ASE ekstraktionsdata 1
| Dato: |
1/27/99 |
1/27/99 |
1/27/99 |
1/27/99 |
1/27/99 |
1/27/99 |
| Apparat': |
ASE |
ASE |
ASE |
ASE |
ASE |
ASE |
| Metode: |
EPA 3545A |
EPA 3545 A |
EPA 3545 A |
EPA 3545 A |
EPA 3545 A |
EPA 3545 A |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
Mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
96.67 |
1.53 |
1.58 |
100 |
5.29 |
5.29 |
| Biphenyl d10 |
94.33 |
3.51 |
3.72 |
99 |
6.43 |
6.47 |
| Phenanthren d10 |
98.67 |
5.13 |
5.20 |
105 |
6.93 |
6.60 |
| Flouranthen d10 |
101.00 |
1.00 |
0.99 |
104 |
6.66 |
6.38 |
| Pyren d10 |
101.67 |
1.15 |
1.14 |
104 |
6.56 |
6.31 |
| Benz(a)pyren d12 |
90.00 |
7.21 |
8.01 |
96 |
6.56 |
6.83 |
| Dibenzo(a,h)anthracen d14 |
91.67 |
12.34 |
13.46 |
97 |
10.50 |
10.87 |
| Naphthalen |
0.54 |
0.02 |
3.00 |
0.11 |
0.00 |
1.59 |
| Acenaphthylen |
0.57 |
0.03 |
4.89 |
0.10 |
0.00 |
4.60 |
| Acenaphthen |
0.20 |
0.01 |
2.78 |
0.03 |
0.00 |
2.01 |
| Fluoren |
0.59 |
0.02 |
3.58 |
0.09 |
0.00 |
1.14 |
| Phenanthren |
7.19 |
0.25 |
3.53 |
0.85 |
0.02 |
2.14 |
| Anthracen |
1.30 |
0.02 |
1.53 |
0.18 |
0.01 |
4.75 |
| Fluoranthen |
12.69 |
0.65 |
5.13 |
1.53 |
0.02 |
1.01 |
| Pyren |
11.15 |
0.40 |
3.62 |
1.32 |
0.01 |
0.59 |
| Benz(a)anthracen |
4.17 |
0.15 |
3.52 |
0.65 |
0.02 |
3.47 |
| Chrysen/Triphenylen |
4.34 |
0.15 |
3.43 |
0.73 |
0.01 |
1.35 |
| Benzo(b+j+k)fluoranthen |
8.38 |
0.22 |
2.58 |
1.49 |
0.07 |
4.66 |
| Benzo(a)pyren |
4.60 |
0.14 |
3.05 |
0.22 |
0.00 |
1.45 |
| Indeno(1,2,3-cd)pyren |
3.75 |
0.15 |
3.93 |
0.66 |
0.01 |
0.81 |
| Dibenzo(a,h)anthracen |
0.59 |
0.07 |
12.36 |
0.12 |
0.00 |
0.50 |
| Benzo(g,h,i)perylen |
3.68 |
0.15 |
4.06 |
0.62 |
0.00 |
0.52 |
| Sum 16 EPA PAH |
64 |
1.5 |
2.3 |
8.7 |
0.1 |
1.1 |
| Sum 7 PAH |
30 |
1.1 |
3.7 |
4.0 |
0.1 |
1.8 |
ASE ekstraktionsdata 2
| Dato: |
9/2/99 |
9/2/99 |
9/2/99 |
9/2/99 |
9/2/99 |
9/2/99 |
| Apparat': |
ASE |
ASE |
ASE |
ASE |
ASE |
ASE |
| Metode: |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
30 |
30 |
30 |
30 |
30 |
30 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
102.67 |
17.39 |
16.94 |
111 |
5.03 |
4.55 |
| Biphenyl d10 |
98.33 |
15.53 |
15.80 |
106 |
4.51 |
4.24 |
| Phenanthren d10 |
106.00 |
18.36 |
17.32 |
122 |
0.58 |
0.47 |
| Flouranthen d10 |
97.00 |
18.33 |
18.90 |
108 |
2.52 |
2.32 |
| Pyren d10 |
100.33 |
19.14 |
19.08 |
108 |
1.53 |
1.41 |
| Benz(a)pyren d12 |
98.33 |
17.79 |
18.09 |
111 |
4.16 |
3.76 |
| Dibenzo(a,h)anthracen d14 |
106.33 |
17.16 |
16.13 |
123 |
5.51 |
4.47 |
| Naphthalen |
0.62 |
0.11 |
17.14 |
0.10 |
0.01 |
6.89 |
| Acenaphthylen |
0.67 |
0.12 |
18.28 |
0.11 |
0.00 |
3.27 |
| Acenaphthen |
0.22 |
0.03 |
15.43 |
0.03 |
0.00 |
3.57 |
| Fluoren |
0.79 |
0.14 |
17.51 |
0.10 |
0.00 |
1.70 |
| Phenanthren |
8.90 |
1.87 |
20.96 |
0.97 |
0.01 |
0.93 |
| Anthracen |
1.46 |
0.28 |
19.11 |
0.18 |
0.00 |
2.32 |
| Fluoranthen |
13.75 |
2.73 |
19.87 |
1.58 |
0.03 |
1.81 |
| Pyren |
12.58 |
2.39 |
18.99 |
1.35 |
0.04 |
2.86 |
| Benz(a)anthracen |
4.81 |
0.98 |
20.40 |
0.58 |
0.01 |
2.14 |
| Chrysen/Triphenylen |
4.64 |
0.93 |
20.00 |
0.65 |
0.01 |
1.98 |
| Benzo(b+j+k)fluoranthen |
9.12 |
1.55 |
16.95 |
1.51 |
0.02 |
1.33 |
| Benzo(a)pyren |
5.00 |
1.06 |
21.22 |
0.64 |
0.02 |
2.65 |
| Indeno(1,2,3-cd)pyren |
4.04 |
0.73 |
18.16 |
0.65 |
0.02 |
2.69 |
| Dibenzo(a,h)anthracen |
0.77 |
0.13 |
17.31 |
0.13 |
0.01 |
4.39 |
| Benzo(g,h,i)perylen |
3.95 |
0.72 |
18.33 |
0.58 |
0.02 |
3.07 |
| Sum 16 EPA PAH |
63 |
2.0 |
3.2 |
9.1 |
0.1 |
1.2 |
| Sum 7 PAH |
29 |
1.0 |
3.4 |
4.5 |
0.1 |
1.4 |
ASE ekstraktionsdata 3
| Dato: |
10/2/99 |
10/2/99 |
10/2/99 |
10/2/99 |
10/2/99 |
10/2/99 |
| Apparat': |
ASE |
ASE |
ASE |
ASE |
ASE |
ASE |
| Metode: |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
| Opløsningsmiddel: |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
| Gram prøve |
30 |
30 |
30 |
30 |
30 |
30 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
94.50 |
3.54 |
3.74 |
97 |
0.00 |
0.00 |
| Biphenyl d10 |
93.00 |
1.41 |
1.52 |
96 |
1.15 |
1.20 |
| Phenanthren d10 |
106.50 |
4.95 |
4.65 |
111 |
3.06 |
2.76 |
| Flouranthen d10 |
97.50 |
3.54 |
3.63 |
101 |
1.53 |
1.51 |
| Pyren d10 |
97.50 |
3.54 |
3.63 |
102 |
0.00 |
0.00 |
| Benz(a)pyren d12 |
105.00 |
0.00 |
0.00 |
112 |
4.00 |
3.57 |
| Dibenzo(a,h)anthracen d14 |
110.50 |
0.71 |
0.64 |
108 |
2.00 |
1.85 |
| Naphthalen |
0.44 |
0.17 |
39.92 |
0.08 |
0.03 |
42.19 |
| Acenaphthylen |
0.66 |
0.02 |
2.36 |
0.12 |
0.00 |
3.98 |
| Acenaphthen |
0.19 |
0.01 |
7.29 |
0.03 |
0.00 |
8.66 |
| Fluoren |
0.68 |
0.03 |
4.71 |
0.10 |
0.01 |
8.28 |
| Phenanthren |
7.33 |
0.38 |
5.15 |
0.89 |
0.06 |
6.74 |
| Anthracen |
1.27 |
0.05 |
4.25 |
0.18 |
0.01 |
5.45 |
| Fluoranthen |
12.49 |
0.12 |
0.99 |
1.57 |
0.04 |
2.70 |
| Pyren |
10.55 |
0.37 |
3.52 |
1.32 |
0.05 |
4.13 |
| Benz(a)anthracen |
4.10 |
0.09 |
2.31 |
0.56 |
0.01 |
1.89 |
| Chrysen/Triphenylen |
3.91 |
0.01 |
0.34 |
0.61 |
0.01 |
1.41 |
| Benzo(b+j+k)fluoranthen |
7.96 |
0.89 |
11.21 |
1.46 |
0.03 |
2.24 |
| Benzo(a)pyren |
4.31 |
0.07 |
1.72 |
0.64 |
0.01 |
2.21 |
| Indeno(1,2,3-cd)pyren |
3.52 |
0.08 |
2.21 |
0.67 |
0.01 |
1.13 |
| Dibenzo(a,h)anthracen |
0.65 |
0.02 |
2.41 |
0.12 |
0.00 |
2.33 |
| Benzo(g,h,i)perylen |
3.39 |
0.07 |
2.07 |
0.58 |
0.01 |
2.04 |
| Sum 16 EPA PAH |
61.5 |
0.60 |
0.98 |
8.9 |
0.1 |
1.4 |
| Sum 7 PAH |
28.9 |
0.94 |
3.24 |
4.5 |
0.0 |
0.8 |
ASE ekstraktionsdata 4
| Dato: |
10/5/99 |
10/5/99 |
10/5/99 |
10/5/99 |
10/5/99 |
10/5/99 |
| Apparat': |
ASE |
ASE |
ASE |
ASE |
ASE |
ASE |
| Metode: |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
EPA 3545A |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
10g + 1 ml H2O |
10g + 1 ml H2O |
10g + 1 ml H2O |
10g + 1 ml H2O |
10g + 1 ml H2O |
10g + 1 ml H2O |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
61 |
0.00 |
0.00 |
69 |
0.00 |
0.00 |
| Biphenyl d10 |
60 |
0.00 |
0.00 |
71 |
0.00 |
0.00 |
| Phenanthren d10 |
67 |
0.00 |
0.00 |
86 |
0.00 |
0.00 |
| Flouranthen d10 |
57 |
0.00 |
0.00 |
78 |
0.00 |
0.00 |
| Pyren d10 |
60 |
0.00 |
0.00 |
77 |
0.00 |
0.00 |
| Benz(a)pyren d12 |
70 |
0.00 |
0.00 |
83 |
0.00 |
0.00 |
| Dibenzo(a,h)anthracen d14 |
74 |
0.00 |
0.00 |
89 |
0.00 |
0.00 |
| Naphthalen |
0.50 |
0.05 |
9.16 |
0.13 |
0.01 |
7.37 |
| Acenaphthylen |
0.78 |
0.07 |
9.40 |
0.17 |
0.01 |
6.71 |
| Acenaphthen |
0.13 |
0.01 |
5.59 |
0.02 |
0.00 |
4.03 |
| Fluoren |
0.44 |
0.03 |
6.43 |
0.07 |
0.01 |
7.01 |
| Phenanthren |
6.42 |
0.30 |
4.63 |
0.85 |
0.05 |
6.21 |
| Anthracen |
1.04 |
0.06 |
5.59 |
0.19 |
0.01 |
6.61 |
| Fluoranthen |
14.19 |
0.39 |
2.74 |
1.67 |
0.10 |
5.67 |
| Pyren |
12.00 |
0.66 |
5.50 |
1.34 |
0.09 |
6.85 |
| Benz(a)anthracen |
3.91 |
0.24 |
6.05 |
0.63 |
0.04 |
5.66 |
| Chrysen/Triphenylen |
4.14 |
0.06 |
1.46 |
0.76 |
0.06 |
7.64 |
| Benzo(b+j+k)fluoranthen |
8.09 |
0.14 |
1.71 |
1.58 |
0.13 |
7.93 |
| Benzo(a)pyren |
4.00 |
0.23 |
5.64 |
0.63 |
0.06 |
9.83 |
| Indeno(1,2,3-cd)pyren |
3.19 |
0.22 |
6.80 |
0.57 |
0.05 |
8.40 |
| Dibenzo(a,h)anthracen |
0.61 |
0.06 |
9.53 |
0.11 |
0.02 |
13.47 |
| Benzo(g,h,i)perylen |
3.08 |
0.22 |
7.16 |
0.52 |
0.05 |
8.62 |
| Sum 16 EPA PAH |
63 |
2.3 |
3.7 |
9.3 |
0.7 |
7.1 |
| Sum 7 PAH |
30 |
0.7 |
2.3 |
4.6 |
0.3 |
7.5 |
Mikrobølge ekstraktionsdata 1
| Dato: |
1/3/99 |
1/3/99 |
1/3/99 |
1/3/99 |
1/3/99 |
1/3/99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
77 |
0.94 |
1.22 |
79.33 |
6.94 |
8.75 |
| Biphenyl d10 |
78 |
0.47 |
0.60 |
78.33 |
4.50 |
5.74 |
| Phenanthren d10 |
85 |
1.41 |
1.66 |
85.67 |
6.94 |
8.11 |
| Flouranthen d10 |
76 |
1.41 |
1.86 |
76.00 |
4.32 |
5.68 |
| Pyren d10 |
74 |
1.89 |
2.54 |
73.00 |
4.97 |
6.80 |
| Benz(a)pyren d12 |
79 |
2.05 |
2.61 |
74.00 |
5.10 |
6.89 |
| Dibenzo(a,h)anthracen d14 |
77 |
2.62 |
3.42 |
71.00 |
3.74 |
5.27 |
| Naphthalen |
0.81 |
0.03 |
3.76 |
0.15 |
0.00 |
2.73 |
| Acenaphthylen |
0.70 |
0.02 |
3.56 |
0.11 |
0.00 |
3.24 |
| Acenaphthen |
0.21 |
0.01 |
2.92 |
0.03 |
0.00 |
1.46 |
| Fluoren |
0.76 |
0.01 |
0.92 |
0.12 |
0.00 |
3.69 |
| Phenanthren |
7.52 |
0.22 |
2.96 |
1.07 |
0.04 |
3.84 |
| Anthracen |
1.41 |
0.03 |
2.12 |
0.20 |
0.01 |
3.24 |
| Fluoranthen |
12.27 |
0.50 |
4.04 |
1.74 |
0.05 |
3.00 |
| Pyren |
11.11 |
0.10 |
0.92 |
1.38 |
0.04 |
2.91 |
| Benz(a)anthracen |
4.37 |
0.13 |
3.02 |
0.62 |
0.02 |
2.78 |
| Chrysen/Triphenylen |
4.32 |
0.12 |
2.89 |
0.70 |
0.01 |
1.39 |
| Benzo(b+j+k)fluoranthen |
7.25 |
0.10 |
1.36 |
1.12 |
0.02 |
2.14 |
| Benzo(a)pyren |
4.36 |
0.03 |
0.74 |
0.60 |
0.01 |
1.85 |
| Indeno(1,2,3-cd)pyren |
3.78 |
0.01 |
0.34 |
0.61 |
0.01 |
1.14 |
| Dibenzo(a,h)anthracen |
0.69 |
0.00 |
0.63 |
0.11 |
0.01 |
9.08 |
| Benzo(g,h,i)perylen |
3.57 |
0.07 |
1.83 |
0.54 |
0.01 |
1.30 |
| Sum 16 EPA PAH |
63 |
0.30 |
0.47 |
9.10 |
0.21 |
2.36 |
| Sum 7 PAH |
28 |
0.36 |
1.26 |
4.18 |
0.10 |
2.42 |
Mikrobølge ekstraktionsdata 2
| Dato: |
3/3/99 |
3/3/99 |
3/3/99 |
3/3/99 |
3/3/99 |
3/3/99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
DCM |
DCM |
DCM |
DCM |
DCM |
DCM |
| Gram prøve |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
67.33 |
5.73 |
8.52 |
44.67 |
14.52 |
32.51 |
| Biphenyl d10 |
68.67 |
6.34 |
9.24 |
60.33 |
4.71 |
7.81 |
| Phenanthren d10 |
81.67 |
7.13 |
8.74 |
80.00 |
1.41 |
1.77 |
| Flouranthen d10 |
72.67 |
6.94 |
9.56 |
70.67 |
1.70 |
2.41 |
| Pyren d10 |
71.00 |
7.07 |
9.96 |
70.33 |
2.62 |
3.73 |
| Benz(a)pyren d12 |
71.00 |
6.38 |
8.98 |
67.33 |
3.30 |
4.90 |
| Dibenzo(a,h)anthracen d14 |
66.00 |
7.07 |
10.71 |
62.67 |
3.77 |
6.02 |
| Naphthalen |
0.84 |
0.02 |
2.34 |
0.17 |
0.00 |
1.98 |
| Acenaphthylen |
0.70 |
0.05 |
6.60 |
0.15 |
0.01 |
9.74 |
| Acenaphthen |
0.21 |
0.01 |
3.39 |
0.04 |
0.00 |
8.41 |
| Fluoren |
0.66 |
0.02 |
3.73 |
0.12 |
0.00 |
1.47 |
| Phenanthren |
6.81 |
0.20 |
2.99 |
1.13 |
0.02 |
1.88 |
| Anthracen |
1.23 |
0.03 |
2.59 |
0.20 |
0.00 |
1.44 |
| Fluoranthen |
11.36 |
0.28 |
2.51 |
1.73 |
0.02 |
1.06 |
| Pyren |
9.76 |
0.41 |
4.17 |
1.41 |
0.04 |
2.61 |
| Benz(a)anthracen |
4.20 |
0.19 |
4.51 |
0.65 |
0.00 |
0.44 |
| Chrysen/Triphenylen |
4.08 |
0.17 |
4.15 |
0.73 |
0.02 |
2.72 |
| Benzo(b+j+k)fluoranthen |
7.48 |
0.42 |
5.60 |
1.35 |
0.03 |
2.54 |
| Benzo(a)pyren |
4.05 |
0.20 |
4.97 |
0.65 |
0.02 |
3.04 |
| Indeno(1,2,3-cd)pyren |
3.82 |
0.18 |
4.72 |
0.74 |
0.01 |
1.30 |
| Dibenzo(a,h)anthracen |
0.65 |
0.03 |
4.96 |
0.13 |
0.00 |
0.72 |
| Benzo(g,h,i)perylen |
3.34 |
0.15 |
4.62 |
0.59 |
0.01 |
1.28 |
| Sum 16 EPA PAH |
59 |
2.2 |
3.8 |
9.76 |
0.07 |
0.72 |
| Sum 7 PAH |
27 |
1.0 |
3.6 |
4.60 |
0.08 |
1.70 |
Mikrobølge ekstraktionsdata 3
| Dato: |
4/3/99 |
4/3/99 |
4/3/99 |
4/3/99 |
4/3/99 |
4/3/99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
Cyclohexan |
Cyclohexan |
Cyclohexan |
Cyclohexan |
Cyclohexan |
Cyclohexan |
| Gram prøve |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
10 + 2 ml H2O |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
Mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
43.00 |
7.07 |
16.44 |
53.33 |
3.30 |
6.19 |
| Biphenyl d10 |
41.00 |
7.12 |
17.36 |
53.33 |
3.30 |
6.19 |
| Phenanthren d10 |
49.67 |
9.57 |
19.27 |
62.67 |
4.64 |
7.41 |
| Flouranthen d10 |
46.33 |
8.99 |
19.41 |
59.67 |
5.44 |
9.11 |
| Pyren d10 |
44.67 |
8.06 |
18.03 |
56.67 |
4.64 |
8.19 |
| Benz(a)pyren d12 |
49.67 |
8.01 |
16.14 |
63.00 |
7.79 |
12.36 |
| Dibenzo(a,h)anthracen d14 |
47.00 |
7.79 |
16.57 |
60.33 |
7.93 |
13.14 |
| Naphthalen |
0.50 |
0.03 |
6.31 |
0.07 |
0.00 |
1.84 |
| Acenaphthylen |
0.58 |
0.02 |
4.08 |
0.08 |
0.00 |
4.91 |
| Acenaphthen |
0.22 |
0.01 |
3.68 |
0.03 |
0.00 |
1.79 |
| Fluoren |
0.65 |
0.04 |
6.90 |
0.08 |
0.00 |
5.31 |
| Phenanthren |
7.24 |
0.47 |
6.49 |
0.94 |
0.04 |
4.71 |
| Anthracen |
1.24 |
0.07 |
5.79 |
0.17 |
0.01 |
5.28 |
| Fluoranthen |
12.71 |
0.66 |
5.21 |
1.70 |
0.05 |
2.77 |
| Pyren |
10.73 |
0.57 |
5.31 |
1.35 |
0.03 |
2.52 |
| Benz(a)anthracen |
4.27 |
0.23 |
5.42 |
0.57 |
0.02 |
3.05 |
| Chrysen/Triphenylen |
4.10 |
0.25 |
6.06 |
0.64 |
0.01 |
1.91 |
| Benzo(b+j+k)fluoranthen |
7.76 |
0.42 |
5.37 |
1.26 |
0.09 |
7.47 |
| Benzo(a)pyren |
4.14 |
0.23 |
5.64 |
0.60 |
0.01 |
1.35 |
| Indeno(1,2,3-cd)pyren |
4.28 |
0.24 |
5.62 |
0.70 |
0.02 |
2.63 |
| Dibenzo(a,h)anthracen |
0.65 |
0.04 |
5.60 |
0.11 |
0.00 |
2.66 |
| Benzo(g,h,i)perylen |
3.72 |
0.20 |
5.43 |
0.55 |
0.01 |
2.20 |
| Sum 16 EPA PAH |
63 |
3.3 |
5.3 |
8.8 |
0.27 |
3.11 |
| Sum 7 PAH |
30 |
1.5 |
5.2 |
4.4 |
0.15 |
3.46 |
Mikrobølge ekstraktionsdata 4
| Dato: |
16/3-99 |
16/3-99 |
16/3-99 |
16/3-99 |
16/3-99 |
16/3-99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
64.67 |
2.62 |
4.06 |
68.83 |
2.91 |
4.23 |
| Biphenyl d10 |
65.00 |
3.27 |
5.02 |
68.50 |
2.99 |
4.36 |
| Phenanthren d10 |
77.00 |
3.74 |
4.86 |
80.83 |
2.41 |
2.98 |
| Flouranthen d10 |
68.67 |
4.50 |
6.55 |
71.67 |
2.49 |
3.48 |
| Pyren d10 |
68.33 |
3.30 |
4.83 |
70.50 |
2.43 |
3.45 |
| Benz(a)pyren d12 |
73.67 |
6.94 |
9.43 |
75.33 |
4.57 |
6.07 |
| Dibenzo(a,h)anthracen d14 |
73.00 |
6.53 |
8.95 |
73.00 |
4.76 |
6.52 |
| Naphthalen |
0.93 |
0.06 |
6.23 |
0.17 |
0.01 |
5.15 |
| Acenaphthylen |
0.79 |
0.14 |
18.24 |
0.11 |
0.01 |
5.33 |
| Acenaphthen |
0.23 |
0.02 |
8.13 |
0.03 |
0.00 |
2.72 |
| Fluoren |
0.58 |
0.02 |
2.59 |
0.09 |
0.01 |
6.62 |
| Phenanthren |
7.88 |
0.14 |
1.77 |
1.02 |
0.04 |
3.52 |
| Anthracen |
1.30 |
0.06 |
4.44 |
0.19 |
0.01 |
5.45 |
| Fluoranthen |
14.02 |
1.05 |
7.46 |
1.60 |
0.06 |
3.92 |
| Pyren |
10.93 |
1.30 |
11.90 |
1.26 |
0.04 |
2.85 |
| Benz(a)anthracen |
3.96 |
0.13 |
3.33 |
0.56 |
0.05 |
8.27 |
| Chrysen/Triphenylen |
3.87 |
0.04 |
1.03 |
0.61 |
0.02 |
2.92 |
| Benzo(b+j+k)fluoranthen |
7.72 |
0.01 |
0.10 |
1.26 |
0.03 |
1.98 |
| Benzo(a)pyren |
3.85 |
0.03 |
0.88 |
0.51 |
0.01 |
2.48 |
| Indeno(1,2,3-cd)pyren |
3.49 |
0.19 |
5.31 |
0.54 |
0.02 |
2.98 |
| Dibenzo(a,h)anthracen |
0.57 |
0.04 |
6.28 |
0.10 |
0.00 |
2.73 |
| Benzo(g,h,i)perylen |
3.30 |
0.25 |
7.55 |
0.48 |
0.01 |
2.82 |
| Sum 16 EPA PAH |
63 |
1.2 |
1.9 |
8.6 |
0.19 |
2.19 |
| Sum 7 PAH |
30 |
1.3 |
4.3 |
4.0 |
0.10 |
2.57 |
Mikrobølge ekstraktionsdata 5
| Dato: |
23/3-99 |
23/3-99 |
23/3-99 |
23/3-99 |
23/3-99 |
23/3-99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
53.00 |
8.60 |
16.23 |
61.00 |
3.74 |
6.13 |
| Biphenyl d10 |
56.00 |
12.33 |
22.02 |
61.67 |
3.09 |
5.01 |
| Phenanthren d10 |
60.33 |
13.72 |
22.74 |
64.33 |
3.68 |
5.72 |
| Flouranthen d10 |
57.67 |
12.47 |
21.63 |
64.67 |
4.11 |
6.36 |
| Pyren d10 |
57.00 |
10.98 |
19.27 |
63.33 |
4.50 |
7.10 |
| Benz(a)pyren d12 |
61.67 |
13.82 |
22.40 |
69.67 |
5.31 |
7.63 |
| Dibenzo(a,h)anthracen d14 |
59.67 |
14.88 |
24.95 |
67.33 |
5.73 |
8.52 |
| Naphthalen |
0.61 |
0.04 |
5.88 |
0.11 |
0.01 |
13.83 |
| Acenaphthylen |
0.59 |
0.10 |
16.46 |
0.11 |
0.01 |
13.13 |
| Acenaphthen |
0.19 |
0.00 |
2.42 |
0.03 |
0.00 |
3.45 |
| Fluoren |
0.53 |
0.02 |
3.74 |
0.08 |
0.00 |
3.88 |
| Phenanthren |
6.63 |
0.21 |
3.21 |
0.87 |
0.03 |
3.11 |
| Anthracen |
1.21 |
0.07 |
6.13 |
0.20 |
0.01 |
5.79 |
| Fluoranthen |
12.22 |
0.66 |
5.44 |
1.47 |
0.05 |
3.20 |
| Pyren |
10.34 |
0.30 |
2.89 |
1.14 |
0.03 |
2.82 |
| Benz(a)anthracen |
3.52 |
0.04 |
1.19 |
0.56 |
0.01 |
2.16 |
| Chrysen/Triphenylen |
3.40 |
0.09 |
2.57 |
0.54 |
0.04 |
6.91 |
| Benzo(b+j+k)fluoranthen |
6.63 |
0.14 |
2.09 |
1.10 |
0.03 |
3.15 |
| Benzo(a)pyren |
3.20 |
0.08 |
2.51 |
0.44 |
0.01 |
2.62 |
| Indeno(1,2,3-cd)pyren |
2.92 |
0.17 |
5.91 |
0.48 |
0.02 |
4.42 |
| Dibenzo(a,h)anthracen |
0.46 |
0.01 |
2.66 |
0.10 |
0.01 |
6.88 |
| Benzo(g,h,i)perylen |
2.84 |
0.13 |
4.69 |
0.42 |
0.03 |
5.96 |
| Sum 16 EPA PAH |
55 |
1.7 |
3.1 |
7.6 |
0.2 |
3.1 |
| Sum 7 PAH |
25 |
1.0 |
3.9 |
3.6 |
0.1 |
3.3 |
Mikrobølge ekstraktionsdata 6
| Dato: |
24/3-99 |
24/3-99 |
24/3-99 |
24/3-99 |
24/3-99 |
24/3-99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
30 |
30 |
30 |
30 |
30 |
30 |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
48.67 |
14.82 |
30.45 |
36.00 |
8.60 |
23.90 |
| Biphenyl d10 |
47.00 |
14.51 |
30.88 |
34.33 |
8.50 |
24.75 |
| Phenanthren d10 |
54.00 |
16.08 |
29.78 |
39.33 |
9.88 |
25.11 |
| Flouranthen d10 |
49.67 |
14.06 |
28.30 |
39.67 |
9.46 |
23.86 |
| Pyren d10 |
49.33 |
13.89 |
28.15 |
39.33 |
9.88 |
25.11 |
| Benz(a)pyren d12 |
49.33 |
14.43 |
29.25 |
38.33 |
7.72 |
20.13 |
| Dibenzo(a,h)anthracen d14 |
46.00 |
12.83 |
27.90 |
37.67 |
6.65 |
17.65 |
| Naphthalen |
0.46 |
0.07 |
14.89 |
0.09 |
0.01 |
8.23 |
| Acenaphthylen |
0.38 |
0.07 |
19.20 |
0.07 |
0.00 |
6.13 |
| Acenaphthen |
0.14 |
0.02 |
14.95 |
0.02 |
0.00 |
2.44 |
| Fluoren |
0.38 |
0.06 |
15.49 |
0.05 |
0.00 |
5.44 |
| Phenanthren |
4.64 |
0.75 |
16.07 |
0.56 |
0.05 |
8.79 |
| Anthracen |
0.91 |
0.15 |
16.22 |
0.13 |
0.01 |
7.08 |
| Fluoranthen |
8.27 |
1.22 |
14.72 |
0.91 |
0.10 |
10.94 |
| Pyren |
7.16 |
1.19 |
16.59 |
0.73 |
0.07 |
9.01 |
| Benz(a)anthracen |
2.70 |
0.52 |
19.39 |
0.31 |
0.05 |
16.51 |
| Chrysen/Triphenylen |
2.66 |
0.43 |
16.33 |
0.38 |
0.05 |
13.77 |
| Benzo(b+j+k)fluoranthen |
4.93 |
0.93 |
18.76 |
0.75 |
0.10 |
14.02 |
| Benzo(a)pyren |
2.42 |
0.45 |
18.73 |
0.29 |
0.04 |
13.67 |
| Indeno(1,2,3-cd)pyren |
2.13 |
0.34 |
15.98 |
0.30 |
0.03 |
10.24 |
| Dibenzo(a,h)anthracen |
0.35 |
0.04 |
12.68 |
0.05 |
0.01 |
17.95 |
| Benzo(g,h,i)perylen |
1.93 |
0.32 |
16.65 |
0.27 |
0.03 |
10.77 |
| Sum 16 EPA PAH |
39 |
6.5 |
16 |
4.9 |
0.5 |
10.9 |
| Sum 7 PAH |
18 |
2.9 |
16 |
2.3 |
0.3 |
12.1 |
Mikrobølge ekstraktionsdata 7
| Dato: |
25/3-99 |
25/3-99 |
25/3-99 |
25/3-99 |
25/3-99 |
25/3-99 |
| Apparat': |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
MARS 5 |
| Metode: |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
EPA 3546 |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:hexan |
| Gram prøve |
30g+db.eks.tid |
30g+db.eks.tid |
30g+db.eks.tid |
30g+db.eks.tid |
30g+db.eks.tid |
30g+db.eks.tid |
| Prøve: |
MEAN |
Std.Dev |
RSD |
MEAN |
Std.Dev |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
53.00 |
7.07 |
13.34 |
61.67 |
6.94 |
11.26 |
| Biphenyl d10 |
50.00 |
3.74 |
7.48 |
58.33 |
7.04 |
12.07 |
| Phenanthren d10 |
49.67 |
3.09 |
6.22 |
65.67 |
6.94 |
10.57 |
| Flouranthen d10 |
37.33 |
4.03 |
10.79 |
52.00 |
5.72 |
10.99 |
| Pyren d10 |
39.67 |
3.77 |
9.51 |
52.67 |
5.73 |
10.89 |
| Benz(a)pyren d12 |
41.33 |
4.78 |
11.57 |
53.67 |
6.13 |
11.42 |
| Dibenzo(a,h)anthracen d14 |
37.00 |
4.32 |
11.68 |
48.67 |
5.73 |
11.78 |
| Naphthalen |
0.63 |
0.02 |
3.71 |
0.10 |
0.04 |
42.79 |
| Acenaphthylen |
0.28 |
0.05 |
17.60 |
0.05 |
0.01 |
19.82 |
| Acenaphthen |
0.13 |
0.00 |
0.64 |
0.02 |
0.01 |
37.52 |
| Fluoren |
0.30 |
0.01 |
3.26 |
0.04 |
0.02 |
41.47 |
| Phenanthren |
2.90 |
0.25 |
8.63 |
0.38 |
0.13 |
33.71 |
| Anthracen |
0.52 |
0.06 |
11.35 |
0.07 |
0.02 |
29.99 |
| Fluoranthen |
5.41 |
0.98 |
18.19 |
0.71 |
0.21 |
29.07 |
| Pyren |
5.13 |
0.84 |
16.48 |
0.58 |
0.15 |
25.61 |
| Benz(a)anthracen |
1.90 |
0.37 |
19.47 |
0.26 |
0.06 |
24.39 |
| Chrysen/Triphenylen |
1.70 |
0.33 |
19.65 |
0.30 |
0.07 |
23.87 |
| Benzo(b+j+k)fluoranthen |
2.87 |
0.66 |
22.98 |
0.53 |
0.12 |
23.24 |
| Benzo(a)pyren |
1.85 |
0.49 |
26.35 |
0.27 |
0.06 |
20.65 |
| Indeno(1,2,3-cd)pyren |
1.83 |
0.47 |
25.53 |
0.31 |
0.08 |
24.87 |
| Dibenzo(a,h)anthracen |
0.28 |
0.07 |
25.42 |
0.06 |
0.01 |
19.33 |
| Benzo(g,h,i)perylen |
1.68 |
0.43 |
25.53 |
0.27 |
0.07 |
23.85 |
| Sum 16 EPA PAH |
27 |
5.0 |
18 |
4.0 |
1.0 |
26 |
| Sum 7 PAH |
12 |
2.7 |
22 |
1.9 |
0.5 |
25 |
Rystemetode ekstraktionsdata 1
| Dato: |
17/5-99 |
17/5-99 |
17/5-99 |
17/5-99 |
17/5-99 |
17/5-99 |
| Apparat': |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
| Metode: |
O-32 |
O-32 |
O-32 |
O-32 |
O-32 |
O-32 |
| Opløsningsmiddel: |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
57.7 |
7.4 |
12.8 |
67.7 |
3.51 |
5.19 |
| Biphenyl d10 |
47.7 |
6.4 |
13.5 |
56.0 |
3.61 |
6.44 |
| Phenanthren d10 |
52.0 |
7.0 |
13.5 |
60.0 |
3.46 |
5.77 |
| Flouranthen d10 |
52.7 |
6.4 |
12.1 |
60.3 |
2.89 |
4.78 |
| Pyren d10 |
54.7 |
7.2 |
13.2 |
63.3 |
2.08 |
3.29 |
| Benz(a)pyren d12 |
67.7 |
8.1 |
11.9 |
76.3 |
2.08 |
2.73 |
| Dibenzo(a,h)anthracen d14 |
76.7 |
9.1 |
11.8 |
82.7 |
3.21 |
3.89 |
| Naphthalen |
0.242 |
0.03 |
10.84 |
0.037 |
0.00 |
1.55 |
| Acenaphthylen |
0.533 |
0.03 |
5.54 |
0.090 |
0.00 |
0.64 |
| Acenaphthen |
0.157 |
0.00 |
1.69 |
0.020 |
0.00 |
0.00 |
| Fluoren |
0.410 |
0.01 |
1.66 |
0.058 |
0.00 |
1.72 |
| Phenanthren |
5.980 |
0.17 |
2.76 |
0.772 |
0.02 |
2.61 |
| Anthracen |
0.906 |
0.02 |
2.34 |
0.149 |
0.00 |
2.05 |
| Fluoranthen |
12.044 |
0.10 |
0.81 |
1.454 |
0.02 |
1.25 |
| Pyren |
9.872 |
0.20 |
2.06 |
1.199 |
0.01 |
0.71 |
| Benz(a)anthracen |
3.340 |
0.03 |
0.89 |
0.481 |
0.01 |
1.67 |
| Chrysen/Triphenylen |
3.311 |
0.03 |
0.98 |
0.562 |
0.00 |
0.57 |
| Benzo(b+j+k)fluoranthen |
5.564 |
0.28 |
5.08 |
1.244 |
0.01 |
1.17 |
| Benzo(a)pyren |
3.350 |
0.01 |
0.27 |
0.498 |
0.01 |
1.31 |
| Indeno(1,2,3-cd)pyren |
2.903 |
0.05 |
1.74 |
0.495 |
0.00 |
0.35 |
| Dibenzo(a,h)anthracen |
0.514 |
0.01 |
1.75 |
0.099 |
0.00 |
1.01 |
| Benzo(g,h,i)perylen |
2.794 |
0.03 |
1.11 |
0.450 |
0.00 |
1.10 |
| Sum 16 EPA PAH |
52 |
0.13 |
0.25 |
7.6 |
0.00 |
0.05 |
| Sum 7 PAH |
24 |
0.42 |
1.72 |
3.8 |
0.02 |
0.42 |
Rystemetode ekstraktionsdata 2
| Dato: |
21/5-99 |
21/5-99 |
21/5-99 |
21/5-99 |
21/5-99 |
21/5-99 |
| Apparat': |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
| Metode: |
O-38 |
O-38 |
O-38 |
O-38 |
O-38 |
O-38 |
| Opløsningsmiddel: |
DCM |
DCM |
DCM |
DCM |
DCM |
DCM |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
85.7 |
6.4 |
7.5 |
61.5 |
0.7 |
1.1 |
| Biphenyl d10 |
80.0 |
2.6 |
3.3 |
62.5 |
0.7 |
1.1 |
| Phenanthren d10 |
91.3 |
3.5 |
3.8 |
86.5 |
7.8 |
9.0 |
| Flouranthen d10 |
89.7 |
4.7 |
5.3 |
85.5 |
6.4 |
7.4 |
| Pyren d10 |
89.3 |
5.8 |
6.5 |
87.5 |
6.4 |
7.3 |
| Benz(a)pyren d12 |
82.7 |
4.7 |
5.7 |
80.0 |
11.3 |
14.1 |
| Dibenzo(a,h)anthracen d14 |
81.3 |
1.5 |
1.9 |
81.0 |
12.7 |
15.7 |
| Naphthalen |
0.456 |
0.03 |
5.82 |
0.145 |
0.01 |
9.30 |
| Acenaphthylen |
0.680 |
0.02 |
2.82 |
0.137 |
0.02 |
15.02 |
| Acenaphthen |
0.152 |
0.00 |
2.65 |
0.032 |
0.00 |
8.84 |
| Fluoren |
0.400 |
0.02 |
4.01 |
0.069 |
0.00 |
1.03 |
| Phenanthren |
5.638 |
0.04 |
0.71 |
0.828 |
0.01 |
1.20 |
| Anthracen |
0.862 |
0.00 |
0.33 |
0.154 |
0.00 |
1.84 |
| Fluoranthen |
11.201 |
0.15 |
1.31 |
1.430 |
0.01 |
0.59 |
| Pyren |
8.838 |
0.54 |
6.13 |
1.248 |
0.04 |
3.12 |
| Benz(a)anthracen |
4.163 |
0.15 |
3.52 |
0.566 |
0.01 |
2.25 |
| Chrysen/Triphenylen |
4.148 |
0.15 |
3.60 |
0.680 |
0.02 |
2.50 |
| Benzo(b+j+k)fluoranthen |
6.179 |
0.31 |
4.98 |
1.290 |
0.01 |
0.55 |
| Benzo(a)pyren |
3.314 |
0.16 |
4.76 |
0.467 |
0.05 |
11.67 |
| Indeno(1,2,3-cd)pyren |
2.977 |
0.03 |
1.17 |
0.461 |
0.02 |
3.53 |
| Dibenzo(a,h)anthracen |
0.520 |
0.01 |
1.20 |
0.093 |
0.00 |
3.04 |
| Benzo(g,h,i)perylen |
2.860 |
0.05 |
1.73 |
0.419 |
0.02 |
4.05 |
| Sum 16 EPA PAH |
52 |
0.59 |
1.12 |
8.0 |
0.04 |
0.44 |
| Sum 7 PAH |
24 |
0.35 |
1.46 |
3.7 |
0.06 |
1.55 |
Rystemetode ekstraktionsdata 3
| Dato: |
20/5-99 |
20/5-99 |
20/5-99 |
20/5-99 |
20/5-99 |
20/5-99 |
| Apparat': |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
| Metode: |
O-40 |
O-40 |
O-40 |
O-40 |
O-40 |
O-40 |
| Opløsningsmiddel: |
Toluen |
Toluen |
Toluen |
Toluen |
Toluen |
Toluen |
| Gram prøve |
50 |
50 |
50 |
50 |
50 |
50 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
72.7 |
8.5 |
11.7 |
68.3 |
13.8 |
20.2 |
| Biphenyl d10 |
74.7 |
5.5 |
7.4 |
70.0 |
8.7 |
12.5 |
| Phenanthren d10 |
93.7 |
4.5 |
4.8 |
89.0 |
4.0 |
4.5 |
| Flouranthen d10 |
92.3 |
4.5 |
4.9 |
91.0 |
3.0 |
3.3 |
| Pyren d10 |
91.0 |
5.0 |
5.5 |
88.0 |
2.6 |
3.0 |
| Benz(a)pyren d12 |
110.3 |
6.4 |
5.8 |
98.0 |
1.7 |
1.8 |
| Dibenzo(a,h)anthracen d14 |
123.0 |
6.2 |
5.1 |
98.3 |
6.0 |
6.1 |
| Naphthalen |
0.458 |
0.06 |
13.24 |
0.087 |
0.02 |
19.24 |
| Acenaphthylen |
0.891 |
0.08 |
8.68 |
0.149 |
0.02 |
10.43 |
| Acenaphthen |
0.178 |
0.02 |
8.83 |
0.030 |
0.00 |
9.52 |
| Fluoren |
0.437 |
0.01 |
2.68 |
0.070 |
0.00 |
2.99 |
| Phenanthren |
5.929 |
0.23 |
3.87 |
0.785 |
0.03 |
3.28 |
| Anthracen |
0.939 |
0.03 |
2.79 |
0.171 |
0.01 |
3.65 |
| Fluoranthen |
10.827 |
0.53 |
4.85 |
1.416 |
0.02 |
1.33 |
| Pyren |
11.235 |
0.73 |
6.47 |
1.215 |
0.00 |
0.38 |
| Benz(a)anthracen |
3.426 |
0.21 |
6.18 |
0.483 |
0.07 |
14.24 |
| Chrysen/Triphenylen |
3.145 |
0.18 |
5.71 |
0.537 |
0.03 |
6.03 |
| Benzo(b+j+k)fluoranthen |
7.028 |
0.38 |
5.41 |
1.172 |
0.08 |
6.68 |
| Benzo(a)pyren |
3.136 |
0.15 |
4.92 |
0.474 |
0.03 |
6.23 |
| Indeno(1,2,3-cd)pyren |
2.809 |
0.06 |
2.14 |
0.427 |
0.04 |
10.27 |
| Dibenzo(a,h)anthracen |
0.536 |
0.00 |
0.84 |
0.097 |
0.01 |
10.46 |
| Benzo(g,h,i)perylen |
2.769 |
0.06 |
2.05 |
0.439 |
0.04 |
9.96 |
| Sum 16 EPA PAH |
54 |
2.6 |
4.9 |
7.6 |
0.27 |
3.56 |
| Sum 7 PAH |
24 |
1.1 |
4.6 |
3.6 |
0.17 |
4.65 |
Rystemetode ekstraktionsdata 4
| Dato: |
21/4-99 |
21/4-99 |
21/4-99 |
21/4-99 |
21/4-99 |
21/4-99 |
| Apparat': |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
| Metode: |
O-41a |
O-41a |
O-41a |
O-41a |
O-41a |
O-41a |
| Opløsningsmiddel: |
Acetone:pentan |
Acetone:pentan |
Acetone:pentan |
Acetone:pentan |
Acetone:pentan |
Acetone:pentan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
59.3 |
4.0 |
6.8 |
57.0 |
1.0 |
1.8 |
| Biphenyl d10 |
66.0 |
2.6 |
4.0 |
61.0 |
1.0 |
1.6 |
| Phenanthren d10 |
83.7 |
2.5 |
3.0 |
76.0 |
2.0 |
2.6 |
| Flouranthen d10 |
85.0 |
2.6 |
3.1 |
78.3 |
4.0 |
5.2 |
| Pyren d10 |
89.7 |
3.2 |
3.6 |
83.0 |
2.6 |
3.2 |
| Benz(a)pyren d12 |
92.3 |
5.7 |
6.2 |
84.0 |
3.6 |
4.3 |
| Dibenzo(a,h)anthracen d14 |
94.7 |
10.0 |
10.6 |
82.7 |
5.5 |
6.7 |
| Naphthalen |
0.486 |
0.03 |
5.92 |
0.103 |
0.003 |
2.57 |
| Acenaphthylen |
0.815 |
0.03 |
3.64 |
0.144 |
0.00 |
2.62 |
| Acenaphthen |
0.207 |
0.01 |
3.17 |
0.032 |
0.00 |
1.82 |
| Fluoren |
0.485 |
0.01 |
1.64 |
0.079 |
0.00 |
1.27 |
| Phenanthren |
6.074 |
0.12 |
2.04 |
0.855 |
0.01 |
0.80 |
| Anthracen |
0.996 |
0.01 |
0.55 |
0.166 |
0.00 |
0.69 |
| Fluoranthen |
12.268 |
0.19 |
1.58 |
1.526 |
0.04 |
2.37 |
| Pyren |
10.390 |
0.40 |
3.83 |
1.173 |
0.02 |
1.56 |
| Benz(a)anthracen |
3.877 |
0.10 |
2.57 |
0.581 |
0.02 |
3.62 |
| Chrysen/Triphenylen |
4.013 |
0.17 |
4.20 |
0.691 |
0.01 |
1.21 |
| Benzo(b+j+k)fluoranthen |
8.510 |
0.14 |
1.66 |
1.504 |
0.01 |
0.77 |
| Benzo(a)pyren |
4.175 |
0.07 |
1.68 |
0.602 |
0.01 |
1.50 |
| Indeno(1,2,3-cd)pyren |
3.578 |
0.07 |
2.02 |
0.652 |
0.00 |
0.44 |
| Dibenzo(a,h)anthracen |
0.645 |
0.00 |
0.45 |
0.126 |
0.01 |
5.94 |
| Benzo(g,h,i)perylen |
3.447 |
0.02 |
0.68 |
0.605 |
0.00 |
0.25 |
| Sum 16 EPA PAH |
60 |
0.94 |
1.57 |
8.8 |
0.06 |
0.72 |
| Sum 7 PAH |
29 |
0.27 |
0.91 |
4.4 |
0.03 |
0.68 |
Rystemetode ekstraktionsdata 5
| Dato: |
11/5/99 |
11/5/99 |
11/5/99 |
11/5/99 |
11/5/99 |
11/5/99 |
| Apparat': |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
Ryste |
| Metode: |
O-41a |
O-41a |
O-41a |
O-41a |
O-41a |
O-41a |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
61.0 |
20.8 |
34.1 |
49.3 |
1.2 |
2.3 |
| Biphenyl d10 |
70.7 |
19.3 |
27.4 |
56.0 |
2.6 |
4.7 |
| Phenanthren d10 |
94.7 |
22.8 |
24.1 |
76.0 |
3.6 |
4.7 |
| Flouranthen d10 |
98.7 |
25.4 |
25.8 |
78.3 |
4.5 |
5.8 |
| Pyren d10 |
101.3 |
25.7 |
25.4 |
81.7 |
3.5 |
4.3 |
| Benz(a)pyren d12 |
102.7 |
29.7 |
29.0 |
81.0 |
4.4 |
5.4 |
| Dibenzo(a,h)anthracen d14 |
103.0 |
26.9 |
26.1 |
78.0 |
5.0 |
6.4 |
| Naphthalen |
0.571 |
0.04 |
6.68 |
0.129 |
0.01 |
5.88 |
| Acenaphthylen |
0.975 |
0.05 |
4.61 |
0.180 |
0.00 |
2.55 |
| Acenaphthen |
0.233 |
0.01 |
3.44 |
0.037 |
0.00 |
9.41 |
| Fluoren |
0.483 |
0.01 |
1.36 |
0.079 |
0.00 |
1.27 |
| Phenanthren |
6.497 |
0.19 |
2.96 |
0.867 |
0.01 |
1.61 |
| Anthracen |
1.048 |
0.01 |
1.10 |
0.175 |
0.00 |
1.71 |
| Fluoranthen |
12.900 |
0.80 |
6.18 |
1.525 |
0.02 |
1.48 |
| Pyren |
11.675 |
1.43 |
12.22 |
1.220 |
0.00 |
0.13 |
| Benz(a)anthracen |
4.027 |
0.05 |
1.35 |
0.593 |
0.02 |
2.79 |
| Chrysen/Triphenylen |
4.170 |
0.05 |
1.09 |
0.695 |
0.02 |
3.28 |
| Benzo(b+j+k)fluoranthen |
8.803 |
0.22 |
2.52 |
1.529 |
0.00 |
0.32 |
| Benzo(a)pyren |
4.254 |
0.13 |
3.11 |
0.615 |
0.01 |
IZE="3">0.95 |
| Indeno(1,2,3-cd)pyren |
3.656 |
0.12 |
3.27 |
0.656 |
0.01 |
1.10 |
| Dibenzo(a,h)anthracen |
0.685 |
0.04 |
5.84 |
0.126 |
0.00 |
2.10 |
| Benzo(g,h,i)perylen |
3.541 |
0.09 |
2.65 |
0.603 |
0.01 |
1.51 |
| Sum 16 EPA PAH |
64 |
1.7 |
2.7 |
9.0 |
0.06 |
0.66 |
| Sum 7 PAH |
30 |
0.4 |
1.2 |
4.5 |
0.03 |
0.70 |
Soxtec ekstraktionsdata 1
| Dato: |
25/2-99 |
25/2-99 |
25/2-99 |
25/2-99 |
25/2-99 |
25/2-99 |
| Apparat': |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
| Metode: |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
76 |
20.1 |
26.3 |
92.3 |
8.62 |
9.34 |
| Biphenyl d10 |
85 |
20.6 |
24.3 |
95.7 |
6.66 |
6.96 |
| Phenanthren d10 |
107 |
10.2 |
9.6 |
110.0 |
6.00 |
5.45 |
| Flouranthen d10 |
102 |
6.6 |
6.4 |
103.3 |
4.51 |
4.36 |
| Pyren d10 |
99 |
6.6 |
6.6 |
106.0 |
5.57 |
5.25 |
| Benz(a)pyren d12 |
106 |
4.0 |
3.8 |
111.7 |
6.66 |
5.96 |
| Dibenzo(a,h)anthracen d14 |
107 |
3.5 |
3.3 |
114.0 |
6.08 |
5.34 |
| Naphthalen |
0.475 |
0.01 |
2.95 |
0.085 |
0.00 |
2.35 |
| Acenaphthylen |
0.689 |
0.12 |
17.54 |
0.116 |
0.00 |
1.32 |
| Acenaphthen |
0.192 |
0.02 |
8.86 |
0.026 |
0.00 |
2.19 |
| Fluoren |
0.596 |
0.06 |
10.62 |
0.087 |
0.00 |
2.66 |
| Phenanthren |
7.049 |
0.41 |
5.78 |
0.874 |
0.02 |
2.08 |
| Anthracen |
1.169 |
0.06 |
5.18 |
0.165 |
0.00 |
1.26 |
| Fluoranthen |
11.684 |
0.04 |
0.36 |
1.439 |
0.01 |
0.86 |
| Pyren |
10.297 |
0.09 |
0.90 |
1.277 |
0.01 |
0.58 |
| Benz(a)anthracen |
3.838 |
0.18 |
4.64 |
0.542 |
0.00 |
0.21 |
| Chrysen/Triphenylen |
3.779 |
0.09 |
2.41 |
0.601 |
0.01 |
1.84 |
| Benzo(b+j+k)fluoranthen |
7.617 |
0.40 |
5.24 |
1.280 |
0.09 |
7.40 |
| Benzo(a)pyren |
3.916 |
0.03 |
0.76 |
0.585 |
0.03 |
4.37 |
| Indeno(1,2,3-cd)pyren |
3.564 |
0.14 |
4.06 |
0.592 |
0.02 |
2.74 |
| Dibenzo(a,h)anthracen |
0.588 |
0.03 |
4.33 |
0.112 |
0.00 |
1.36 |
| Benzo(g,h,i)perylen |
3.231 |
0.04 |
1.21 |
0.513 |
0.02 |
2.93 |
| Sum 16 EPA PAH |
59 |
0.37 |
0.63 |
8.3 |
0.15 |
1.86 |
| Sum 7 PAH |
27 |
0.47 |
1.71 |
4.0 |
0.12 |
2.91 |
Soxtec ekstraktionsdata 2
| Dato: |
3/3/99 |
3/3/99 |
3/3/99 |
3/3/99 |
3/3/99 |
3/3/99 |
| Apparat': |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
| Metode: |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
| Opløsningsmiddel: |
Cyclohexan |
Cyclohexan |
Cyclohexan |
Cyclohexan |
Cyclohexan |
Cyclohexan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
59.3 |
4.2 |
7.0 |
48.7 |
16.50 |
33.91 |
| Biphenyl d10 |
77.7 |
6.0 |
7.8 |
65.3 |
11.06 |
16.93 |
| Phenanthren d10 |
91.7 |
8.1 |
8.8 |
74.7 |
8.50 |
11.39 |
| Flouranthen d10 |
93.7 |
9.1 |
9.7 |
72.0 |
10.54 |
14.63 |
| Pyren d10 |
91.0 |
7.2 |
7.9 |
71.0 |
9.54 |
13.44 |
| Benz(a)pyren d12 |
86.0 |
16.1 |
18.7 |
73.7 |
10.26 |
13.93 |
| Dibenzo(a,h)anthracen d14 |
69.7 |
20.6 |
29.5 |
68.0 |
12.29 |
18.07 |
| Naphthalen |
0.493 |
0.04 |
7.70 |
0.126 |
0.03 |
21.31 |
| Acenaphthylen |
0.541 |
0.01 |
1.86 |
0.154 |
0.03 |
19.36 |
| Acenaphthen |
0.224 |
0.01 |
3.59 |
0.040 |
0.01 |
16.51 |
| Fluoren |
0.568 |
0.03 |
4.49 |
0.090 |
0.02 |
17.88 |
| Phenanthren |
7.096 |
0.35 |
4.96 |
0.987 |
0.17 |
16.74 |
| Anthracen |
1.113 |
0.05 |
4.28 |
0.160 |
0.03 |
17.56 |
| Fluoranthen |
12.938 |
0.11 |
0.85 |
1.842 |
0.34 |
18.21 |
| Pyren |
11.777 |
0.55 |
4.66 |
1.635 |
0.27 |
16.55 |
| Benz(a)anthracen |
4.900 |
0.59 |
12.04 |
0.637 |
0.04 |
6.08 |
| Chrysen/Triphenylen |
4.585 |
0.46 |
10.08 |
0.719 |
0.05 |
6.59 |
| Benzo(b+j+k)fluoranthen |
8.284 |
1.07 |
12.97 |
1.286 |
0.10 |
7.68 |
| Benzo(a)pyren |
4.723 |
0.31 |
6.55 |
0.650 |
0.08 |
12.30 |
| Indeno(1,2,3-cd)pyren |
4.700 |
0.10 |
2.03 |
0.726 |
0.05 |
7.25 |
| Dibenzo(a,h)anthracen |
0.807 |
0.08 |
10.02 |
0.134 |
0.01 |
4.16 |
| Benzo(g,h,i)perylen |
4.827 |
0.47 |
9.81 |
0.670 |
0.04 |
6.19 |
| Sum 16 EPA PAH |
68 |
4.0 |
5.9 |
9.9 |
1.0 |
10.3 |
| Sum 7 PAH |
31 |
1.5 |
4.9 |
4.6 |
0.4 |
8.7 |
Soxtec ekstraktionsdata 3
| Dato: |
19/4-99 |
19/4-99 |
19/4-99 |
19/4-99 |
19/4-99 |
19/4-99 |
| Apparat': |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
| Metode: |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
| Opløsningsmiddel: |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
Cyc:Isopro 2:1 |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
63 |
5.7 |
9.1 |
69 |
2.65 |
3.83 |
| Biphenyl d10 |
67 |
7.8 |
11.7 |
77 |
3.06 |
3.98 |
| Phenanthren d10 |
77 |
11.3 |
14.6 |
87 |
2.08 |
2.40 |
| Flouranthen d10 |
76 |
11.0 |
14.4 |
86 |
3.21 |
3.72 |
| Pyren d10 |
81 |
10.7 |
13.3 |
89 |
2.65 |
2.97 |
| Benz(a)pyren d12 |
78 |
13.2 |
17.0 |
90 |
5.03 |
5.61 |
| Dibenzo(a,h)anthracen d14 |
80 |
13.7 |
17.2 |
87 |
5.00 |
5.75 |
| Naphthalen |
0.450 |
0.02 |
4.90 |
0.089 |
0.01 |
6.41 |
| Acenaphthylen |
0.723 |
0.02 |
3.08 |
0.149 |
0.01 |
4.40 |
| Acenaphthen |
0.227 |
0.04 |
16.45 |
0.064 |
0.01 |
9.50 |
| Fluoren |
0.488 |
0.02 |
3.56 |
0.075 |
0.00 |
1.55 |
| Phenanthren |
6.144 |
0.04 |
0.63 |
0.773 |
0.01 |
1.78 |
| Anthracen |
0.974 |
0.03 |
2.72 |
0.155 |
0.00 |
0.99 |
| Fluoranthen |
11.643 |
0.11 |
0.97 |
1.363 |
0.03 |
2.30 |
| Pyren |
11.123 |
0.33 |
2.97 |
1.183 |
0.02 |
1.33 |
| Benz(a)anthracen |
4.339 |
0.21 |
4.80 |
0.593 |
0.01 |
1.72 |
| Chrysen/Triphenylen |
3.894 |
0.10 |
2.68 |
0.617 |
0.02 |
2.86 |
| Benzo(b+j+k)fluoranthen |
8.494 |
0.18 |
2.09 |
1.390 |
0.04 |
3.05 |
| Benzo(a)pyren |
4.072 |
0.02 |
0.45 |
0.548 |
0.01 |
2.49 |
| Indeno(1,2,3-cd)pyren |
3.679 |
0.04 |
1.16 |
0.602 |
0.02 |
2.91 |
| Dibenzo(a,h)anthracen |
0.656 |
0.05 |
6.97 |
0.109 |
0.01 |
12.61 |
| Benzo(g,h,i)perylen |
3.558 |
0.04 |
1.16 |
0.554 |
0.02 |
3.07 |
| Sum 16 EPA PAH |
60 |
0.35 |
0.58 |
8.3 |
0.19 |
2.24 |
| Sum 7 PAH |
29 |
0.17 |
0.61 |
4.0 |
0.11 |
2.85 |
Soxtec ekstraktionsdata 4
| Dato: |
20/4-99 |
20/4-99 |
20/4-99 |
20/4-99 |
20/4-99 |
20/4-99 |
| Apparat': |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
| Metode: |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
| Opløsningsmiddel: |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
Acetone:Cyc |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
82 |
9.1 |
11.1 |
78 |
3.79 |
4.83 |
| Biphenyl d10 |
81 |
7.6 |
9.3 |
82 |
4.62 |
5.61 |
| Phenanthren d10 |
94 |
4.9 |
5.2 |
97 |
4.04 |
4.18 |
| Flouranthen d10 |
98 |
5.1 |
5.2 |
102 |
3.51 |
3.45 |
| Pyren d10 |
96 |
5.1 |
5.3 |
97 |
3.79 |
3.89 |
| Benz(a)pyren d12 |
102 |
5.7 |
5.6 |
101 |
5.29 |
5.24 |
| Dibenzo(a,h)anthracen d14 |
104 |
8.1 |
7.7 |
99 |
4.73 |
4.79 |
| Naphthalen |
0.478 |
0.03 |
6.17 |
0.114 |
0.00 |
2.03 |
| Acenaphthylen |
0.957 |
0.06 |
6.68 |
0.182 |
0.02 |
9.82 |
| Acenaphthen |
0.191 |
0.01 |
3.67 |
0.033 |
0.00 |
10.50 |
| Fluoren |
0.497 |
0.01 |
3.02 |
0.075 |
0.00 |
4.06 |
| Phenanthren |
6.292 |
0.06 |
0.93 |
0.807 |
0.01 |
1.33 |
| Anthracen |
1.056 |
0.01 |
0.74 |
0.170 |
0.00 |
2.44 |
| Fluoranthen |
13.028 |
0.06 |
0.44 |
1.525 |
0.04 |
2.37 |
| Pyren |
10.262 |
0.09 |
0.89 |
1.102 |
0.04 |
4.04 |
| Benz(a)anthracen |
3.915 |
0.03 |
0.78 |
0.573 |
0.02 |
2.67 |
| Chrysen/Triphenylen |
4.023 |
0.07 |
1.75 |
0.666 |
0.02 |
3.39 |
| Benzo(b+j+k)fluoranthen |
8.628 |
0.03 |
0.33 |
1.445 |
0.03 |
1.88 |
| Benzo(a)pyren |
4.113 |
0.08 |
2.02 |
0.574 |
0.01 |
2.14 |
| Indeno(1,2,3-cd)pyren |
3.632 |
0.04 |
1.02 |
0.625 |
0.01 |
1.71 |
| Dibenzo(a,h)anthracen |
0.678 |
0.03 |
4.33 |
0.122 |
0.00 |
3.28 |
| Benzo(g,h,i)perylen |
3.509 |
0.03 |
0.86 |
0.575 |
0.00 |
0.61 |
| Sum 16 EPA PAH |
61 |
0.38 |
0.62 |
8.6 |
0.10 |
1.19 |
| Sum 7 PAH |
30 |
0.14 |
0.48 |
4.3 |
0.08 |
1.85 |
Soxtec ekstraktionsdata 5
| Dato: |
10/6/99 |
10/6/99 |
10/6/99 |
10/6/99 |
10/6/99 |
10/6/99 |
| Apparat': |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
| Metode: |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
| Opløsningsmiddel: |
DCM |
DCM |
DCM |
DCM |
DCM |
DCM |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
69.7 |
14.4 |
20.6 |
84.0 |
3.61 |
4.29 |
| Biphenyl d10 |
75.0 |
7.9 |
10.6 |
83.0 |
1.00 |
1.20 |
| Phenanthren d10 |
94.0 |
5.3 |
5.6 |
96.7 |
1.53 |
1.58 |
| Flouranthen d10 |
86.3 |
5.1 |
5.9 |
93.0 |
2.65 |
2.84 |
| Pyren d10 |
90.7 |
6.7 |
7.3 |
97.7 |
2.08 |
2.13 |
| Benz(a)pyren d12 |
90.7 |
7.4 |
8.1 |
97.0 |
3.46 |
3.57 |
| Dibenzo(a,h)anthracen d14 |
83.7 |
7.2 |
8.6 |
89.0 |
3.46 |
3.89 |
| Naphthalen |
0.408 |
0.01 |
1.27 |
0.096 |
0.01 |
5.26 |
| Acenaphthylen |
0.477 |
0.02 |
3.43 |
0.097 |
0.00 |
4.49 |
| Acenaphthen |
0.132 |
0.00 |
2.00 |
0.020 |
0.00 |
5.68 |
| Fluoren |
0.382 |
0.01 |
2.49 |
0.060 |
0.00 |
2.56 |
| Phenanthren |
5.990 |
0.18 |
3.01 |
0.765 |
0.02 |
2.90 |
| Anthracen |
0.768 |
0.01 |
1.62 |
0.138 |
0.00 |
1.10 |
| Fluoranthen |
10.581 |
2.07 |
19.60 |
1.298 |
0.06 |
4.59 |
| Pyren |
9.252 |
1.37 |
14.82 |
1.093 |
0.08 |
7.61 |
| Benz(a)anthracen |
3.945 |
0.16 |
4.06 |
0.545 |
0.06 |
10.30 |
| Chrysen/Triphenylen |
3.844 |
0.15 |
3.85 |
0.610 |
0.02 |
3.76 |
| Benzo(b+j+k)fluoranthen |
7.836 |
0.30 |
3.89 |
1.324 |
0.07 |
5.66 |
| Benzo(a)pyren |
3.730 |
0.12 |
3.31 |
0.536 |
0.03 |
6.16 |
| Indeno(1,2,3-cd)pyren |
2.646 |
0.12 |
4.43 |
0.408 |
0.03 |
7.93 |
| Dibenzo(a,h)anthracen |
0.741 |
0.06 |
7.88 |
0.125 |
0.00 |
2.30 |
| Benzo(g,h,i)perylen |
3.399 |
0.15 |
4.53 |
0.527 |
0.04 |
7.75 |
| Sum 16 EPA PAH |
54 |
4.4 |
8.1 |
7.6 |
0.4 |
5.6 |
| Sum 7 PAH |
26 |
2.5 |
9.8 |
3.7 |
0.2 |
5.5 |
Soxtec ekstraktionsdata 6
| Dato: |
17/6-99 |
17/6-99 |
17/6-99 |
17/6-99 |
17/6-99 |
17/6-99 |
| Apparat': |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
Soxtec |
| Metode: |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
EPA 3541 |
| Opløsningsmiddel: |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
Acetone:Pentan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| Naphthalen d8 |
103.3 |
3.1 |
3.0 |
102.3 |
1.15 |
1.13 |
| Biphenyl d10 |
101.3 |
3.2 |
3.2 |
100.0 |
1.00 |
1.00 |
| Phenanthren d10 |
115.7 |
1.5 |
1.3 |
110.7 |
3.21 |
2.90 |
| Flouranthen d10 |
113.7 |
2.5 |
2.2 |
119.0 |
4.36 |
3.66 |
| Pyren d10 |
120.0 |
3.6 |
3.0 |
123.3 |
2.08 |
1.69 |
| Benz(a)pyren d12 |
145.0 |
1.0 |
0.7 |
143.7 |
4.73 |
3.29 |
| Dibenzo(a,h)anthracen d14 |
119.0 |
2.6 |
2.2 |
111.7 |
2.08 |
1.86 |
| Naphthalen |
0.409 |
0.01 |
2.50 |
0.076 |
0.00 |
4.60 |
| Acenaphthylen |
0.573 |
0.03 |
6.02 |
0.092 |
0.01 |
6.30 |
| Acenaphthen |
0.158 |
0.00 |
1.10 |
0.022 |
0.00 |
0.00 |
| Fluoren |
0.401 |
0.01 |
3.30 |
0.051 |
0.00 |
1.19 |
| Phenanthren |
5.741 |
0.16 |
2.82 |
0.770 |
0.03 |
3.48 |
| Anthracen |
0.829 |
0.03 |
4.04 |
0.149 |
0.01 |
4.05 |
| Fluoranthen |
12.535 |
0.21 |
1.66 |
1.480 |
0.02 |
1.51 |
| Pyren |
11.028 |
0.24 |
2.22 |
1.080 |
0.04 |
3.33 |
| Benz(a)anthracen |
4.646 |
0.11 |
2.31 |
0.617 |
0.05 |
7.42 |
| Chrysen/Triphenylen |
3.247 |
0.08 |
2.42 |
0.658 |
0.02 |
2.61 |
| Benzo(b+j+k)fluoranthen |
6.495 |
0.06 |
0.90 |
1.182 |
0.02 |
1.80 |
| Benzo(a)pyren |
3.491 |
0.07 |
2.14 |
0.435 |
0.01 |
2.22 |
| Indeno(1,2,3-cd)pyren |
3.180 |
0.08 |
2.57 |
0.484 |
0.00 |
0.90 |
| Dibenzo(a,h)anthracen |
0.560 |
0.03 |
4.59 |
0.098 |
0.00 |
0.59 |
| Benzo(g,h,i)perylen |
3.251 |
0.11 |
3.40 |
0.485 |
0.00 |
0.12 |
| Sum 16 EPA PAH |
57 |
0.53 |
0.94 |
7.7 |
0.07 |
0.91 |
| Sum 7 PAH |
26 |
0.41 |
1.55 |
3.7 |
0.05 |
1.39 |
SFE ekstraktionsdata 1
| Dato: |
16/3-99 |
16/3-99 |
16/3-99 |
16/3-99 |
16/3-99 |
16/3-99 |
| Apparat': |
SFE |
SFE |
SFE |
SFE |
SFE |
SFE |
| Metode: |
150 C |
150 C |
150 C |
150 C |
150 C |
150 C |
| Opløsningsmiddel: |
CO2 |
CO2 |
CO2 |
CO2 |
CO2 |
CO2 |
| Gram prøve |
2 |
2 |
2 |
2 |
2 |
2 |
| Prøve: |
MEAN |
Std.Dev. |
Rel. Std. |
MEAN |
Std.Dev. |
Rel. Std. |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
93.7 |
13.01 |
13.88 |
98.1 |
12.3 |
12.5 |
| Biphenyl d10 |
90.4 |
15.13 |
16.73 |
83.9 |
7.7 |
9.1 |
| Phenanthren d10 |
77.9 |
20.35 |
26.14 |
63.6 |
8.6 |
13.5 |
| Flouranthen d10 |
9.0 |
2.58 |
28.69 |
7.7 |
2.8 |
36.4 |
| Pyren d10 |
38.3 |
17.75 |
46.37 |
30.0 |
5.0 |
16.8 |
| Benz(a)pyren d12 |
6.0 |
2.65 |
44.10 |
6.3 |
2.1 |
34.0 |
| Dibenzo(a,h)anthracen d14 |
15.0 |
6.56 |
43.72 |
7.4 |
4.9 |
66.3 |
| Naphthalen |
1.025 |
0.074 |
7.19 |
0.209 |
0.02 |
9.08 |
| Acenaphthylen |
0.144 |
0.014 |
9.48 |
0.052 |
0.01 |
21.12 |
| Acenaphthen |
0.192 |
0.015 |
7.76 |
0.053 |
0.01 |
13.61 |
| Fluoren |
0.451 |
0.035 |
7.77 |
0.065 |
0.01 |
15.31 |
| Phenanthren |
8.811 |
0.888 |
10.07 |
1.397 |
0.18 |
12.98 |
| Anthracen |
1.458 |
0.126 |
8.62 |
0.347 |
0.03 |
8.95 |
| Fluoranthen |
15.730 |
2.464 |
15.66 |
2.238 |
0.33 |
14.86 |
| Pyren |
10.595 |
0.875 |
8.26 |
1.549 |
0.14 |
9.05 |
| Benz(a)anthracen |
4.054 |
0.330 |
8.14 |
0.551 |
0.04 |
7.66 |
| Chrysen/Triphenylen |
4.128 |
0.342 |
8.28 |
0.793 |
0.08 |
9.95 |
| Benzo(b+j+k)fluoranthen |
3.319 |
0.654 |
19.70 |
0.607 |
0.13 |
21.89 |
| Benzo(a)pyren |
0.505 |
0.039 |
7.76 |
0.089 |
0.02 |
16.92 |
| Indeno(1,2,3-cd)pyren |
0.312 |
0.044 |
13.96 |
0.023 |
0.01 |
56.48 |
| Dibenzo(a,h)anthracen |
0.072 |
0.010 |
13.87 |
0.009 |
0.01 |
63.30 |
| Benzo(g,h,i)perylen |
0.284 |
0.050 |
17.59 |
0.020 |
0.0 |
60.18 |
| Sum 16 EPA PAH |
51 |
5.4 |
11 |
8.0 |
0.8 |
9.5 |
| Sum 7 PAH |
19 |
2.8 |
15 |
3.0 |
0.3 |
11 |
SFE ekstraktionsdata 2
| Dato: |
17/3-99 |
17/3-99 |
17/3-99 |
17/3-99 |
17/3-99 |
17/3-99 |
| Apparat': |
SFE |
SFE |
SFE |
SFE |
SFE |
SFE |
| Metode: |
150 C |
150 C |
150 C |
150 C |
150 C |
150 C |
| Opløsningsmiddel: |
CO2 + MeOH |
CO2 + MeOH |
CO2 + MeOH |
CO2 + MeOH |
CO2 + MeOH |
CO2 + MeOH |
| Gram prøve |
2 |
2 |
2 |
2 |
2 |
2 |
| Prøve: |
MEAN |
Std.Dev. |
Rel. Std. |
MEAN |
Std.Dev. |
Rel. Std. |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| |
mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| Naphthalen d8 |
0.5 |
0.28 |
61.69 |
0.8 |
0.3 |
38.8 |
| Biphenyl d10 |
68.3 |
7.83 |
11.46 |
53.3 |
9.2 |
17.2 |
| Phenanthren d10 |
119.3 |
7.76 |
6.51 |
96.4 |
9.7 |
10.1 |
| Flouranthen d10 |
78.3 |
13.49 |
17.23 |
59.3 |
17.5 |
29.4 |
| Pyren d10 |
96.4 |
7.50 |
7.78 |
80.1 |
7.7 |
9.6 |
| Benz(a)pyren d12 |
25.7 |
10.29 |
40.02 |
18.1 |
10.2 |
56.0 |
| Dibenzo(a,h)anthracen d14 |
30.0 |
8.60 |
28.67 |
19.3 |
5.9 |
30.8 |
| Naphthalen |
0.058 |
0.022 |
37.92 |
0.028 |
0.006 |
20.82 |
| Acenaphthylen |
0.621 |
0.036 |
5.77 |
0.158 |
0.028 |
17.51 |
| Acenaphthen |
0.278 |
0.031 |
11.19 |
0.058 |
0.008 |
14.18 |
| Fluoren |
0.436 |
0.018 |
4.21 |
0.089 |
0.007 |
7.76 |
| Phenanthren |
6.061 |
0.259 |
4.28 |
0.922 |
0.051 |
5.51 |
| Anthracen |
1.052 |
0.048 |
4.53 |
0.216 |
0.016 |
7.52 |
| Fluoranthen |
17.610 |
2.255 |
12.80 |
2.405 |
0.539 |
22.40 |
| Pyren |
10.556 |
0.416 |
3.94 |
1.265 |
0.063 |
4.96 |
| Benz(a)anthracen |
3.017 |
0.261 |
8.65 |
0.356 |
0.052 |
14.62 |
| Chrysen/Triphenylen |
2.854 |
0.235 |
8.24 |
0.521 |
0.044 |
8.50 |
| Benzo(b+j+k)fluoranthen |
3.532 |
0.636 |
18.00 |
0.696 |
0.092 |
13.23 |
| Benzo(a)pyren |
1.408 |
0.336 |
23.86 |
0.143 |
0.026 |
18.34 |
| Indeno(1,2,3-cd)pyren |
0.727 |
0.214 |
29.43 |
0.170 |
0.036 |
21.40 |
| Dibenzo(a,h)anthracen |
0.152 |
0.058 |
37.86 |
0.041 |
0.012 |
28.85 |
| Benzo(g,h,i)perylen |
0.633 |
0.188 |
29.65 |
0.140 |
0.029 |
20.64 |
| Sum 16 EPA PAH |
49 |
2.5 |
5.1 |
7.2 |
0.3 |
4.7 |
| Sum 7 PAH |
23 |
2.1 |
9.1 |
3.5 |
0.4 |
12 |
Soxhlet ekstraktionsdata 1
| Dato: |
30/6-99 |
30/6-99 |
30/6-99 |
30/6-99 |
30/6-99 |
30/6-99 |
| Apparat': |
Soxhlet |
Soxhlet |
Soxhlet |
Soxhlet |
Soxhlet |
Soxhlet |
| Metode: |
EPA 3540 C |
EPA 3540 C |
EPA 3540 C |
EPA 3540 C |
EPA 3540 C |
EPA 3540 C |
| Opløsningsmiddel: |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
Acetone:Hexan |
| Gram prøve |
10 |
10 |
10 |
10 |
10 |
10 |
| Prøve: |
MEAN |
Std.Dev. |
RSD |
MEAN |
Std.Dev. |
RSD |
| |
Mg/kg TS |
mg/kg TS |
% |
mg/kg TS |
mg/kg TS |
% |
| |
HL |
HL |
HL |
LL |
LL |
LL |
| Naphthalen d8 |
66 |
31 |
47 |
47 |
8.72 |
18.55 |
| Biphenyl d10 |
88 |
19 |
21 |
83 |
7.00 |
8.43 |
| Phenanthren d10 |
102 |
12 |
11 |
103 |
17.32 |
16.82 |
| Flouranthen d10 |
111 |
10 |
8.9 |
115 |
4.93 |
4.30 |
| Pyren d10 |
113 |
9 |
7.7 |
115 |
5.69 |
4.93 |
| Benz(a)pyren d12 |
119 |
4 |
3.4 |
115 |
5.29 |
4.60 |
| Dibenzo(a,h)anthracen d14 |
110 |
8 |
7.4 |
114 |
8.33 |
7.28 |
| Naphthalen |
0.62 |
0.03 |
4.3 |
0.232 |
0.043 |
18.4 |
| Acenaphthylen |
0.72 |
0.12 |
16.5 |
0.159 |
0.016 |
10.1 |
| Acenaphthen |
0.16 |
0.01 |
7.4 |
0.033 |
0.001 |
1.8 |
| Fluoren |
0.37 |
0.03 |
8.7 |
0.070 |
0.009 |
13.2 |
| Phenanthren |
6.18 |
0.18 |
3.0 |
0.910 |
0.091 |
10.0 |
| Anthracen |
0.97 |
0.05 |
5.0 |
0.176 |
0.028 |
16.1 |
| Fluoranthen |
10.65 |
0.16 |
1.5 |
1.390 |
0.078 |
5.6 |
| Pyren |
8.38 |
0.04 |
0.5 |
1.101 |
0.018 |
1.6 |
| Benz(a)anthracen |
3.55 |
0.24 |
6.9 |
0.532 |
0.012 |
2.3 |
| Chrysen/Triphenylen |
3.50 |
0.17 |
5.0 |
0.657 |
0.032 |
4.9 |
| Benzo(b+j+k)fluoranthen |
7.24 |
0.26 |
3.6 |
1.421 |
0.083 |
5.8 |
| Benzo(a)pyren |
3.60 |
0.06 |
1.7 |
0.538 |
0.053 |
9.8 |
| Indeno(1,2,3-cd)pyren |
3.48 |
0.05 |
1.3 |
0.630 |
0.051 |
8.1 |
| Dibenzo(a,h)anthracen |
0.70 |
0.08 |
11.8 |
0.143 |
0.009 |
6.5 |
| Benzo(g,h,i)perylen |
3.49 |
0.10 |
2.9 |
0.627 |
0.023 |
3.6 |
| Sum 16 EPA PAH |
54 |
0.62 |
1.16 |
8.6 |
0.16 |
1.9 |
| Sum 7 PAH |
26 |
0.51 |
1.98 |
4.1 |
0.05 |
1.3 |
|