Survey of Dioxin Emission from PCP-treated Wood

5 Results

5.1 PCP screening of pallet board samples

Table 5.1 shows the analysed concentrations of pentachlorophenol in the pallet board samples. All samples have only been single-determined. The results show that 6 out of 10 samples contained pentachlorophenol. Sample number 2 from Portugal had the highest concentration of pentachlorophenol, and the dioxin concentration in this sample was therefore afterwards measured (see result in next section).

Table 5.1 shows that out of the 6 samples with a detected pentachlorophenol concentration, two of the samples came from Spain; two came from France and two from Portugal. This means that both analysed samples from Portugal and 2 out of the three samples from France were positive.

It should be noted that the concentration of PCP registered in the samples represents an average of the concentration over the entire thickness of the individual samples.

Table 5.1 Results of screening of pentachlorophenol in pallet board samples.

Sample number Type of goods Country Analysed amount [g] Concentration of pentachlorophenol [μg/kg]
1 Wine Spain 0.102 nd1
2 Port wine Portugal 0.103 231
3 Champagne France 0.102 nd
4 Wine Spain 0.100 nd
5 Langostillos claw in pickle Spain 0.100 nd
6 Green olives a la Provence France 0.101 21
7 Green olives Spain 0.100 33
8 Olives Spain 0.101 75
9 Wine France 0.100 166
10 Port Wine Portugal 0.101 26
Blind     0.100 7

* The results have been deducted the value of the blind sample.

1 Not detected.

5.2 Dioxin analysis of pallet board sample

Pallet board sample number 2 was analysed for dioxin, but as table 5.2 shows the dioxin concentration in the pallet board sample is low. It is noted that only one analysis has been made, and the result may thus be regarded as an indication of the dioxin level in these items rather than solid documentation.

As for PCP the concentration of dioxin registered in the sample represents an average of the concentration over the entire thickness of the sample.

Table 5.2 Results of dioxin analysis of pallet board sample no. 2

Sample number 2
Analysed amount [g] 0.103
Dioxin concentration ng/kg
2378-TCDD nd
12378-PeCDD nd
123478-HxCDD nd
123678-HxCDD nd
123789-HxCDD nd
1234678-HpCDD nd
OCDD nd
2378-TCDF 9.7
12378-PeCDF 4.9
23478-PeCDF nd
123478-HxCDF 6.8
123678-HxCDF 4.9
123789-HxCDF nd
234678-HxCDF nd
1234678-HpCDF nd
1234789-HpCDF nd
OCDF nd
WHO-TEQ 4.6
I-TEQ 4.6

nd = Not detected

5.3 Construction-wood samples

The five samples of construction wood have been analysed for dioxin by single determination. The pentachlorophenol concentration in the samples has not been analysed.

Table 5.3 shows the concentration of the different isomers measured and the total concentration of the dioxin isomers given in ng I-TEQ/kg and in ng WHO-TEQ/kg.

The concentration of dioxin registered in the samples represents an average of the concentration over the entire thickness of the individual samples.

Table 5.3 Results of dioxin analyses of the five samples of construction wood.

Sample number 1 2 3 4 5 Blind
Analysed amount [g] 1.03 1.00 1.00 1.01 1.00 1
Dioxin concentration ng/kg ng/kg ng/kg ng/kg ng/kg ng/kg
2378-TCDD 8.6 nd nd 0.3 0.9 0.1
12378-PeCDD 20.3 2.3 1.3 5.9 9.2  
123478-HxCDD nd nd nd nd 23  
123678-HxCDD 1527 88 201 470 159  
123789-HxCDD 189 8 13 133 48 0.1
1234678-HpCDD 47547 2958 9704 10223 8180 1.4
OCDD 189140 10243 89588 55519 55982 11.2
2378-TCDF 9.8 nd 0.1 1.9 11.6  
12378-PeCDF 6.4 1.1 0.6 4.0 6.5  
23478-PeCDF 26.0 2.4 3.0 17.7 33.6  
123478-HxCDF 217.1 18.1 181.0 75.6 33.0  
123678-HxCDF 139.2 18.5 24.3 59.0 44.5  
123789-HxCDF 31.7 2.0 9.6 18.8 12.6  
234678-HxCDF 151.4 16.6 27.9 84.3 58.0  
1234678-HpCDF 18503 1672 3995 12845 1472 0.4
1234789-HpCDF 1251 122 654 158 120  
OCDF 77128 9730 33396 20211 8648 1.3
WHO-TEQ 950 68 200 333 158 0.1
I-TEQ 1097 84 279 398 212 0.1

* The values have been deducted the values of the blind sample.

** The values written in italics are detected with high uncertainty.

nd = Not detected

 



Version 1.0 Juli 2004, © Danish Environmental Protection Agency