Guidelines for Air Emission Regulation

Table 11.
Recommended methods for measurement of air pollution from installations (emission): Methods for performance monitoring and random testing
   

Substance group

Parameter

Recommended method

Standard

Title

Measurement range

Note

Dust

Particles measured as total dust

VDI 2066, Sheet 2 (1993)

Messen von Partikeln;
Manuelle Staubmessung in strömenden Gasen; Gravimetrische Bestimmung der Staubbeladung; Filterkopfgeräte (4 m 3 /h & 12m 3 /h)

1-1,000 mg/m³

To be used for measurement of high concentrations (> 50 mg/m³)

PrEN 13284-1 (1999)

Stationary source emissions. Determination of low range mass concentration of dust.

0-50 mg/m³

To be used for measurement at low concentrations (<50 mg/m³)

Particles <10mm

VDI 2066/Sheet 2. (1993)

Messen von Partikeln; Manuelle Staubmessung in strömenden Gasen; Gravimetrische Bestimmung der Staubbeladung; Filterkopfgeräte (4 m 3 /hr & 12m 3 /hr)

1-1,000 mg/m³

To be used for measurement of particles <10 µm

Inorganic compounds

 

Carbon monoxide (CO)

US EPA Method 10 (1995)

Determination of Carbon Monoxide Emissions From Stationary Sources. rev. 4.

0-1,000 ppm (0-1,250 mg/m3)

 

Nitrogen oxides (NOX)

US E.P.A. Method 7E, rev. 1 (1985)

Determination of nitrogen oxide emissions from stationary sources. Instrumental analyzer procedure.

Not stated

 

Hydrogen chloride (HCl)

DS/EN 1911, parts 1-3 (1997)

Luftundersøgelse. Emissioner fra stationære kilder. Manuel bestemmelse af HCl.

1 – 5,000 mg/m3

 

Hydrogen fluoride (HF)

VDI 2470, Sheet 1 (1975)

Messung gasförmiger Emissionen. Messen gasförmiger Fluor-Verbindungen. Absorptions- Verfahren.

0.05 – 200 mg F - /m3.

 

 

Sulphur dioxide (SO2 )

ISO 7934 (1989) and the appendix Amd. 1 (1998)

Stationary source emission – Determination of the mass concentration of sulfur dioxide –hydrogen peroxide/ barium-perchlorate/ Thorin method.

30-2,000 mg/m3

Inspectors may choose between the two methods used to determine SO2 contents

DS/ISO 11632 (1998)

Emissioner fra stationære kilder – Bestemmelsen af massekoncentrationen af svovldioxid – Ionchromatografisk metode.

6-333 mg/m3

Inspectors may choose between the two methods used to determine SO2 contents

Hydrogen sulphide (H2S)

US EPA Method 11 (1978)

Determination of Hydrogen Sulfide Content of Fuel Gas Streams in Petroleum Refineries

Not stated

 

Metals

Mercury (Hg)

Final draft PrEN 13211 (2000)

Air quality – Determination of the concentration of total mercury in stationary source emissions.

0.001-0.5 mg/m3

 

 

Arsenic (As), Cadmium (Cd), Cobalt (Co), Chromium (Cr), Copper (Cu), Manganese (Mn), Nickel (Ni), Lead Pb), Antimony (Sb), Thallium (Tl), and Vanadium (V).

CEN/TC 264 N404 (WI 00264013) (2000)

Determination of Total Emission of Specific Elements.

No final range

Not yet adopted by the CEN, but sufficiently far advanced to be recommended as a method.

Until this standard is formally adopted, US EPA Method 29, VDI 3868 Bl.1 and VDI 2268 may be used. Particles should be measured according to US EPA Method 29 (plan filter), Gaseous metals should be measured according to VDI 3868 Bl. 1, and digestion of filter and analyses should be carried out according to VDI 2268.

Volatile organic compounds

(VOC)

Total organic carbon (TOC)

EN 12619:1999

Stationary source emissions  Determination of the mass concentration of total gaseous organic carbon at low concentrations in flue gasses – continuous flame ionisation detector method

0-20mg C/m³(n)

Used for measurement of flue gases.

The measurement range may be extended until a new standard becomes available for measurement of flue gases at high levels, (prEN 13526) is available.

 

 

VDI 3481 sheet 3 (1995)

Determination of volatile organic compounds, especially solvents – FID

From 1-2 mg C/m³

Used for measurement in outlets without combustion.

Secondary parameters

 

 

Secondary parameters (continued)

Volume flow

ISO 10780 (1994)

Stationary Source Emissions – Measurement of velocity and volume flow-rate of gas streams in ducts

5- 50 m/s

 

Carbon dioxide (CO2) Oxygen (O2)

US EPA Method 3A (1989)

Determination of Oxygen and Carbon Dioxide Concentrations in Emissions From Stationary Sources

Not stated

 

Water (H2O)

US EPA Method 4 (1977) (Rev. 3, 5/94)

Determination of Moisture Content in Stack Gases

Not stated

 

Temperature

IEC Publication 584-2 (1989)

Thermocouples

Down to -40 °C, up to 1,600 °C (depending on type) (tolerance class 2).