Some of HCFC-22 results from HFC mixtures (HFC-401a, HFC-402a, HFC-403a, HFC-408a, HFC-409a and HFC-502a) that are sent to the Kommune Kemi treatment plant for processing by Danish importers either as mixtures of pure refrigerants or in mixture cylinders. 4 Greenhouse gases4.1 Import of substancesAn overall picture of the trends in the import of greenhouse gases is given in Table 4.1, based on information from importers for the years 1987, 1989, 1992, and 1994-2001. 4.1.1 HFCsHFCs were imported by nine enterprises in 2001, of which five are Danish suppliers and four are user enterprises, importing directly from other EU countries. The total import (minus re-export) for all HFCs, according to the importers, has fallen from 1,027 tonnes in 2000 to 676 tonnes in 2001. This is a reduction of about 34% compared to 2000. The import of HFC-134a has fallen from 711.1 tonnes in 2000 to 472.8 tonnes in 2001. In particular it has been possible to ascertain a reduction in consumption by manufacturers of fridges, as there has been a significant reduction in production by one manufacturer. The import of HFC-152a has been reduced from 16.4 tonnes in 2000 to 11.1 tonnes in 2001.The import of HFC-404a has been reduced from 193.1 tonnes in 2000 to 126.3 tonnes in 2001. The reduction in the consumption of HFC-404a is to a large degree due to lower consumption by commercial refrigerators. It is not possible to explain this development, but it is clear that the refrigerator industry had a lower turnover in 2001 than in the year before. Therefore it can be assumed that there were fewer refillings in 2001 than in 2000. The import of HFC-407c has been reduced from 44.7 tonnes in 2000 to 40.3 tonnes in 2001. HFC-407c is a substitute refrigerant for HCFC-22 in stationary A/C systems. The import of other HFCs (HFC-408a, HFC-409a, HFC-410a, HFC-227, HFC-365 and HFC-23) measures 18.4 in 2001 compared with 24.1 tonnes in 2000. The year 2001 is the first year where an import of the new substance HFC-365 has been registered. The import of HFC-365 amounts to approx. 3.5-4 tonnes. HFC-365 has been developed by Solvey as a substitute for HFC-134a and other blowing agents for foam plastics. HFC-227 is often used as a substitute for CFC blowing agents, but the consumption for 2001 has not been ascertained. The import of HFC-507a has been reduced to 2.2 tonnes in 2001. In 2000 the import totalled 23.9 tonnes. The import of HFC-401a measures 4.1 tonnes and HFC-402a measures 0.8 tonnes. The consumption of these was also relatively small in 2000. 4.1.2 SulphurhexafluorideThree importers report imports and sales of 2.7 tonnes of sulphurhexafluoride in 2001. The areas of application concerned are the glass industry, high-voltage plants, and a small amount as trace gas for laboratory purposes. Use of SF6 in the metal industry was phased out in 2000. In addition, a supplier of GIS plants (power switches in high-voltage plant) imported 2 tonnes of SF6 in 2001 from another EU country. 4.1.3 Perfluorinated hydrocarbonsTwo importers report imports of mixture products containing perfluorinated substances. The substance in this case is perfluoropropane, C3F8, for refrigerant application in commercial refrigerators. Imports of this substance amount to approx. 3.2 tonnes. One producer reports imports and sales of detergent for electronics, containing approx. 0.5 tonnes of perfluoropropane. Table 4.1 4.2 Consumption distributed among application areasThe evaluation of the consumption distributed by application areas is estimated on the basis of information from importers and producers, and on records regarding sales to the Danish Refrigeration Installers Environmental Scheme (KMO). The consumption distributed by application area is shown in Table 4.2. Table 4.2
4.2.1 Consumption of HFC as refrigerantThe general trend in Danish consumption of HFCs for refrigerants is falling in all areas. Refrigerant consumption for production of refrigerators/freezers is falling because of a lower production of appliances based on HFCs. A similar consumption to 2001 is expected in future years. Similarly, there is a falling trend for refrigerant consumption for stationary refrigeration units. Due to new legislation banning construction of new HFC units after 2007, and generally better units, the trend is expected to continue to fall. For use of HFCs in mobile climate equipment there is a clear increase in consumption for refilling mobile equipment. The consumption distributed according to application area is based on information from producers and importers and on data from the Danish Refrigeration Installers Environmental Scheme (KMO), which receives records of the sales of substances from refrigerator installers and automobile garages, and so forth. The consumption of refrigerants relating to household fridges and freezers is calculated based on information from user enterprises. The consumer figures for refrigerants in commercial and stationary A/C systems, and mobile A/C systems and refrigerators are estimated using data from the Danish Refrigeration Installers Environmental Scheme (KMO) and import information. Table 4.3 shows the relative consumption of refrigerants according to application area. Table 4.3
The consumption of HFC-134a accounts for 59% of the overall consumption and the consumption of HFC-404a accounts for 27%. This distribution is comparable to that of the previous year. 4.2.2 Consumption of HFC for foam productionThere are no significant changes in Danish consumption of HFC for foam production since last year. However, over the past 5 years there has been a significant fall in consumption, partly because there is no longer any production of filler foam in Denmark. In the future it is expected that HFC consumption will fall within all foaming applications. With regard to the use of HFC as a propellant it is assumed that 2002 will be the last year in which HFC-134a is used as a propellant in the production of aerosol containers. The consumption of HFC-134a utilised in insulation foam in fridges, freezers and similar products amounts to 158.9 tonnes in 2001, which is a reduction compared to 2000. It is only HFC-134a that is used in this type of foam production. The consumption of HFC-134a and HFC-152a for other purposes, such as soft foam production and for use as a propellant, is approximately the same as the previous year. The consumption of HFC-134a amounts to 48 tonnes in 2001 compared to 50.4 tonnes in 2000. HFC-152a consumption has fallen from 15.4 tonnes in 2000 to 11.1 tonnes in 2001. In addition, consumption of HFC-365 and HFC-227 for foam production purposes measures 7.4 tonnes in total. HFC-365 is used as a substitute for HFC-134a and HFC-227 is typically a substitute for CFC. The information forms returned only state the sum total and therefore the calculations in other parts of this report assume a 50/50 consumption of these substances. 4.2.3 Consumption of SF6The overall consumption of SF6 in 2001 was 4.7 tonnes. The distribution of the consumption is shown in the table below. Table 4.4
|
Substance group |
DK consumption, tonnes |
GWP contribution, tonnes |
HFCs |
|
646 400 |
PFCs |
|
22 130 |
SF6 |
|
30 400 |
Total |
|
698 900 |
In this years evaluation of the emission from refrigerants the following distinctions have been made:
![]() | Fridges and freezers for household use |
![]() | Commercial refrigerators (in industry and shops) and stationary air conditioning systems |
![]() | Mobile air conditioning systems (in cars, trucks, busses, trains etc.) |
![]() | Refrigerated vans and lorries |
The actual emission from these sources occurs in connection with:
![]() | filling with refrigerants (0.5 % to 2 % of the consumption depending on the application area) |
![]() | continual release during the operational lifetime. An assumed average value which also accounts for release occurring as a result of accident and damage (10 % to 33 % of consumption per annum depending on application area) |
Release resulting from disposal does not count as emission in Denmark since Danish legislation ensures that management and treatment of refrigerants prevents such emissions. The release is defined as the writing-off of stock (the quantity of refrigerant contained in a product).
Table 4.6 shows the emission factors used in the determination of the emission from refrigerants in household and commercial fridges/freezers, commercial stationary refrigerators, and refrigerated vans and lorries.
Table 4.6
Factors in the determination of the emission from refrigerants in household and
commercial fridges/freezers, refrigerators, stationary A/C and (transport refrigerators) /4/
|
Fridges/freezers |
Commercial refrigerators and stationary A/C |
Transport refrigerators |
Filling |
2% |
1.5% |
0.5% |
Operation |
1% |
10% |
17% |
Disposal |
0% |
0% |
0% |
Lifetime |
15 years |
15 years |
15 years |
Commercial refrigerators and stationary A/C systems
The largest source of emission comes from stationary commercial refrigerators used in supermarkets and in industry. The most commonly used refrigerant in this product group is HFC-134a and HFC-404a.
The primary refrigerant used in A/C systems is HFC-407c, a high temperature refrigerant and substitute product for HCFC-22.
Used to a lesser extent are the refrigerants HFC-401a, HFC-402a, HFC-408a, HFC-409a, HFC-410a and HFC-507c.
It is not necessary to correct for the import and export of HFCs in stationary commercial refrigerators since filling takes place at the site of operation following installation.
Table 4.7 shows the actual emission evaluated for specific HFCs. The total emission of all HFCs is given in CO2 equivalents to take into account the different GWP values of the substances.
The determination of the GWP contribution in the category "other HFCs" (HFC-408a, HFC-409a and HFC-410a) incorporates a worst-case assumption made on the grounds of HFC-410a (50% HFC-32, 50% HFC-125). The GWP value for HFC-410a is 1,725.
Table 4.7
Actual emission and GWP contribution from commercial refrigerators 2001 and 2010,
tonnes
Source |
Substance |
Con- sump-tion, DK |
Stock |
Actual emis-sion |
GWP contribution 2001 |
GWP contribution 20102) |
Com- mercial refrige-rators and stationary A/C |
HFC-134a HFC-401a HFC-402a HFC-404a HFC-407c HFC-507a Other HFCs1) All substances |
102.4 4.1 0.8 113.7 40.3 2.2
|
650 39.4 42 705.7 132.5 43.5
|
62.6 4.5 4.7 67.7 10.9 4.6
|
81 300 0.1 7 800 220 600 16 600 14 300
357 300 |
95 000 0 2 700 282 500 24 000 6 300 13 600 424 100 |
1) | The category other includes HFC -408a, -409a, -410a (in the emission calculation a worst-case assumption is used on the grounds of the GWP value for HFC-410a). |
2) | The possible future scenario takes account of the effect of an implemented phasing-out of HFCs and other substances, and the effect of an implemented charge scheme. Conditions relating to the substitution of HCFC-22 with HFC-134a and HFC-404a are also taken into account. |
In the projection of emissions in 2010, in which concrete phase out dates are taken into account, as established in the Statutory Order on regulation of certain industrial greenhouse gases, it is estimated that the GWP contribution from commercial refrigerators in 2010 would be approx. 424,100 tonnes.
Fridges/freezers
The actual emission from refrigerants in fridges and freezers is determined on the basis of consumption corrected for import and export of HFCs. The determination assumes that the refrigerant is removed and treated upon disposal so that no emission occurs.
After adjusting for import and export, estimations based on values calculated in /3/ show that export accounts for 50 % of consumption. Only fridges containing HFC-134a are imported/exported. The determination is made on the basis of Denmarks foreign trade statistics of average figures for the amount of HFC-134a in a standard fridge/freezer manufactured in 1999. The statistical background data for this is given in Appendix 2.
In addition, the effect of charges in the reduction in consumption is taken into account in the case of HFC-134a fridges. This is not accounted for in the case of HFC-404a refrigerators because these products are an exception.
Table 4.8 shows the actual emission from fridges/freezers in 2001 and 2010.
Table 4.8
Emission of refrigerants from fridges/freezers 2000 and 2010, tonnes
|
2001 134a |
2010- |
2001 404a |
2010 404a |
Consumption |
130.1 |
106 |
6.5 |
6.5 |
Emission during production |
2.6 |
2.1 |
<1 |
<1 |
Export |
65.1 |
53 |
- |
- |
Stock |
678.4 |
1 027.9 |
64.6 |
112.3 |
Emission from stock |
6.2 |
10.1 |
0.6 |
1.2 |
Emission from treatment |
0 |
0 |
0 |
0 |
Actual emission |
8.8 |
12.2 |
<1 |
<1.5 |
GWP contribution, 000 tonnes of CO2 equivalents |
11.5 |
15.9 |
2.4 |
4.3 |
The total emission of HFC refrigerants from fridges/freezers in 2001 measures 13,900
tonnes CO2 equivalents. In the projections of the actual emissions a small
increase is expected to approx. 20,000 tonnes CO2 equivalents in 2010.
Mobile A/C
The emission from mobile A/C systems is released during filling and from continual loss of HFC-134a, and is also due to accident and damage.
The determination has been corrected for import and export of HFC-134a, which is the only HFC imported in A/C systems in cars and trucks. In Denmark filling is only carried out after import. Initial filling is carried out by car manufactures.
The total filling (stock) in Denmark in A/C systems in cars and trucks is determined using statistical information about annual imports and re-exports of cars, vans, and trucks. The statistical figures for imported units are multiplied by an estimated percentage that expresses the proportion of cars and trucks with air conditioning. In 1998 an evaluation was made of the stock for 1998 and the projections since then have accounted for a 20% proportion of cars and a 50% proportion of trucks.
In the present year, this estimate has been revised and the total stock figure has been updated. The conditions employed in the final evaluation are shown in the table below. The conditions have been grouped according to individual statistical categories for types of transport and they represent estimated values based on information from car importers and refrigerator service enterprises.
Table 4.9.
Conditions used in the calculation of stock in mobile A/C systems
|
Percentage with A/C |
Filling, Kg HFC-134a |
Percentage of all vehicles that undergo A/C maintenance |
Cars |
10 % |
0.75 |
50 % |
Busses |
20 % |
9 |
20 % |
Vans |
10 % |
0.8 |
50 % |
Trucks up to 6 t |
50% |
1.2 |
50 % |
Trucks over 6 t |
50% |
1.5 |
40 % |
The Danish Automobile Dealers Association (DAF) publishes annual statistics of the number
of vehicles in Denmark /17/. This data forms the basis for evaluating
the HFC-134a stock in vehicles in Denmark below. Determinations are also provided for the
percentage of installed A/C systems that are currently undergoing servicing and are thus
refilled with refrigerant upon leakage and other repairs. This forms the basis for
determining the amount of refilling of HFC-134a in vehicles in Denmark in 2001.
The results are shown in the table below.
Table 4.10.
Determination of Danish stock in mobile A/C systems in 2001 grouped by vehicle type
|
|
2001 |
Stock, kg |
Filling undergoing maintenance |
Refrigerant (HFC-134a) refilled in Danish vehicles 2001, tonnes |
Cars |
|
1 854 060 |
139 055 |
69 527 |
23.2 |
Buses |
|
13 968 |
25 142 |
5 028 |
1.7 |
Vans |
|
335 990 |
13 440 |
6 720 |
2.2 |
Trucks up to 6 t |
|
4 628 |
2 777 |
1388 |
0.5 |
Trucks over 6 t |
|
32 975 |
2 4731 |
9 892 |
3.3 |
TOTAL |
|
|
205 145 |
92 556 |
30.9 |
The figures shown in the table have been determined using various assumptions, such as the estimated percentage of the various types of vehicles with A/C systems. The total stock of HFC-134a in mobile A/C systems in Denmark has been calculated as 203 tonnes in 2001. This increase is expected to increase further in coming years since there is a continuing trend of more vehicles and new vehicles with more A/C systems. The filled amount of HFC-134a refrigerant in mobile A/C systems in 2001 has been calculated as 30.9 tonnes. This alone accounts for usage in refilling during maintenance of existing systems /16/.
Actual emissions from mobile A/C systems have been calculated on the basis of the following emission factors.
Table 4.11
Emission factors for mobile A/C systems
|
Emission factor |
Filling |
4.5 % |
Operation |
30 % |
Destruction |
0 % |
The table below shows the actual emissions from mobile A/C systems in Denmark. The table
has been prepared on the basis of a steady-state assumption where consumption for
refilling in 2010 is assumed to be the same as in 2001. This assumption is very
conservative as all signs indicate continued increases in vehicles with A/C systems.
Table 4.12
Calculated emissions of HFC-134a from mobile A/C systems in 2001 and 2010
|
2001, tonnes |
2010, tonnes |
Imported via vehicles |
27.8 |
27.8 |
Consumption with refilling |
30.9 |
30.9 |
Total addition to stock |
58.7 |
58.7 |
Emission from filling |
1.4 |
1.4 |
Emission from operation of stock |
44.8 |
57.5 |
Total reduction in stock |
46.2 |
58.9 |
Stock |
205.1 |
191.5 |
Actual emission |
46.2 |
58.9 |
GWP contribution |
60 000 |
76 600 |
Refrigerated vans and lorries
The evaluation of refrigerated vans and lorries employs the following Danish emission factors, which are based on a study of the servicing of Danish transport refrigerators /17/.
|
Emission factor |
Filling |
0.5 % |
Operation |
17 % per year |
Destruction |
0 % |
There are an estimated 5,500-6,000 refrigerated vans and lorries in Denmark /16/. These refrigerators require an average filling of approx. 8 kg,
equivalent to 44-49 tonnes of refrigerant altogether, either HFC-134a, HFC-404a or
HCFC-22. An estimated one third of the refrigerators utilise HCFC-22 and for HFC
refrigerators 75 % of the HFC stock consists of HFC-404a. The remaining 25 % use HFC-134a.
This results in the following stock distribution for 2000:
![]() | Stock in refrigerated vans and lorries containing HFC-404a = 22-24.5 (23.2 tonnes) |
![]() | Stock in refrigerated vans and lorries containing HFC-134a = 7.3-8.1 (7.7 tonnes) |
![]() | Stock in refrigerated vans and lorries containing HCFC-22 = 14.6-16.3 (15.5 tonnes) |
The actual emission from refrigerated vans and lorries is stated in the table below.
The HFC emission determination used for foam plastic products employs two determination principles, depending on the type of product:
1) Hard PUR foam plastics (closed cell)
2) Soft PUR foam plastics (open cell)
The following basis of determination has been used in the emission calculation for foam plastic products.
Table 4.13
Factors in the determination of emission from foam plastic products.
|
Hard PUR foam |
Soft PUR foam |
Polyether foam |
Emission during production |
10% |
100% |
15% |
Annual release |
4.5% |
- |
4.5% |
Lifetime |
15 |
- |
1-10 (3 years) |
Insulating foam
Hard foam plastics produced with HFC-134a are mainly used in insulating foam in fridges/freezers. The emission determinations for insulating foam in fridges/freezers are adjusted for the import and export of fridges /freezers. The determinations are carried out on the basis of 1998 figures for the average quantity contained in fridges/freezers for household use. Based on manufacturer information the average content has been estimated at 240 grams per product, and in 1998 there was a net export of two tonnes of HFC-134a (see Appendix 3).
Usage of HFC-134a in insulating foam in industrial and commercial refrigerators is very limited. Insulating foam for such purposes is usually produced using HCFC-141b.
The actual emission of HFC-134a from insulating foam is summarised in Table 4.12.
Table 4.14
Emission of HFCs from insulating foam, tonnes
|
2001 |
2010 |
Consumption |
158.9 |
0 |
Emission during production |
15.9 |
0 |
Export |
2 |
0 |
Stock |
1462 |
1138 |
Emission from stock |
68.9 |
89.2 |
Actual emission |
84.8 |
89.2 |
GWP contribution, 000 tonnes of CO2 equivalents |
110.2 |
115.9 |
In the projections for 2010, it is estimated that the stock will reduce as a result of the
phase out of HFC-134a in foam production by 1/1 2006 in compliance with regulations on the
phase out of strong greenhouse gases.
Foam polyether
There is only one Danish producer of foam polyether and the firm concerned in this specialised area of production did not wish to provide any information again on their consumption for 2001. Therefore the firms consumption of HFC-134a in 1999 is taken in their polyether-based shoe production in 2001. The consumption in 1999 was reported as approx. 5 tonnes and the actual emission is estimated at 2.1 tonnes, equivalent to 2,800 tonnes CO2 equivalents. The determination makes the assumption that no emission is released upon disposal since the gases are destroyed during incineration.
Evaluations from 1998 are used for the export adjustments. In the evaluation it is estimated that 5 % of all shoes with plastic, rubber, or leather soles contain polyether. In 1998 approx. 12.8 million pairs of shoes were exported (Statistics Denmark, Foreign Trade) and it is estimated that a single pair of shoes contains an average of 8 grams HFC-134a. Based on these figures the export is estimated at 0.3 tonnes of HFC-134a.
Joint foam/soft foam/aerosol sprays
The emission of HFCs from joint foam and soft foam (open cell foam) accounts for 100% of the consumption in the year of application /4/. The emission from soft foam occurs during production and it is thus not necessary to correct for import/export.
Joint foam is no longer produced in Denmark, leaving only emissions from imported joint foam products to be accounted for. The determination of joint foam imports is based on previous information made available by the producers /2/. An estimated average of 100 grams of HFC-134a and 25 grams of HFC-152 per can of joint foam is considered reasonable. The emission calculation assumes that the joint foam is used in the same year as the production year.
It is estimated by the producers that in 1998 the amount of imported HFC-based joint foam was equivalent to 10 tonnes of HFC-134a and 1 ton of HFC-152a. This import quantity is also assumed for 2001, following which the consumption will be phased-out. This is equivalent to a GWP contribution from joint foam in 2001 of 13,140 tonnes CO2 equivalents.
The emission of HFC in the production of soft foam is identical to the consumption in Denmark and the emission of HFC as a propellant used in aerosol sprays is equal to the consumption of HFC-based aerosol sprays in Denmark after adjusting for import and export. The total emission from these two areas is 43.1 tonnes of HFC-134a, equivalent to 57,000 tonnes CO2 equivalents, and 11.1 tonnes of HFC-152a, equivalent to 1,600 tonnes CO2 equivalents, which is a small decrease compared with 2000.
Medical supplies
Due to marginal emissions the HFC emission from medical supplies has not been evaluated this year.
The total emission of SF6 in 2001 has been determined at approx. 1.3 tonnes, equivalent to a GWP contribution of approx. 30,400 tonnes CO2 equivalents. The net consumption was 4.7 tonnes.
The emissions derive from four sources, of which power switches and sealed glazing units for windowpanes are the main sources, contributing approx. 41 % and 34 %.
Sealed glazing units for windowpanes. The emission determination for SF6 from sealed glazing units for windowpanes has been evaluated using information from producers and industry experts. The emission factors below are employed in the determination. The emission of SF6 in the life cycle of a sealed glazing units for windowpanes consists of three phases:
![]() | Production, 15% resulting from filling. |
![]() | Ongoing release following installation, 1% per year. |
![]() | Emission during disposal of windows, equivalent to the remaining quantity of SF6. Based on an average expected lifetime of 20 years this gives an emission of 66 % during treatment. The determination assumes that the gas is not released from the windows prior to disposal. |
The determination of import and export of sealed glazing units for window panes filled with SF6 takes into account an estimated net export of 50 %.
Table 4.15.
Emission of SF6 from sealed glazing units for windowpanes, tonnes
|
2001 |
2010 |
2015 |
Consumption |
0.2 |
0 |
0 |
Emission from production |
0 |
0 |
0 |
Release from installed sealed glazing units for window panes |
0.4 |
0.4 |
0.2 |
Export |
0.1 |
0 |
0 |
Emission during disposal |
0 |
0 |
3.7 |
Stock |
39.9 |
36.5 |
18.5 |
Actual emission |
0.4 |
0.4 |
3.9 |
GWP contribution, 000 tonnes CO2 equivalents |
10.2 |
8.8 |
94.5 |
The projections assume that the consumption will be zero in 2003. In subsequent years the
emission will rise again due to the start of disposal /substitution of windows with SF6
thermal glass and in 2015 it is estimated that the GWP contribution from thermal glass
will be 94,500 tonnes CO2 equivalents.
Metal work
Metal workers in Denmark no longer use sulphurhexafluoride in magnesium smelting.
Power switches in high-voltage plant
Power switches are filled or refilled with SF6, either during new installations of plant or during service and repair. The filling is usually carried out at new plant and a small proportion of the consumption is due to re-filling /11/.
Emissions from power switches in high-voltage plant are released according to the following:
![]() | release of 5 % on filling with new gas |
![]() | ongoing release of 0.5 % of the stock |
![]() | release of 5 % on drawing off and recycling of used gas |
No emission is assumed to result from disposal since the used SF6 is drawn off from the power switches and is either re-used internally by the power enterprise concerned or is re-used externally through means of a collection scheme. The emission resulting from external re-use is determined on the assumption that 0.5 % of the annual stock is sent for external re-use.
Table 4.16 shows the evaluated actual emission from SF6 power switches.
Table 4.16
Emission of SF6 from power switches in high-voltage plant 2000, 2010, and
2015, tonnes
|
2001 |
2010 |
2015 |
Consumption |
4.4 |
3 |
3 |
Emission during service |
0.2 |
0.15 |
0.15 |
Emission from re-use |
0.02 |
0.02 |
0.03 |
Emission from stock |
0.28 |
0.4 |
0.46 |
Stock |
61.2 |
83.5 |
95.4 |
Actual emission |
0.50 |
0.6 |
0.6 |
GWP contribution, 000 tonnes of CO2 equivalents |
12.5 |
13.7 |
15.2 |
Laboratories
In 2001 the consumption for laboratory purposes measures 0.2 tonnes and the actual emission amounts to 5,000 tonnes CO2 equivalents.
Running shoes
Information provided by importers shows that the quantity of SF6 contained in imported running shoes totals approx. 1 tonne, imported during the period 1990-1998. The emission of SF6 occurs as a result of the disposal of the shoes. The emission from running shoes in 2001 is estimated at 0.11 tonnes as in previous years, which is equivalent to a GWP contribution of approx. 2,650 tonnes CO2 equivalents. The consumption of SF6 for use in running shoes will end in 2003.
The actual emission of perfluoropropane has been calculated at 22,000 tonnes CO2 equivalents in 2001 and the total consumption measures approx. 3.7 tonnes. Perfluoropropane is the only known perfluorinated hydrocarbon used in Denmark. The emission is released from refrigerants in commercial refrigerators and from cleaning liquids for electronics.
The consumption of perfluoropropane in refrigerants for commercial refrigerators in 2001 was 3.2 tonnes and the stock in commercial refrigerators was evaluated at approx. 26.5 tonnes. The emission in 2001 has been determined as approx. 2.6 tonnes, equivalent to a GWP contribution of 18,500 tonnes of CO2 equivalents. Since mixture products containing PFC are used in stationary refrigerators adjustments have not been made for the import and export of the substance in products.
The consumption of perfluoropropane in liquid cleaners for electronics has been reported as 0.5 tonnes in 2001 and the actual emission amounts to 3,600 tonnes of CO2 equivalents.
/1/ | Arbejdsrapport nr. 20. Forbrug og emissioner af 8 fluorerede
og klorerede kulbrinter, Miljøstyrelsen, 1996. |
/2/ | Miljøprojekt nr. 523. Ozonlagsnedbrydende stoffer og visse
drivhusgasser - 1998, Miljøstyrelsen, 2000. [Back] |
/3/ | Udenrigshandelen fordelt på varer og land. Januar-december
1989, 1990-1999. Danmarks Statistik. [Back] |
/4/ | Reference Manual and Workbook of the IPCC 1996 Revised
Guidelines for National Greenhouse Gas Inventories, IPCC Switzerland September 1996. [Back] |
/5/ | Ozonlaget og drivhuseffekten. Miljøstyrelsen, april 1996. [Back] |
/6/ | Beskyttelse af ozonlaget - nordisk perspektiv. Nordisk
Ministerråd, okt. 1997. [Back] |
/7/ | DEFU Komiterapport 94. Håndtering af SF6 og dets
reaktionsprodukter i elforsyningsanlæg. |
/8/ | Methods used to Estimate Emission Inventories of
Hydrofluorocarbons, Perfluorocarbons and Sulphur Hexafluoride. Draft report prepared for
the UNFCCC secretariat. March Consulting, May 1999. |
/9/ | Hvor kommer luftforureningen fra? - fakta om kilder, stoffer
og udvikling. TEMA-rapport fra DMU, 29/1999. |
/10/ | Erstatning af kraftige drivhusgasser (HFC'er, PFC'er, SF6).
Per Henrik Pedersen, Miljøstyrelsen 1998. (Substitutes for Potent Greenhouse Gases
Final Report, Per Henrik Pedersen, Danish Environmental Protection Agency, 1999) [Back] |
/11/ | Indsamling og genanvendelse af SF6 fra
højspændingsanlæg. Tomas Sander Poulsen, Miljøstyrelsen 2000. [Back] |
/12/ | Denmarks National Inventory Report Submitted
under the UN Convention on Climate Change. Illerup, J.B., Lyck, E., Winther, M. Rasmussen,
E. DMU, 2000 Arbejdsrapport nr. 127 (http://arbejdsrapporter.dmu.dk). [Back] |
/13/ | Arbejdsrapport nr. 580. Ozonlagsnedbrydende stoffer og visse
drivhusgasser -1999, Miljøstyrelsen, 2001. [Back] |
/14/ | Denmarks National Inventory Report. Submitted under the
UN Framework Convention on Climate Change 1990-1999. Emissions Inventories. Department of
Policy Analysis. Illerup, Lyck, Winther, 2001. 675 pp Research Notes from NERI 149
(http://www.dmu.dk/1_viden/2_publikationer/ 3_arbrapporter/rapporter/AR149.pdf) |
/15/ | Annual Danish Atmospheric Emissions Inventory. 1999. Illerup,
Andersen, Winther, Lyck, Bruun. National Environmental Research Institute, Denmark. 8 pp. |
/16/ | Revurdering af emissionsfaktorer for kommercielle køleanlæg
og mobile A/C og køleanlæg. Poulsen, T.S, COWI; Arbejdsrapport for Miljøstyrelsen,
2002. (I tryk) [Back] |
/17/ | D.A.F prepare statistics of registered vehicles, analysed
into various categosries of vehicle. These statistics are updated annaully and used to
calculate Danish filling of HFC-134a in vehicles. [Back] |
Table 1.a
Ozone-depleting substances, their chemical formulas and ODP values. Regulated by the
Montreal Protocol.
Substance |
Chemical formula |
ODP values |
CFCs CFC-11 CFC-12 CFC-113 CFC-115 Other CFCs |
CFCl3 CF2Cl2 C2F3Cl3 C2F5Cl - |
1.0 1.0 0.8 0.6 - |
Tetrachloromethane |
CCl4 |
1.1 |
1,1,1-trichloroethane |
CH3CCl3 |
0.1 |
Halons Halon-1301 Halon-1211 Halon-2402 |
CF3Br CF2BrCl CF2BrCF2Br |
10 3 6 |
Methylbromide |
CH3Br |
0.6 (1) |
HCFCs HCFC-22 HCFC-123 HCFC-141 b HCFC-142 b |
CHF2Cl C2H3FCl2 C2H3F2Cl - |
0.055 0.11
0.065 |
(1) | Changed from 0.7 to 0.6 at the 7th Meeting of the Parties to the Montreal Protocol, December, 1995. 0.6 is used in the determinations for 1996 and 1997. |
Table 1.b
Pure(1) greenhouse gases, their chemical formulas and GWP values,
stipulated in the Kyoto Protocol.
Substance name |
Chemical formula |
GWP value |
HFCs HFC-32 HFC-125 HFC-134 a HFC-143 a HFC-152 a HFC-245 HFC-365 HFC-404 a(2) HFC-401a(3) HFC-402a(4) HFC-407c(5) HFC-408a(6) HFC-409a(7) HFC-410a(8) HFC-507a(9) |
CH2FH2 C2HF5 CF3CFH2 C2H3F3 CF2HCH3
- - |
650 2,800 1,300 3,800 140 950 890 3,260 18 1,680 1,525 1,030 0 1,725 3,300 |
Sulphurhexafluoride |
SF6 |
23,900 |
Perfluorinated hydrocarbons Tetrafluoromethane (perfluoromethane) Fluoroethane (perfluoroethane) Fluoropropane (perfluoropropane) Fluorocyclobutane (perfluorocyclobutane) Fluorohexane (perfluorohexane) |
CF4 C2F6 C3F8 C-C4F8 C6F14 |
6,500 9,200 7,000 8,700 7,400 |
(1) | Not having an ozone-depleting effect. |
(2) | Mixture consisting of 52% HFC-143a, 44% HFC-125 and 4% HFC-134a. The GWP value is determined from this. |
(3) | Mixture consisting of 53% HCFC-22, 13% HFC-152a and 34% HCFC-124. The GWP value is determined from this. |
(4) | Mixture consisting of 38% HCFC-22, 60% HFC-125 and 2% propane. The GWP value is determined from this. |
(5) | Mixture consisting of 25% HFC 125, 52% HFC 134a, and 23% HFC 32. The GWP value is determined from this. |
(6) | Mixture consisting of 46% HFC 143a and 7% HFC 125. The GWP value is determined from this. |
(7) | A HFCFC mixture consisting entirely of HCFCs, where the GWP value in accordance with the climate convention guidelines is 0, since the mixture does not contain greenhouse gases. The real GWP value is 1,440. |
(8) | Mixture consisting of 50% HFC 32 and 50% HFC-125. |
(9) | Mixture consisting of 50% HFC 125 and 50% HFC 143a. The GWP value is determined from this. |
Table 1.
Statistical data concerning import and export calculated as net export of fridges and
freezers (commercial + household).
Import/export of fridges/freezers
Key figures, refrigerant + foam: |
grams 134a |
Fridges/freezers |
351 |
Fridges |
305 |
Chest freezers |
404 |
Freezers |
367 |
Export, units |
1998 |
1997 |
1996 |
1995 |
1994 |
1993 |
1992 |
Fridges/freezers |
26 387 |
65 491 |
40 040 |
48 332 |
47 851 |
72 017 |
66 488 |
Fridges |
-109 550 |
4 308 |
-30 381 |
-90 011 |
-29 184 |
-11 382 |
-7 250 |
Chest freezers |
815 523 |
778 580 |
701 748 |
879 172 |
855 691 |
771 198 |
766 453 |
Freezers |
89 878 |
135 376 |
56 385 |
72 232 |
68 278 |
80 312 |
92 278 |
Export, units in total |
822 238 |
983 755 |
767 792 |
909 725 |
942 636 |
912 145 |
917 969 |
Export of foam (a16 chest freezers) |
6 715 |
205 175 |
66 044 |
30 553 |
86 945 |
140 947 |
151 516 |
HFC export, tons |
|
|
|
|
|
|
|
HFC 134a |
338.3 |
388.5 |
309.0 |
371.2 |
372.4 |
90.7 |
0.0 |
HFC 134a (foam) |
197.3 |
236.1 |
184.3 |
218.3 |
169.7 |
54.7 |
|
HFC 134a (refrigerant) |
141.0 |
152.4 |
124.7 |
152.9 |
202.7 |
36.0 |
|
HFC-134a (foam, exp) |
1.6 |
49.2 |
15.9 |
7.3 |
20.9 |
33.8 |
36.4 |
It should be noted that this is an over simplification since the quantity of HFC used for
foam and refrigerant varies depending on the producer and product size. The average
quantities used in evaluation are shown in Table 2.
Table 2.
Average content of HFC refrigerant in household refrigerators and commercial
refrigerators/freezers.
Category |
Fridge/freezer |
Fridge |
Chest freezer |
Freezer |
HFC-134a |
111 g |
65 g |
164 g |
127 g |
Table 3.
Statistical data on the import and export of cars and trucks.
Air conditioning |
Cars |
Trucks |
In total, tons |
Net import, 1998 |
151 385 |
26 249 |
|
Proportion with A/C |
151 38.5 |
13 124 |
|
Quantity of HFC 134a, kg |
11 353.875 |
16 405.625 |
27.8 |
Cars: 10% with A/C and 0.75 kg - 134a
Trucks: 50% with A/C and 1.25 kg - 134a
Table 4.
Projection, with 30% in 2005
Air conditioning |
Cars |
Trucks |
In total, tons |
Net import, 1998 |
151 385 |
26 249 |
|
Proportion with A/C |
45 415.5 |
13 124.5 |
|
Quantity of HFC 134a, kg |
34 061.625 |
16 405.625 |
50.5 |
Table 5.
Projection, with 50% in 2005, cars
Air conditioning |
Cars |
Trucks |
I alt, tons |
Net import, 1998 |
151 385 |
26 249 |
|
Proportion with A/C |
75 692.5 |
13 124.5 |
|
Quantity of HFC 134a, kg |
56 769.375 |
16 405.625 |
73.2 |
Appendix 3 - Consumption and emissions of ozone depleting substances in Greenland
Statistics Denmark registers both imports to Greenland and exports from Denmark to Greenland.
The trends in supply to Greenland during the period 1990 to 2001 are shown in Table 1.
Table 1.
Trends in supply to Greenland based on data from Statistics Denmark, tonnes.
Sub- stance |
1990 |
1991 |
1992 |
1993 |
1994 |
1995 |
1996 |
1997 |
1998 |
1999 |
2000 |
2001 |
CFC-11 |
5.5 |
0.1 |
4.5 |
0 |
2.2 |
1.6 |
0 |
0 |
2.1 |
1.9 |
<0.3 |
0 |
CFC-12 |
6.0 |
0 |
0.1 |
0 |
0.7 |
6.7 |
10.3 |
0 |
1.2 |
0 |
0 |
0 |
CFC-113 |
- |
- |
- |
- |
- |
- |
- |
- |
0 |
0 |
<0.2 |
0 |
CFC-115 |
- |
- |
- |
31 |
5.5 |
0 |
0 |
0.2 |
0.4 |
0 |
0 |
0 |
All CFCs |
13 |
7 |
6 |
31 |
8 |
8 |
10 |
0.2 |
3.7 |
1.9 |
<0.5 |
0 |
Based on the statistics available it was not possible to evaluate the consumption of
substances other than those shown in the table, as these are the only substances specified
individually. The export substance group "Halogen derivatives of methane, ethane or
propane", which is assumed to contain substances such as HFCs and HCFCs, represented
an export to Greenland of 10.1 tonnes in 2001. In 2000 the export was 0 tonnes and in 1999
it was 29.3 tonnes.
There is no information registered on imports of CFCs to Greenland in 2001. In 2000 the import was <0.5 tonnes and in 1999 it was 1.9 tonnes. The import of HCFC-22 cannot be quantified on the basis of information on foreign trade from Statistics Denmark.
The above data does not provide an ODP-weighted consumption for 2001.
Appendix 4 -GWP contribution from HFCs, PFCs, and SF6 1993-2020.The table below shows determined GWP contributions.
The emission projections are determined by starting with a steady state consumption using 2001 as the reference year and employing a series of dates for the phasing-out of specific substances in accordance with the phasing-out process of strong greenhouse gases. A charge effect is also included in the relevant areas of application and expected increases in several application areas are taken into account as much as possible, as are reductions in several of the applications areas.
The calculated GWP contribution expresses the actual emission, corrected for import and export (the latest basis of determination).
Table 1.
GWP contribution, 000 tonnes from HFCs, PFCs and SF6 1993-20202
2 | In light of new knowledge, the determinations of the GWP contributions have been altered in relation to last years evaluation /13/. |