33) and harmful to the health (R 48/22). Lead hexafluorosilicate (CAS No. 25808-74-6): toxic to reproduction (Rep1, R 61; Rep3, R 62), harmful to the health (R 20/22) and danger of cumulative effects after repeated use (R 33). Lead hydrogen arsenate (CAS No. 7784-40-9): carcinogenic (Carc1; R 45), toxic to reproduction (Rep1, R 61; Rep3, R 62), toxic (R 23/25) and danger of cumulative effects after repeated use (R 33). Lead(II) methane sulphonate (CAS No. 17570-76-2): toxic to reproduction (Rep1, R 61; Rep3, R 62), harmful to the health (R 20/22-48/20/22), danger of cumulative effects after repeated use (R 33), local irritant (R 38-41) and harmful to the environment (R 58). Trilead bis(orthophosphate) (CAS No. 7446-27-7): toxic to reproduction (Rep1, R 61; Rep3, R 62), harmful to the health (R 48/22) and danger of cumulative effects after repeated use (R 33). Lead styphnate (CAS No. 15245-44-0): toxic to reproduction (Rep1, R 61; Rep3, R 62), explosive (R 3), harmful to the health (R 20/22) and danger of cumulative effects after repeated use (R 33). Lead sulphochromate yellow (CAS No. 1344-37-2): toxic to reproduction (Rep1, R 61; Rep3, R 62) carcinogenic (Carc3; R 40) and danger of cumulative effects after repeated use (R 33). Lead-2,4,6-trinitroresorcinolate (CAS No. 15245-44-0): toxic to reproduction (Rep1, R 61; Rep3, R 62), explosive (R 3), harmful to the health (R 20/22) and danger of cumulative effects after repeated use (R 33). Other lead compounds: toxic to reproduction (Rep1, R 61; Rep3, R 62), harmful to the health (R 20/22) and danger of cumulative effects after repeated use (R 33). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on Restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /18/ (National Consumer Agency of Denmark Statutory Order on safety requirements for toys and products), /28/ (Danish EPA Statutory Order on cosmetic products), /31/ (Danish EPA Statutory Order, the "Risk" Statutory Order), /46/ (EU Directive on polluting of aquatic environments), /66/ (Danish EPA guideline on the classification etc., of chemical substances and products), /67/ (Danish EPA guideline on the restriction of air pollution by enterprises), /76/ (Danish EPA Statutory Order on the prohibition of lead shot), /90/ (Danish EPA Statutory Order on batteries and accumulators that contain dangerous substances) Quality criteria/limit values: /3/ (Danish EPA Statutory Order on waste products intended for agricultural purposes), /22/ (National Working Environment Authority instruction on limit values), /28/ (Danish EPA Statutory Order on cosmetic products), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /34/ (Danish EPA Statutory Order on surface water used for drinking water), /36/ (Danish EPA information on B values), /54/ (Danish EPA: quality requirements on soil and drinking water), /55/ (Danish EPA: soil-quality criteria), /77/ (Danish EPA Statutory Order on sludge etc., intended for agricultural purposes), /78/ (Danish EPA Statutory Order on waste incineration), /79/ (Danish EPA Statutory Order on the use of slags and fly ash), /63/ (Danish EPA Statutory Order on the lead content of petrol, etc.) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances), /68/ (National Energy Agency Statutory Order on work on off-shore installations), /69/ ((Ministry of Labour instruction on the performance of work), /70/ (Ministry of Labour Statutory Order on metallic lead and its ionic compounds), /71/ (Ministry of Labour instruction on pregnancy and the working environment), /72/ (Directorate of Labour Inspection information on metallic lead), /73/ (EU Directive on the protection of young people at work), /74/ (EU Directive on pregnant women etc.), /75/ (EU Directive on the protection of employees) (EU Directive on the protection of employees) Miscellaneous regulations: /6/ (EU Commission directive on high-priority substances), /7/ (EU Regulation on the risks of existing substances), /42/ (EU Directive on dangerous waste), /49/ (EU regulation on waste transport), /62/ (Danish EPA Statutory Order on waste), /64/ (Danish EPA guideline on tannery sites), /65/ (Danish EPA guideline on boring control at waterworks), /80/ (Danish EPA Statutory Order on lead-acid accumulators etc.), /81/ (Danish EPA Statutory Order on surcharges on lead-acid accumulators), /82/ (Danish EPA Statutory Order on certain requirements on packaging), /109/ (Danish EPA guideline on industrial waste water), /134/ (Water Framework Directive), /136/ (HELCOM) Activities: An EU Directive, which will restrict the quantity, e.g., of lead in the air, is on the way. The intention is to sort products containing the substances out of the waste stream with a view to special waste treatment. High priority has been assigned to the substitution of lead in a number of products. These projects receive funding from the Cleaner Products Support Programme, etc., (Danish EPA). A Statutory Order, on the prohibition of products containing lead, is expected to be issued during 2000. This Statutory Order will include a general prohibition - with exceptions - against lead compounds and specific prohibitions against metallic lead. Work is in progress in OSPAR on reducing discharges and losses of lead, with a view to reducing their presence in marine areas to concentrations close to zero before 2020 /57/. 5.9 Boric acid and boraxCAS No.: 1303-96-4 (borax) EINECS No.: Product groups: Cosmetics Impregnation products Toys Reason for selection: Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: Working environment: Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: At the beginning of 2000, the Danish EPA requested the Danish toy sector to phase out the use of these substances voluntarily. The request was made on the basis of the Danish proposal for classification of the substances. Boric acid (CAS No. 10043-35-3) is undergoing risk assessment in the EU. Reporting state: Austria. 5.10 Brominated flame retardantsCAS Nos.: Product groups: Textiles Electronics Reason for selection: Goals: Restrictions on these substances are desired because of their diffuse distribution, e.g., in the marine environment, and increasing frequency of occurrence in breast milk. Classification: Present regulation: /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances to specific purposes, 1997), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: Miscellaneous regulations: /49/ (EU regulation on waste transport), /109/ (Danish EPA guideline on industrial waste water), /134/ (Water Framework Directive) Activities: Polybrominated diphenyl ethers (PBDE) penta-, octa- and deca- and hexabromocyclododecane are undergoing assessment in the EU. Reporting states: England, France and Sweden. Polybrominated biphenyls (PBB) are undergoing assessment in the OECD /137/. A number of projects concerned with substitutions for brominated flame retardants in selected products have high priority. These projects receive funding from the the Cleaner Products Support Programme, etc., (Danish EPA). Work is in progress in OSPAR, on initiatives for reducing discharges and losses of brominated flame retardants, with a view to reducing their presence in marine areas to concentrations close to zero before 2020 /57/. A draft action plan for brominated flame retardants was sent for a hearing in April 2000. The final action plan is expected around mid-2000. Projects concerned with environmental and health screening of the alternatives are under way are are expected around mid-2000. 5.11 2-ButanonoximeCAS No.: EINECS No.: Synonym: Product groups: Rust preventives Wood-impregnation products Serigraphic dyes Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: This substance's classification is being reviewed in the EU. 5.12 Cadmium and cadmium compoundsCAS Nos.: Product groups: Plastics Batteries and accumulators Pigments Cadmium plating Reason for selection: High priority in the marine environment (batteries). Goals: Restrictions on heavy metals are desired because of their harmful effects on the health and environment. No knowledge of substitution alternatives is available for certain areas of application today. Work is needed to find technically and economically feasible alternatives in the future. Restrictions on these substances are desired because of their impact on the health and environment, in connection with the use of residuals, such as slags, compost and sludge. Classification: Cadmium chloride (CAS No. 10108-64-2): carcinogenic (Carc2; R 45) and toxic (R 48/23/25). Cadmium cyanide (CAS No. 542-83-6): very toxic (R 26/27/28), danger of cumulative effects after repeated use (R 33), a highly toxic gas is liberated by contact with acids (R 32) and there is the possibility of irreversible effects on the health (R 40). This substance has various classifications, depending on the concentration. Cadmium fluoride (CAS No. 7790-79-6), cadmium formiate (CAS No. 4464-23-7), cadmium hexafluorosilicate (CAS No. 17010-21-8) and cadmium iodide (CAS No. 7790-80-9): toxic (R 23/25), danger of cumulative effects after repeated use (R 33) and there is the possibility of irreversible effects on the health (R 40). This substance has various classifications, depending on the concentration. Cadmium oxide (CAS No. 1306-19-0) and cadmium sulphate (CAS No. 10124-36-4): carcinogenic (Carc2; R 49), harmful to the health (R 22) and toxic (R 48/23/25). Cadmium sulphide (CAS No. 1306-23-6): carcinogenic (Carc3; R 40), harmful to the health (R 22) and toxic (R 48/23/25). Other cadmium compounds: harmful to the health (R 20/21/22). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /18/ (National Consumer Agency of Denmark Statutory Order on safety requirements for toys and products), /28/ (Danish EPA Statutory Order on cosmetic products), /95/ (Danish EPA Statutory Order on Cd in fertiliser), /96/ (Danish EPA Statutory Order on prohibition of Cd products), /134/ (Water Framework Directive), /90/ (Danish EPA Statutory Order on batteries and accumulators that contain dangerous substances) Quality criteria/limit values: /3/ (Danish EPA Statutory Order on waste products intended for agricultural purposes), /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values) /47/ (EU Directive on the quality of bathing water), /54/ (Danish EPA: quality requirements on soil and drinking water), /55/ (Danish EPA: soil-quality criteria), /77/ (Danish EPA Statutory Order on sludge etc., intended for agricultural purposes), /78/ (Danish EPA Statutory Order on waste incineration), /97/ (Danish EPA Statutory Order on Cd in industrial process water), /98/ (Danish EPA Statutory Order on surfactants in detergents and cleaning products), /99/ (Danish EPA Statutory Order on limit values for Hg) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances), /100/ (Ministry of Labour on the use of certain Cd soldering products) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /62/ (Danish EPA Statutory Order on waste), /82/ (Danish EPA Statutory Order on certain requirements on packaging), /93/ (EU regulation on List III), /94/ (EU regulation on information on existing substances), /101/ (Danish EPA Statutory Order on sealed Ni-Cd batteries), /109/ (Danish EPA guideline on industrial waste water), /134/ (Water Framework Directive), /136/ (HELCOM) Activities: The Commission of the European Community has presented proposals for phasing out the use of cadmium in batteries. In the EU, prohibitions or restrictions on use are being considered for: cadmium sulphide, cadmium mercury sulphide, cadmium stearate, cadmium dilaurate, cadmium zinc sulphide yellow, cadmium sulphoselenide orange and cadmium sulphoselenide red. Cadmium is included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. The intention is to sort products containing these substances out of the waste stream with a view to special waste treatment. An EU Directive, which will limit the the amount, e.g., of cadmium, in the air is on the way. A mass-stream analysis for cadmium is being prepared and is expected during 2000. During 2000, monitoring authorities in the EU will launch a joint campaign to investigate whether or not the requirements of EU Directive 91/338/EEC are being observed. Work is in progress on initiatives in OSPAR for reducing discharges and losses of cadmium, with a view to reducing their presence in the marine areas to concentrations of close to zero before 2020 /57/. 5.13 Chlorinated solvents5.13.1 1,2-dichloroethaneCAS No.: EINECS No.: Product groups: Sealing compounds Degreasing agents Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /61/ (EU regulation on the export and import of dangerous chemicals), /134/ (Water Framework Directive) Quality criteria/limit values: /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /46/ (EU Directive on polluting of aquatic environments), /126/ (EU Directive on child-resistant fastenings) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution), /134/ (Water Framework Directive), /136/ (HELCOM) Activities: 1,2-dichloroethane is included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. 5.13.2 1,2-dichloromethaneCAS No.: EINECS No.: Synonym: Product groups: Solvent-based adhesives Solvents Releasing agents, including mould releasing agents for plastics and other applications Cleaning products Adhesive hardeners Thinners (for paints, varnishes, adhesives, etc.) Reason for selection: Goals: Restrictions on this substance are desired because of its harmful effects on the health. Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products), /134/ (Water Framework Directive), /138/ (Ministry of Taxation Promulgation Act on surcharges on chlorinated solvents) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution), /126/ (EU Directive on child-resistant fastenings), /134/ (Water Framework Directive), /136/ (HELCOM) Activities: Undergoing classification as an environmental hazard in the EU. A Danish EPA Environment Project concerning the use of this substance in paint and varnish strippers and a mapping of possible alternatives will be published during 2000. A new Directive, which restricts the use of dichloromethane is being drafted in the EU. 5.13.3 TetrachloroethyleneCAS No.: EINECS No.: Synonym: Product groups: Dry cleaning Degreasing agents and solvents Reason for selection: Goals: Restrictions/total phasing-out of this substance is desired because of the concentrations found in groundwater. Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products), /138/ (Ministry of Taxation Promulgation Act on surcharges on chlorinated solvents) Quality criteria/limit values: /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values), /108/ (Danish EPA Statutory Order on List-1 substances), /127/ (EU Directive on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /22/ (National Working Environment Authority instruction on limit values) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /64/ (Danish EPA guideline on tannery sites), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution), /136/ (HELCOM) Activities: Undergoing risk assessment in the EU. Reporting state: England. Other regulatory initiatives are pending on this assessment. This substance's classification is undergoing reappraisal in the EU. 5.13.4 TrichloroethyleneCAS No.: EINECS No.: Product groups: Adhesives Solvents Paint and varnish strippers Serigraphic dyes Binding agents Reason for selection: Goals: Restrictions/phasing out of this substance are desired because of the concentrations found in groundwater and because of its harmful effect on the health. Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /138/ (Ministry of Taxation Promulgation Act on surcharges on chlorinated solvents) Quality criteria/limit values: /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values), /108/ (Danish EPA Statutory Order on List-1 substances), /127/ (EU Directive on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /22/ (National Working Environment Authority instruction on limit values), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /64/ (Danish EPA guideline on tannery sites), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution), /136/ (HELCOM) Activities: Undergoing risk assessment in the EU. Reporting state: England. Additional regulation is pending on this assessment. 5.14 Chlorinated paraffins (short-, medium- and long-chained)CAS No.: Product groups: Coolants/lubricants and cutting oils Paints Plastics and flame retardants Reason for selection: Goals: Restrictions on these substances are desired because of their diffuse distribution in the marine environment. Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.), /134/ (Water Framework Directive) Quality criteria/limit values: Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM) Activities: The medium-chained chlorinated paraffins, C'14-17' chlorinated paraffins (CAS No. 85535-85-9), are undergoing risk assessment in the EU, including assessment of how they shall be classified. Reporting state: England. Additional regulatory initiatives are pending on this assessment. High priority has been given to a number of projects concerned with substitution for the medium-chained chlorinated paraffins in selected products. These projects receive funding from the the Cleaner Products Support Programme, etc., (Danish EPA). Work is in progress on initiatives in OSPAR for reducing discharges and losses of the short-chained chlorinated paraffins, with a view to reducing their presence in the marine areas to concentrations of close to zero before 2020 /57/. 5.15 Chromium compoundsCAS Nos.: Product groups: Paints Chromium plating Cleaning products Imported leather Reason for selection: Certain substances have been systematically selected because of their classifications. Goals: Restrictions on these substances are desired because of their concentrations found in and their impact on the environment and on the health, in connection with the use of residuals, such as slags, compost and sludge. Classification: Ammonium dichromate (CAS No. 7789-09-5): carcinogenic (Carc2; R 49), mutagenic (Mut2; R 46), very toxic (R 26), toxic (R 25), harmful to the health (R 21), sensitising (R 43), local irritant (R 37/38-41), oxidising (R 8), explosive (R 1) and harmful to the environment (R 50/53). Calcium chromate (CAS No. 13765-19-0), strontium chromate (CAS No. 7789-06-2): carcinogenic (Carc2; R 45), harmful to the health (R 22) and harmful to the environment (R 50/53). Chromium(VI) compounds, with the exception of barium chromate and the substances mentioned below: carcinogenic (Carc2; R 49) sensitising (R 43) and harmful to the environment (R 50/53). Chromium trioxide (CAS No. 1333-82-0): carcinogenic (Carc1; R 49), toxic (R 25), oxidising (R 8), corrosive (R 35), sensitising (R 43) and harmful to the environment (R 50/53). Chromyl dichloride (CAS No. 14977-61-8): carcinogenic (Carc2; R 49) and mutagenic (Mut2; R 46), oxidising (R 8), corrosive (R 35), sensitising (R 43) and harmful to the environment (R 50/53). Dichromtris(chromate) (CAS No. 24613-89-6): carcinogenic (Carc2; R 45), corrosive (R 35), sensitising (R 43), oxidising (R 8) and harmful to the environment (R 50/53). Potassium chromate (CAS No. 7789-00-6): carcinogenic (Carc2; R 49), mutagenic (Mut2; R 46), local irritant (R 36/37/38), sensitising (R 43) and harmful to the environment (R 50/53). Potassium dichromate (CAS No. 7778-50-9): carcinogenic (Carc2; R 49), mutagenic (Mut2; R 46), very toxic (R 26), toxic (R 25), harmful to the health (R 21), sensitising (R 43), local irritant (R 37/38-41) and harmful to the environment (R 50/53). Sodium dichromate (CAS No. 10588-01-9): carcinogenic (Carc2; R 49), mutagenic (Mut2; R 46), very toxic (R 26), toxic (R 25), harmful to the health (R 21), sensitising (R 43), local irritant (R 37/38-41), oxidising (R 8) and harmful to the environment (R 50/53). Sodium dichromate, dihydrate (CAS No. 7789-12-0): carcinogenic (Carc2; R 49), mutagenic (Mut2; R 46), very toxic (R 26), toxic (R 25), harmful to the health (R 21), local irritant (R 37/38-41), sensitising (R 43) and harmful to the environment (R 50/53). Zinc chromates: carcinogenic (Carc1; R 45), harmful to the health (R 22), sensitising (R 43) and harmful to the environment (R 50/53). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products), /45/ (Directorate of Labour Inspection Statutory Order on F-gas containers in vehicles) Quality criteria/limit values: /8/ (EU Commission on ecolabels for textile products), /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values), /55/ (Danish EPA: soil-quality criteria), /78/ (Danish EPA Statutory Order on waste incineration), /105/ (European Commission on ecolabels for double-ended light bulbs), /106/ (European Commission on ecolabels for single-ended light bulbs) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances), /107/ (Directorate of Labour Inspection Statutory Order on Cr in cement) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /64/ (Danish EPA guideline on tannery sites), /82/ (Danish EPA Statutory Order on certain requirements on packaging), /93/ (EU regulation on List III), /102/ (Danish EPA guideline on surface treatment of ships), /103/ (Danish EPA Statutory Order on quality requirements/environmental goals), /104/ (Danish EPA guideline on on pollution from fish farms), /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM) Activities: Chromium trioxide (CAS No. 1333-82-0), sodium chromate (CAS No. 7775-11-3), potassium chromate (CAS No. 7778-50-9), ammonium dichromate (CAS No. 7789-09-5) and sodium dichromate (CAS No. 10588-01-9) are undergoing risk assessment in the EU. Reporting state: England. Additional regulatory initiatives are pending on this assessment. The intention is to sort products containing these substances out of the waste stream with a view to special waste treatment. A mass stream analysis for chromium compounds is being implemented under the Cleaner Products Support Programme, etc., (Danish EPA). 5.16 Creosote compounds with carcinogenic impuritiesCAS/EINECS Nos.:
Product groups: Paint and varnish hardeners Building materials Undercoats and anti-rust products Reason for selection: Systematically selected because of their classification. Goals: Restriction of the use of these substances is desired because of their harmful effects on the health. Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /25/ (EU Dir. on restriction of the marketing and use of certain dangerous products), /131/ (Danish EPA Statutory Order on creosote) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: Activities: 5.17 CryoliteCAS No.: EINECS No.: Product groups: Cleaning products Heat-transfer media Friction agents Cleaning products for boilers and tanks Casting/moulding compounds/materials Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /25/ (EU Dir. on restriction of the marketing and use of certain dangerous products) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /93/ (EU regulation on List III), /109/ (Danish EPA guideline on industrial waste water) Activities: his substance is undergoing danger assessment in the OECD /137/. 5.18 CyclohexaneCAS No.: EINECS No.: Product groups: Paints and varnishes Solvents, thinners (for paints, varnishes, adhesives, etc.) Undercoats Degreasing agents Filler products Water softeners Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /36/ (Danish EPA information on B values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /91/ (EU Regulation on List I), /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM) Activities: Undergoing risk assessment in the EU. Reporting state: France. Additional regulatory initiatives are pending on this assessment. An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.19 Petroleum distillatesCAS/EINECS Nos.:
Product groups: Coolants/lubricants Anti-rust products Solvents Adhesives Paints Reason for selection: Classification: Distillates (petroleum), heavy naphthenic (CAS No. 64741-53-3): carcinogenic (Carc1; R 45). Extracts (petroleum), heavy paraffinic distillate solvent (CAS No. 64742-04-7): carcinogenic (Carc2; R 45). Solvent naphtha, petroleum, medium aliph. (CAS No. 64742-88-7): flammable (R 10), harmful to the health (R 65) and (R 48/20). Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /25/ (EU Directive on restriction of the marketing and use of certain dangerous products) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.20 3,6-Diazaoctane-1,8-diamineCAS No.: EINECS No.: Synonym: Product groups: Paints Casting/moulding compounds/materials Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: This substance is undergoing danger assessment in the OECD /137/. An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.21 3,3'-Dichlorobenzidine dihydrochlorideCAS No.: EINECS No.: Synonym: Product groups: Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: 5.22 Dichloro-N-[(dimethylamino)sulfonyl] fluoro-N-(p-tolyl)methanesulfenamideCAS No.: EINECS No.: Synonym: Product groups: Wood-impregnation products Fungicides Preservatives Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: This substance is undergoing danger assessment in the OECD /137/. 5.23 DiethanolamineCAS No.: EINECS No.: Synonym: Product groups: Cleaning products Degreasing agents Releasing agents for plastic metal-working Paints Film developers Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution) Activities: This substance is undergoing danger assessment in the OECD /137/. An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.24 DimethylphenolCAS No.: EINECS No.: Synonym: Product groups: Paints Cleaning products Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.25 Ethylene glycol monoethyl etherCAS No.: EINECS No.: Synonym: Product groups: Undercoats Thinners Reason for selection: Goals: Restrictions on this substance are desired because of its harmful effects on the health. Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /59/ (Danish EPA Statutory Order on propellants and solvents in aerosol canisters) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /36/ (Danish EPA information on B values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /6/ (European Commission directive on high-priority substances), /7/ (EU Regulation on the risks of existing substances), /64/ (Danish EPA guideline on tannery sites), /67/ (Danish EPA guideline on the restriction of air pollution by enterprises), /109/ (Danish EPA guideline on industrial waste water) Activities: High priority has been assigned to a number of projects working on substitutes for ethylene glycol monoethyl ether in selected products. Funding from the the Cleaner Products Support Programme, etc., (Danish EPA). 5.26 6-Ethoxy-1,2-dihydro-2,2,4-trimethylquinolineCAS No.: EINECS No.: Synonym: Product groups: Biocides Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: Undergoing re-assessment with respect to environmental classification in the EU. 5.27 FormaldehydeCAS No.: EINECS No.: Product groups: Preservatives Textiles and dyes Cosmetics Reason for selection: Goals: Restrictions on this substance are desired because of its harmful effects on the health. Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products), /128/ (Danish EPA Statutory Order on formaldehyde) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /28/ (Danish EPA Statutory Order on cosmetic products), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /31/ (Danish EPA Statutory Order, the "Risk" Statutory Order), /86/ (EU Directive on emissions from motor vehicles), /109/ (Danish EPA guideline on industrial waste water) Activities: Danish EPA Environmental Project No. 501, Emission af flygtige forbindelser fra træ, træbaserede materialer, møbler og inventar ("Emissions of volatile compounds from wood, wood-based materials, furniture and fittings," Danish-language only) was published in 1999. This project describes, e.g., the types of wood that release formaldehyde. Danish EPA Environmental Project No. 511, "Toxicological evaluation and limit values for methyl tertiary-butyl ether (MTBR), formaldehyde, glutaraldehyde and furfural" was published at the beginning of 2000. An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.28 Glutaric dialdehydeCAS No.: EINECS No.: Synonym: Product groups: Cleaning products Developers Preservatives Anti-fouling products, e.g., used off-shore Wax and other polishes for flooring Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: This substance is undergoing danger assessment in the OECD /137/. 5.29 HexachlorobenzeneCAS No.: EINECS No.: Product groups: Reason for selection: A special initiative in the EU has been assigned high priority, because of this substance's harmful effects on the aquatic environment. Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /61/ (EU regulation on the export and import of dangerous chemicals), /111/ (Danish EPA Statutory Order on amendment of the Act on chemical substances and products), /134/ (Water Framework Directive) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /108/ (Danish EPA Statutory Order on List-1 substances), /110/ (EU Directive on limit values), /112/ (Danish EPA Statutory Order on limit values for List I substances) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /134/ (Water Framework Directive), /136/ (HELCOM) Activities: Hexachlorobenzene is included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. 5.30 1,6-HexanedioldiacrylateCAS No.: EINECS No.: Synonym: Product groups: Paints, including protective varnishes and masking varnishes (masking inks) Binding agents Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /30/ (Danish EPA Statutory Order on waters and requirements on discharges) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.31 Hydrocarbons, C26-55, aromaticCAS No.: EINECS No.: Product groups: Binding agents Synthesis of raw materials Impregnation products Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /25/ (EU Directive on restriction of the marketing and use of certain dangerous products) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: The Danish EPA's Chemical Inspection Service will investigate the use of these substances in consumer products during 2001-2002. 5.32 Hydrogenated fluorocarbons (HFC)CAS Nos.: HFC 125 (CAS No. 354-33-6, EINECS No. 206-557-8) HFC 143a (CAS No. 420-46-2, EINECS No. 206-996-5) HFC 152a (CAS No. 75-37-6, EINECS No. 200-866-1)) Product groups: Spray canisters Refrigerating plants Foam rubber Insulating materials Reason for selection: Severe greenhouse effect. Goals: Restrictions on these substances are desired because of their severe greenhouse effect. Classification: Present regulation: /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /59/ (Danish EPA Statutory Order on propellants and solvents in aerosol canisters) Quality criteria/limit values: Working environment: /113/ (Directorate of Labour Inspection Statutory Order on aerosols) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: Several projects have been launched with respect to substitution alternatives for greenhouse gases in selected products. Funding from the the Cleaner Products Support Programme, etc., Danish EPA 5.33 Isocyanates5.33.1 Diphenylmethane-2,4'-diisocyanate, diphenylmethane-4, 4'-diisocyanate and diphenylmethanediisocyanate, isomers and homologuesCAS No.: 2. 101-68-8 (diphenylmethane-4,4'-diisocyanate) 3. 9016-87-9 (diphenylmethanediisocyanate, isomers and homologues) EINECS No.: 2. 202-966-0 3. None Product groups: Fillers, including joint fillers (joint sealants) Casting/moulding compounds/materials and joint fillers Undercoats and binding agents Adhesives and paints Reason for selection: Classification: Diphenylmethane-4,4'-diisocyanate (CAS No. 101-68-8): harmful to the health (R 20), local irritant (R 36/37/38) and sensitising (R 42). Diphenylmethanediisocyanate, isomers and homologues (CAS No. 9016-87-9): harmful to the health (R 20), local irritant (R 36/37/38) and sensitising (R 42). Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /22/ (National Working Environment Authority instruction on limit values), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances), /92/ (Directorate of Labour Inspection Statutory Order on epoxy resins and isocyanates) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Diphenylmethane-4,4'-diisocyanate and diphenylmethanediisocyanate, isomers and homologues are undergoing danger assessment in the OECD /137/. An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.33.2 2,4-Diisocyanatotoluene and 2,6-diisocyanatotolueneCAS No. 1. 584-84-9 (2,4-diisocyanatotoluene) 2. 91-08-7 (2,6-diisocyanatotoluene) EINECS No.: 1. 209-544-5 2. 202-039-0 Product groups: Jointing and sealing compounds Serigraphic dyes Textile impregnation products Adhesives Reason for selection: Classification: 2,6-Diisocyanatotoluene (CAS No. 91-08-7): carcinogenic (Carc3, R 40), highly toxic (R 26), local irritant (R 36/37/38), sensitising (R 42/43) and harmful to the environment (R 52/53). Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /92/ (Directorate of Labour Inspection Statutory Order on epoxy resins and isocyanates) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.34 4,4'-IsopropylidenediphenolCAS No.: EINECS No.: Product groups: Casting/moulding compounds/materials Binding agents for casting/moulding Hardeners for adhesives Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM) Activities: Included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. Undergoing risk assessment in the EU. Reporting state: England. Additional regulatory initiatives are pending on this assessment. An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.35 Copper and copper compoundsCAS Nos.: Product groups: Anti-fouling products Pigments and dyes Copper water pipes Reason for selection: Goals: Restrictions on these substances are desired because of the high concentrations found in residual products. Classification: Copper cyanide (Index No. 006-007-00-5): highly toxic (R 26/27/28) and very toxic gas is liberated by contact with acids (R 32). Copper(I)-O,O-diisopropyldithiophosphate, etc. (EINECS No. 401-520-4): harmful to the environment (R 50/53). Copper(II) methanesulphonate (CAS No. 54253-62-2: harmful to the health (R 22), local irritant (R 41) and harmful to the environment (R 50/53). Copper naphthenate (CAS No. 1338-02-9): harmful to the health (R 22) and flammable (R 10). Copper(I) oxide (CAS No. 1317-39-1: harmful to the health (R 22). Copper sulphate (CAS No. 7758-98-7): harmful to the health (R 22) and local irritant (R 36/38). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /18/ (National Consumer Agency of Denmark Statutory Order on safety requirements for toys and products) Quality criteria/limit values: /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values), /54/ (Danish EPA: quality requirements on soil and drinking water), /55/ (Danish EPA: soil-quality criteria), /78/ (Danish EPA Statutory Order on waste incineration), /79/ (Danish EPA Statutory Order on the use of slags and fly ash) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /134/ (Water Framework Directive), /136/ (HELCOM) Activities: The intention is to sort products containing these substances out of the waste stream with a view to special waste treatment. Undergoing classification as environmental hazard in the EU. 5.36 Colophony (rosin free from turpentine oil)CAS No. EINECS No. Product groups: Paints and varnishes Soldering fluxes Cosmetics Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.37 Mercury and mercury compoundsCAS Nos.: Product groups: Dental fillings Fluorescent lamps Thermometers Reason for selection: High priority assigned to a special initiative in the EU, due to their harmful effects on the aquatic environment (batteries and thermometers) Goals: Restrictions on heavy metals are desired because of their harmful effects on the health and environment. No knowledge of substitution alternatives is available for certain areas of application, and work is needed to find technically and economically feasible alternatives in the future. Restrictions on the use of these substances are also desired because of their impact on the health and environment, in connection with the use of residuals, such as slags, compost and sludge. Classification: Mercury (CAS No. 7439-97-6): toxic (R 23), danger of cumulative effects after repeated use (R 33). Mercury alkyls: danger of cumulative effects after repeated use (R 33) very toxic (R 26/27/28). Calomel (CAS No. 10112-91-1): harmful to the health (R 22) and local irritant (R 36/37/38). Mercury dichloride (CAS No. 7487-94-7): very toxic (R 28), toxic (R 48/24/25) and corrosive (R 34). Mercury(II) fulminate (CAS No. 628-86-4) and mercury(II) oxidecyanide (CAS No. 1335-31-5): explosive (R 3), toxic (R 23/24/25) and danger of cumulative effects after repeated use (R 33). Other organic mercury compounds: danger of cumulative effects after repeated use (R 33) and highly toxic (R 26/27/28). Other inorganic mercury compounds, with the exception of mercury(II) sulphide: danger of cumulative effects after repeated use (R 33) and highly toxic (R 26/27/28). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /18/ (National Consumer Agency of Denmark Statutory Order on safety requirements for toys and products), /28/ (Danish EPA Statutory Order on cosmetic products), /31/ (Danish EPA Statutory Order, the "Risk" Statutory Order), /111/ (Danish EPA Statutory Order on amendment of the Act on chemical substances and products), /123/ (Danish EPA Statutory Order on prohibition of the sale and export of products containing Hg), /134/ (Water Framework Directive), /90/ (Danish EPA Statutory Order on batteries and accumulators that contain dangerous substances) Quality criteria/limit values: /3/ (Danish EPA Statutory Order on waste products intended for agricultural purposes), /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values), /55/ (Danish EPA: soil-quality criteria), /78/ (Danish EPA Statutory Order on waste incineration), /79/ (Danish EPA Statutory Order on the use of slags and fly ash), /97/ (Danish EPA Statutory Order on Cd in industrial process water), /99/ (Danish EPA Statutory Order on limit values for mercury), /116/ (Danish EPA Statutory Order on sludge etc., for agriculture) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /66/ (Danish EPA guideline on the classification etc., of chemical substances and products), /109/ (Danish EPA guideline on industrial waste water), /114/ (EU Directive on dangerous chemicals), /136/ (HELCOM) Activities: Undergoing classification as an environmental hazard in the EU. An EU Directive, which will limit the amounts, e.g., of mercury, in the air is on the way. The intention is to sort products containing these substances out of the waste stream with a view to special waste treatment. Work is in progress on initiatives in OSPAR for reducing discharges and losses of mercury, with a view to reducing its presence in the marine areas to concentrations of close to zero before 2020 /57/. 5.38 Low boiling point naphtha, which contains carcinogenic substances (benzene ³ 0.1% by volumeCAS/EINECS Nos.:
Product groups: Undercoats Serigraphic dyes Surface-treatment products Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /25/ (EU Directive on restriction of the marketing and use of certain dangerous products) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /36/ (Danish EPA information on B values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.39 Maleic anhydrideCAS No.: EINECS No.: Synonym: Product groups: Paints and varnishes Binding agents Fillers Wax and other polishes for flooring Undercoats Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /67/ (Danish EPA guideline on the restriction of air pollution by enterprises), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.40 Mercaptobenzothiazole (MBT)CAS No.: EINECS No.: Synonym: Product groups: Reason for selection: Goals: Restrictions on the use of this substance is desired because of its impact on the health. Prohibited or restricted use in natural-rubber dummies is under consideration. Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.41 MesityleneCAS No.: EINECS No.: Synonym: Product groups: Undercoats thinners (for paints, varnishes, adhesives, etc.) Solvents Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /122/ (EU Directive on the protection of employees) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.42 MethenamineCAS No.: EINECS No.: Synonym: Product groups: Cosmetics Reason for selection: Systematically selected because of its classification. Primarily problematical due to the extent to which it is used in consumer products. Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.43 (1-Methyl-1,2-ethanediyl)bis [oxy(methyl-2,1-ethanediyl)]diacrylateCAS No.: EINECS No.: Synonym: Product groups: Printing inks Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.44 MethylmethacrylateCAS No.: EINECS No.: Synonym: Product groups: Undercoats Binding agents Adhesives Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /36/ (Danish EPA information on B values) Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /91/ (EU Regulation on List I), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution) Activities: 5.45 Musk xylenesCAS No.: Synonym: Product groups: Cosmetics Reason for selection: Goals: Restrictions on these substances are desired because their diffuse distribution in the marine environment. Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: Working environment: Miscellaneous regulations: /6/ (European Commission directive on high-priority substances), /93/ (EU regulation on List III), /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM) Activities: Undergoing assessment under the directive on cosmetic products. Musk xylenes musk xylene (CAS No. 81-15-2) and musk ketone (CAS No. 81-14-1) are undergoing risk assessment in the EU. Reporting state: Holland. Additional regulatory initiatives are pending on this assessment. Work is in progress on initiatives in OSPAR for reducing discharges and losses of musk xylenes, with a view to reducing their presence in the marine areas to concentrations of close to zero before 2020 /57/. 5.46 Methyl tertiary-butylether (MTBE)CAS No.: EINECS No.: Product groups: Reason for selection: Goals: Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances) Activities: Included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. Undergoing risk assessment in the EU. Reporting state: Finland. Additional regulatory initiatives are pending on this assessment. Danish EPA Environmental Project No. 511, "Toxicological evaluation and limit values for methyl tertiary-butyl ether (MTBR), formaldehyde, glutaraldehyde and furfural" was published at the beginning of 2000. 5.47 Sodium and calcium hypochloriteCAS Nos.: 1. 7681-52-9 (Sodium hypochlorite) 2. 7778-54-3 (Calcium hypochlorite) EINECS Nos.: 1. 231-668-3 2. 231-908-7 Product groups: Cleaning products Reason for selection: Risk of the liberation of chlorine gases by contact with acids (when mixed with other cleaning products). Primarily problematical due to the extent to which it is used in consumer products. Classification: Calcium hypochlorite (CAS No. 7778-54-3): oxidising (R 8), harmful to the health (R 22), toxic gas is liberated by contact with acids (R 31), corrosive (R 34) and harmful to the environment (R 50). Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Sodium hypochlorite (CAS No. 7681-52-9) is undergoing risk assessment in the EU. Reporting state: Italy. Additional regulatory initiatives are pending on this assessment. An information campaign aimed at the consumer will be launched during 2000. 5.48 Nickel in certain applications and nickel compoundsCAS Nos.: Product groups: Jewellery, buckles, spectacles, etc. Pigments Tyres Certain nickel-plated products Reason for selection: Goals: Restrictions on these substances are desired because their harmful effects on the health. Restrictions on these substances are desired because of the concentrations found, and because of their impact on the health and environment, in connection with the use of residuals, such as slags, compost and sludge. Classification: Nickel (CAS No. 7440-02-0): carcinogenic (Carc3; R 40) and sensitising (R 43). Nickel monoxide (CAS No. 1313-99-1), nickel dioxide (CAS No. 12035-36-8), nickel sulphide, dinickel trioxide (CAS No. 1314-06-3), trinickel disulphide (CAS No. 12035-72-2): carcinogenic (Carc1; R 49) and sensitising (R 43). Nickel sulphate (EINECS No. 232-104-9): carcinogenic (Carc3; R 40), harmful to the health (R 22), sensitising (R 42/43) and harmful to the environment (R 50/53) . Nickel carbonate (CAS No. 3333-67-3): carcinogenic (Carc3; R 40), harmful to the health (R 22) and sensitising (R 43). Nickel dihydroxide (CAS No. 12054-48-7): carcinogenic (Carc3; R 40), harmful to the health (R 20/22) and sensitising (R 43). Nickel carbonyl (CAS No. 13463-39-3): toxic to reproduction (Rep2; R 61), carcinogenic (Carc3; R 40) very toxic (R 26) and highly flammable (R 11). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /60/ (EU Directive on the risk of major incidents involving dangerous substances), /117/ (Danish EPA Statutory Order on prohibition of products containing Ni), /134/ (Water Framework Directive) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /67/ (Danish EPA guideline on the restriction of air pollution by enterprises), /95/ (Danish EPA Statutory Order on Cd in fertiliser) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /31/ (Danish EPA Statutory Order, the "Risk" Statutory Order), /62/ (Danish EPA Statutory Order on waste), /101/ (Danish EPA Statutory Order on sealed Ni-Cd batteries), /109/ (Danish EPA guideline on industrial waste water), /136/ (HELCOM) Activities: The EU directive (94/27/EEC), on the restriction of nickel in certain applications in which it can come into direct contact with the skin for long periods, has been adopted. New Statutory Orders on the prohibition, importing and sale of certain products containing nickel have been published and enter into force on 20 July 2000. The new regulations represent a tightening of the present Danish regulations. Nickel (CAS No. 7440-02-0), nickel sulphate (CAS No. 7786-81-4), nickel carbonate (CAS No. 3333-67-3), nickel dinitrate (CAS No. 13138-45-9) and nickel dichloride (CAS No. 7718-54-9) are undergoing risk assessment in the EU. Reporting state: Denmark. Additional regulatory initiatives are pending on this assessment. An EU Directive is on the way, which will limit the amounts, e.g., of nickel, in the air. The intention is to sort products containing these substances out of the waste stream with a view to special waste treatment. 5.49 Organo-tin compoundsCAS Nos.: Product groups: Anti-fouling products Reason for selection: Goals: Restrictions on these substances are desired because of the concentrations found, and because of their impact on the health and environment, in connection with the use of residuals, such as sludge. Restrictions on these substances are desired because of their harmful effects on the health and/or the environment. No knowledge of substitution alternatives is available for certain areas of application, and work is needed to find technically and economically feasible alternatives in the future. Classification: Bis(tris(2-methyl-2-phenylpropyl)tin) oxide (CAS No. 13356-08-6): harmful to the health (R 21) and local irritant (R 36/38). Tin(II) methane sulphonate (CAS No. 53408-94-9): sensitising (R 43), harmful to the health (R 22) and corrosive (R 34). Tributyltin compounds: toxic (R25 - R48/23/25), harmful to the health (R 21) and local irritant (R 36/38). Tricyclohexyltin hydroxide (CAS No. 13121-70-5): harmful to the health (R 20/21/22). Tricyclohexyltin compounds: harmful to the health (R 20/21/22). Triethyltin compounds: very toxic (R 26/27/28). Trihexyltin compounds: harmful to the health (R 20/21/22). Trimethyltin compounds: very toxic (R 26/27/28). Trioctyltin compounds: Local irritant (R 36/37/38). Tripentyltin compounds: harmful to the health (R 20/21/22). Triphenyltin acetate (CAS No. 900-95-8): very toxic (R 26), toxic (R 24/25), local irritant (R 36/38), sensitising (R 43) and harmful to the environment (R 50/53). Triphenyltin compounds, miscellaneous: toxic (R 23/24/25). Tripropyltin compounds, miscellaneous: toxic (R 23/24/25). Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /21/ (Danish EPA Statutory Order on restricting the sale and use of certain chemical substances, 1991), /66/ (Danish EPA guideline on the classification etc., of chemical substances and products), /118/ (Danish EPA Statutory Order on pesticides), /134/ (Water Framework Directive) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /36/ (Danish EPA information on B values), /102/ (Danish EPA guideline on surface treatment of ships) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Prohibition or restrictions on the use of bis(tributyltin) oxide (CAS No. 56-35-9) are under consideration in the EU. Denmark is participating in negotiations under the IMO (International Maritime Organisation), on a prohibition against TBT (tributyltin) in paints for ships. It appears that the application of paint containing TBT will be prohibited from 1 January 2003. in 2008, no TBT must be found on ships' hulls. The prohibition against TBT will encompass national and international shipping. Work is in progress on initiatives in OSPAR for reducing discharges and losses of organic tin, with a view to reducing their presence in the marine areas to concentrations of close to zero before 2020 /57/. 5.50 Surfactants which do not degrade completely under anaerobic conditionsCAS No.: Synonym: LAS (linear alkylbenzene sulphonates), certain secondary alkane sulphonates and certain sulphosuccinates. Product groups: Reason for selection: Cut-off value of LAS in a sludge matrix. Classification: Present regulation: /11/ (voluntary agreement between the Danish EPA and the Association of Danish Cosmetics, Toiletries, Soap and Detergent Industries), /16/ (Danish EPA Statutory Order on classification, etc.), /98/ (Danish EPA Statutory Order on surfactants in detergents and cleaning products) Quality criteria/limit values: /3/ (Danish EPA Statutory Order on waste products intended for agricultural purposes), /34/ (Danish EPA Statutory Order on surface water used for drinking water), /54/ (Danish EPA: quality requirements on soil and drinking water), /55/ (Danish EPA: soil-quality criteria) Working environment: Miscellaneous regulations: /119/ (Danish EPA Statutory Order on detergents and cleaning products), /109/ (Danish EPA guideline on industrial waste water) Activities: LAS is included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. Mapping the occurrence and fate of selected substances (LAS) in all media of the environment within a geographically demarcated area. National Environmental Research Institute project on substances alien to the environment. Expected date of completion: 2000. To be further assessed with a view to classification. 5.51 2,2,4,6,6-Pentamethyl heptaneCAS No.: EINECS No.: Product groups: Anti-rust products Polishes and car-care products Varnish-care products Releasing agents, including mould releasing agents for plastics Solvents Adhesives Reason for selection: Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: To be further assessed with a view to classification as an environmental hazard. 5.52 Perfluorinated hydrocarbons, e.g., CF4, C2F6, C3F8CAS/EINECS Nos.: Perfluoroethane (C2f6) (CAS No. 76-16-4, EINECS No. 200-939-8) Octafluoropropane (C3f8) (CAS No. 76-19-7, EINECS No. 200-941-9) Product groups: Protective gases Reason for selection: Goals: Restrictions on these substances are desired because of their severe greenhouse effect. Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Several projects have been launched with respect to substitution alternatives for greenhouse gases in selected products. Funding from the the Cleaner Products Support Programme, etc., Danish EPA 5.53 PhenolCAS No.: EINECS No.: Product groups: Undercoats (primers) Binding agents for casting/moulding, paints, adhesives, etc. Adhesives Jointing compounds Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /34/ (Danish EPA Statutory Order on surface water used for drinking water), /36/ (Danish EPA information on B values), /54/ (Danish EPA: quality requirements on soil and drinking water) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /67/ (Danish EPA guideline on the restriction of air pollution by enterprises), /109/ (Danish EPA guideline on industrial waste water), /129/ (Danish EPA Statutory Order on sites contaminated by tar/asphalt), /130/ (Danish EPA guideline on sites contaminated by wood-impregnation activities) Activities: Undergoing risk assessment in the EU. Reporting state: Germany. Additional regulatory initiatives are pending on this assessment. Mapping its occurrence and fate in all media of the environment within a geographically demarcated area. National Environmental Research Institute project on substances alien to the environment. Expected date of completion: 2000. 5.54 Phenol, 4,4'-(1-methylethylidene)bis, polymer with 2,2-((1-methylethylidene)bis)CAS No.: EINECS No.: Product groups: Reason for selection: Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: To be assessed with a view to classification as an environmental hazard. 5.55 Phenol, methyl-CAS No.: EINECS No.: Synonym: Product groups: Solvent-based adhesives Paints and varnishes Undercoats Sealing compounds Fuel additives Anti-rust products Fillers Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: The Danish EPA's Chemical Inspection Service will investigate the use of this substance in consumer products during 2001-2002. 5.56 PhthalatesCAS Nos.: Di-(2-ethylhexyl) phthalate (CAS No. 117-81-7, EINECS No. 204-211-0) Bis(2-methoxyethyl) phthalate (CAS No. 34006-76-3) p-Dibutyl phthalate (CAS No. 1962-75-0, EINECS No. 217-803-9) Butyl benzyl phthalate (CAS No. 85-68-7, EINECS No. 201-622-7) Diisodecyl phthalate (CAS No. 26761-40-0, EINECS No.249-977-1) Diisononyl phthalate (CAS No. 28553-12-0, EINECS No.249-079-5) Dibutyl phthalate (CAS No. 84-74-2; EINECS No.201-557-4) Product groups: Toys Paints, varnishes and printing inks Cosmetics Adhesives and filler products Reason for selection: Problematical substances in the waste cycle, especially in sludge and compost. Bis(2-methoxyethyl)phthalate (CAS No. 34006-76-3) has also been selected because of its classification. Goals: Restrictions on these substances are desired because of the concentrations found, and because of their impact on the health and environment, in connection with the use of residuals, such as slags, compost and sludge. Restrictions on these substances are desired because of their harmful effects on the health. Classification: The other phthalates are not on the List of Dangerous Substances /1/. Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /58/ (Danish EPA Statutory Order on the prohibition of phthalates in toys), /134/ (Water Framework Directive), /139/ (Ministry of Taxation Act on surcharges on PVC and phthalates) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /36/ (Danish EPA information on B values), /121/ (EU Directive on pollution from combustion engines) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /136/ (HELCOM) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /67/ (Danish EPA guideline on the restriction of air pollution by enterprises), /109/ (Danish EPA guideline on industrial waste water), /120/ (Danish EPA Statutory Order on ships' stowage logs) Activities: The Act on surcharges on PVC and phthalates in certain products will enter into force on 1 July 2000. Several projects have been launched with respect to substitutes for phthalates in PVC and other products. Funding from the the Cleaner Products Support Programme, etc., (Danish EPA). Mapping the occurrence and fate of selected substances (DBP, BBP, DEHP and DOP) in all media of the environment within a geographically demarcated area. National Environmental Research Institute project on substances alien to the environment. Expected date of completion: 2000. A report on phthalates in paints, varnishes, printing inks and cosmetics is expected during the autumn of 2000. A project concerned with alternatives has been launched and is expected to be completed at the end of 2000. Butylbenzyl phthalate (CAS No. 85-68-7) and di(2-ethylhexyl)phthalate (DEHP) (CAS No. 117-81-7) are included in the national surveillance programme for the aquatic environment 1998-2003, also called NOVA 2003 /20/. Dibutyl phthalate (CAS No. 1962-75-0) and dioctyl phthalate (CAS No. 117-81-7) are undergoing risk assessment (including an assessment of whether or not these substances should be classified) in the EU. Reporting state: Holland. Diisodecyl phthalate (DIDP, CAS No. 26761-40-0) and diisononyl phthalate (DINP, CAS No. (14103-61-8 or 68515-48-0)) are undergoing risk assessment in the EU. Reporting state: France. Diethylhexyl phthalate (CAS No. 1330-92-3) is undergoing risk assessment in the EU. Reporting state: Sweden. Butylbenzyl phthalate (CAS No. 85-68-7) is undergoing risk assessment in the EU. Reporting state: Norway. Work is in progress on initiatives in OSPAR for reducing discharges and losses of dibutyl phthalate and diethylhexyl phthalate, with a view to reducing their presence in the marine areas to concentrations of close to zero before 2020 /57/. 5.57 Phthalic anhydrideCAS No.: EINECS No.: Synonym: Product groups: Binding agents Fillers Serigraphic dyes Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.58 Simple hydrocarbons (carbon hydrides)5.58.1 n-HexaneCAS No.: EINECS No.: Product groups: Cleaning products Anti-rust products Releasing agents, including mould releasing agents for plastics and other applications Lubricants Paints Adhesives Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water), /125/ (Danish EPA guideline on air pollution) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.58.2 HeptaneCAS No.: EINECS No.: Synonym: Product groups: Thinners (for paints, varnishes, adhesives and suchlike) Cleaning products Degreasing agents Promoters Solvents Lubricants, including lubricating greases, lubricating oils, etc. Releasing agents Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: An information campaign aimed at consumers will be launched during 2000. This campaign will give information on the necessary precautions when using such products as paints and varnishes. 5.59 Sulfamic acidCAS No.: EINECS No.: Product groups: Paint and varnish hardeners Sanitation products for lavatories surface-treatment products for metals (not paints, etc.) Products for pH regulation (buffers) Dyes Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.60 Sulphur hexafluorideCAS No.: EINECS No.: Product groups: Insulators Protective gases Reason for selection: Goals: Restrictions on this substance are desired because of its severe greenhouse effect. Classification: Present regulation: /16/ (Danish EPA Statutory Order on classification, etc.), /59/ (Danish EPA Statutory Order on propellants and solvents in aerosol canisters) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values) Working environment: /88/ (Directorate of Labour Inspection Statutory Order on volatile substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.61 Coal-tar productsCAS Nos.: 2. 65996-93-2 (coal-tar pitch) 3. 61789-60-4 (pitch, which contains more than 50 ppm benzo(a)pyrene) EINECS No.: 2. 266-028-2 3. 263-072-4 Product groups: Paints and varnishes Binding agents, e.g., for paints, adhesives, etc. Jointing compounds Anti-rust products Undercoats Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: Working environment: /5/ (Directorate of Labour Inspection instruction on suppliers' instructions for use of products), /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /93/ (EU regulation on List III), /109/ (Danish EPA guideline on industrial waste water), /124/ (EU Directive on cosmetics) Activities: 5.62 1,2,4-TrichlorobenzeneCAS No.: EINECS No.: Product groups: Paint and varnish strippers Solvents Reason for selection: Restrictions on this substance are desired because of its diffuse distribution in the marine environment. Goals: Restrictions/phasing out of this substance are desired because of the concentrations found in groundwater. Restrictions on this substance are desired because of its harmful properties with respect to the health. Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /134/ (Water Framework Directive) Quality criteria/limit values: /22/ (National Working Environment Authority instruction on limit values), /30/ (Danish EPA Statutory Order on waters and requirements on discharges), /108/ (Danish EPA Statutory Order on List-1 substances) Working environment: Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Undergoing risk assessment in the EU. Reporting state: Denmark. Denmark is planning the drafting of a risk-reduction strategy. 5.63 Tris(2-chloroethyl)phosphateCAS No.: EINECS No.: Product groups: Flame-retardant additives for textiles, plastics, etc. Casting/moulding compounds/materials, including jointing compounds Adhesives and varnishes Surface-treatment products for metals (not paints, etc) Non-galvanic metal plating (chromium plating, etc) Solvents Reason for selection: Goals: Restrictions on this substance are desired because of its harmful effects on the health and environment. Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: This substance is undergoing risk assessment in the EU. Reporting state: Germany. Additional regulatory initiatives are pending on this assessment. 5.64 Distillates (petroleum), heavy paraffinicCAS No.: EINECS No.: Product groups: Mould oils and shuttering wax used in building industry Anti-rust products Coolants/lubricants Metal surface-treatment products Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /15/ (Danish EPA Statutory Order on restricting the sale and use of certain dangerous chemical substances, 1997), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: /36/ (Danish EPA information on B values) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work), /17/ (Directorate of Labour Inspection Statutory Order on the prevention of cancer risks, 1997), /56/ (Ministry of Labour Statutory Order on the registration of carcinogenic substances) Miscellaneous regulations: /6/ (European Commission directive on high-priority substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.65 Selected substances in "perfume products"CAS/EINECS Nos.: List A:
List B: Perfume ingredients, which are under observation. There are firm suspicions that these substances can cause allergies /140/.
Product groups: Reason for selection: d-Limonene (CAS No. 5989-27-5) has also been systematically selected, since it also finds other applications, e.g., as a solvent. Goals: Restrictions are desired on these substances because of their harmful effects on the health. Classification: Benzylalcohol (CAS No. 100-51-6): harmful to the health (R 20/22). Benzylbenzoate (CAS No. 120-51-4): harmful to the health (R 22). Citral (CAS No. 5392-40-5): local irritant (R 38) and sensitising (R 43). d-Limonen (CAS No. 5989-27-5): flammable (R 10), local irritant (R 38), sensitising (R 43), and harmful to the environment (R 50/53). Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /28/ (Danish EPA Statutory Order on cosmetic products) Quality criteria/limit values: /36/ (Danish EPA information on B values) Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: Amendment of the regulations of the EU Directive on cosmetic products is under consideration, so that declarations shall also include information on substances used in perfumes. 5.66 Unspecified gas oil with carcinogenic propertiesCAS Nos.: 2. 64742-13-8 (distillates (petroleum), acid-treated medium heavy) EINECS Nos.: 2. 265-113-1 Product groups: Dessicants Degreasing agents Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.), /25/ (EU Directive on restriction of the marketing and use of certain dangerous substances), Quality criteria/limit values: Working environment: /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: 5.67 Petroleum distillates, which contain carcinogenic substances (DMSO-extract ³ 3%)CAS/EINECS Nos.: 2. Distillates (petroleum), hydrogen-treated heavy naphthene- (CAS No. 64742-52-5, EINECS No. 265-155-0) 3. Distillates (petroleum), solvent-dewaxed heavy paraffin- (CAS No. 64742-65-0, EINECS No. 265-169-7) 4. Distillates (petroleum), solvent-refined heavy paraffin- (CAS No. 64741-88-4, EINECS No. 265-090-8) 5. Distillates (petroleum), solvent-refined heavy naphthene- (CAS No. 64741-96-4, EINECS No. 265-097-6) Product groups: Solvent products (for offset plates, etc.) (plate cleaners) Anti-rust products Releasing agents, including mould releasing agents for plastics and other applications Surface-treatment products Fuel additives Reason for selection: Classification: Present regulation: Quality criteria/limit values: Working environment: /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /7/ (EU Regulation on the risks of existing substances), /109/ (Danish EPA guideline on industrial waste water) Activities: The Danish EPA's Chemical Inspection Service will investigate the use of these substances in consumer products during 2001-2002. 5.68 ZinebCAS No.: EINECS No.: Product groups: Ships' undercoats Reason for selection: Classification: Present regulation: /1/ (List of Dangerous Substances), /16/ (Danish EPA Statutory Order on classification, etc.) Quality criteria/limit values: Working environment: /12/ (Directorate of Labour Inspection Statutory Order on setting code numbers), /13/ (Directorate of Labour Inspection Statutory Order on working with code-numbered products), /14/ (Ministry of Labour on young people at work) Miscellaneous regulations: /109/ (Danish EPA guideline on industrial waste water) Activities: Undergoing classification as an environmental hazard in the EU. |