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Cleaner Technology Projects in Denmark 1996
VOC Reduction in the Printing Industry
VOC-reduktion i grafisk industri
Miljørapport nr. 339, 1996, Miljøstyrelsen
In the external environment, volatile organic compounds (VOC) contribute to
photochemical air pollution. The environmental effects are transboundary as well as
regional. This publication summarises the types of cleaner technology solutions, which are
useable for reducing the emission of volatile organic compounds from the printing
industry. The structure of the publication is based on the production process of printed
matter from prepress to finishing.
Each chapter covers each printing method and the activities, which contribute to
the VOC emissions. Subsequently, the cleaner technologies which can reduce the emissions
immediately, and the technologies which imply certain changes of technical, economic or
developing characters are described. At the end of each chapter, the traditional cleaning
technologies are briefly mentioned as an alternative if the suggested cleaner technology
solution is not sufficient.
Today, prepress work is mainly made on computers (electronic data processing) but the
processes still include use of photographic materials. For the development of these, the
use of VOC is insignificant.
Flexographic printing is the most widely used relief printing method, especially for
printing on packaging made of corrugated cardboard, paper and plastics and for wrapping
paper, bags, labels, etc. As suppliers develop water washout printing plates the
VOC-emission from plate making can be reduced. It is possible to change from solvent-based
to water-based flexo inks when printing on paper, cardboard and corrugated board. The use
of water-based flexo inks for printing on plastics is possible to a certain degree but a
wider use of the technology demands further development. It is expected that it will soon
be possible to increase the use of UV-curing flexo inks but development of know-how and
large investments are necessary.
As for replacement of VOC rinsing of the flexo machine parts, either high-pressure
flushing or ultrasound rinsing can be used under certain conditions.
Letterset is used for printing on plastic buckets and cups. Today, the printing inks
are UV-curing and do not contain VOC. However, VOC is used for rinsing the printing
machines. Vegetable oil can be used instead when rinsing printing plates, rubber blankets,
and inking rollers.
Letterpress is used for printing adhesive labels. The plates for letterpress printing
are today washed out with pure water and the printing inks are UV-curing without solvents.
The consumption of VOC for rinsing is minor and can be substituted with vegetable oil.
Offset in different forms is used for printing leaflets, catalogues, books, newspapers,
magazines, cardboard boxes, tin cans, etc. The emission of VOC derives from alcohol in the
fountain water and the use of white spirit and the like for the cleaning of the machines.
In tin printing, varnishing causes emission of VOC. However, at manual rinsing it is
possible to reduce the use of VOC by substituting white spirit with vegetable oils. The
use of VOC in automatic rinsing can be reduced as new machines fit for cleaning with
vegetable oils are introduced.
It is possible to reduce the amount of alcohol in the fountain water or to avoid the
use of alcohol in web offset. If the necessary know-how is developed and investments are
made on equipment for temperature control, the companies can use a relatively new method,
waterless offset where fountain water - and consequently alcohol - is not used.
When successfully developed, water-based or UV-curing varnishes presumably will be used
for the varnishing in tin printing.
There is a distinction between publication gravure and packaging gravure when it comes
to machines and printing inks. Publication gravure is used for printing magazines while
packaging gravure is used for long-term printing of flexible packaging made of paper,
plastics, metal foil, and laminates. The emission from publication gravure is reduced by
recovering the solvent from the printing ink. The solvents from packaging gravure cannot
be recovered.
Cylinder making implies only sporadic use of organic solvents if any.
Water-based printing ink is a potential possibility for VOC-reduction in publication as
well as in packaging gravure but the inks are still in the experimental stage. UV-curing
gravure inks have not yet been tested.
Powder cleaning or even ultrasound cleaning can be used for cleaning machine parts
under certain conditions.
Screen-printing is used for printing signs, posters, labels, t-shirts, etc. It can be
used for printing on paper, plastics, textiles, glass and metal. Solvents are only used
sporadically for the stencil making.
It is possible to use water reducible screen printing inks for printing on thick paper
and cardboard. Water reducible as well as UV-curing inks can be used for printing on
certain types of plastics (PVC, PC, PS, acrylics and possibly more) if the surface is well
treated. The use of UV-curing inks implies investments in UV-lamps and can cause health
problems for the workers. The use of water-based or certain water-reducible UV-curing
screen printing inks open a possibility for using waterbased cleaning agents.
Solvent waste from the cleaning of screen printing frames can be regenerated if the
necessary equipment is installed.
Finishing of printed matter includes gluing, varnishing and laminating. Gluing causes
an insignificant use of solvents.
VOC emission can occur from the adhesive when printed paper is laminated with a thin
plastic film. There is no immediately useable solution in the form of cleaner technology.
Author/ institution
Susanne Møller, Dansk Teknologisk Institut.
Erik Silfverberg, Gitte Gladding og Rikke Dreyer; Den Grafiske Højskole.
This report is subsidies by the National Council for Recycling and Cleaner Technology.
ISSN no. 0908-9195
ISBN no. 87-7810-541-2
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