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Ozone depleting substances and the greenhouse gases HFCs, PFCs and SF6
On behalf of the Danish Environmental Protection Agency, COWI has conducted an
assessment of the Danish consumption and emissions of ozone-depleting substances and the
greenhouse gases HFCs, PFCs, and SF6 for 2001. The evaluation survey has been
carried out in continuation of previous assessments, refer to /13/ and references in this report.
The report provides an evaluation of the actual emissions of HFCs, PFCs, and SF6.
This method of determination was first used in the 1998 evaluation /2/. The determination of the actual emissions takes into
account the emissions from stock contained in products and adjustments have been made for
the import and export of the substances contained in products.
In 2001, the method of determination underwent further development and now defines
Danish emission factors for certain primary areas of application such as commercial
refrigerators and mobile refrigerator units. In order to ensure consistency of the
determination, the new basis of determination has been used in the 2001 evaluation for all
historical data back to 1990.
The report has been prepared partly to enable Denmark to fulfil its international
obligations to provide statistics in the area and partly to follow the trend in
consumption of ozone-depleting substances and emissions of HFCs, PFCs, and SF6.
A report on Danish emissions is given in reference /18/ as an example on the reporting as
part of international obligations.
The ozone-depleting substances regulated in the Montreal Protocol are depleting the
earths protective ozone layer at a much greater rate than natural processes
reproduce ozone. This is disturbing the natural balance and leading to an increase in
dangerous ultraviolet radiation. The depletion is dependent on the different depleting
potentials of specific substances - ODP values (Ozone-depleting Potential).
Greenhouse gases cause an increase in the ability of the atmosphere to retain heat
radiated from the earth. Consequently the temperature of the earths surface rises
and this can lead to climate changes. There are several ozone-depleting substances that
also have a strong greenhouse effect.
The potential effect of different greenhouse gases varies from substance to substance.
This potential is expressed by a GWP value (Global Warming Potential). The so-called
pure greenhouse gases that do not have an ozone-depleting effect, but which
have high GWP values (HFCs, PFCs and SF6) are regulated in the Kyoto Protocol
under the Climate Change Convention.
The Danish Environmental Protection Agency has published a booklet on the ozone layer
and the greenhouse effect /5/, and in cooperation with
the other Nordic countries the Agency has published a booklet on the protection of the
ozone layer Nordic Perspective /6/. The Danish
Environmental Protection Agency has also published a report on substitutes for the
greenhouse gases HFCs, PFCs and SF6 /10/.
The project has been overseen by a monitoring group which has reviewed the results of
the assessment. The monitoring group consisted of:
 | Frank Jensen, Danish Environmental Protection Agency |
 | Erik Lyck, National Environmental Research Institute, Denmark (DMU) |
 | Confederation of Danish Industries (DI) |
 | Statistics Denmark |
 | Tomas Sander Poulsen, COWI |
The objective of the project is to evaluate the 2001 consumption of recently produced
ozone-depleting substances and the consumption and the actual emission of the greenhouse
gases HFCs, PFCs, and SF6. The evaluation has been made partly in accordance
with the IPCC guidelines, the Intergovernmental Panel on Climate Change /4/, and partly following the methods employed in previous
evaluations.
In Appendix 1, Tables 1.a and 1.b show the ozone-depleting substances regulated in the
Montreal Protocol, their chemical formulas and ODP values (Ozone-depleting Potential), and
the pure potent greenhouse gases covered by the Kyoto Protocol under the
Climate Change Convention, and their chemical formulas and GWP values (Global Warming
Potential).
Ozone-depleting substances
This evaluation survey covers the net consumption of ozone-depleting substances.
The term net consumption is understood as the amount of imported goods in bulk or drums,
not counting any re-export of substances as raw materials.
Ozone-depleting substances contained in finished products that are imported and
exported are not included in the evaluation. This delimitation is in full compliance with
international guidelines.
The evaluation does not account for the consumption of ozone-depleting substances as
raw material used in the production of other substances, such as tetrachloromethane, which
are not subsequently emitted to the atmosphere.
The information on consumption has been gathered from importers, suppliers and user
enterprises (usually the purchasing departments), and Statistics Denmark. The method of
data gathering used ensures that the information collected corresponds to the quantities
of substances that are traded. The purchase and sales figures are utilised in this
evaluation as an expression synonymous with the level of consumption. This approach is
considered to be suitable and adequate for the present purpose, since experience from
previous projects shows that a levelling out occurs with time and the substances
sold/bought are consumed within a relatively small time horizon.
None of the substances covered here are produced in Denmark. Furthermore,
ozone-depleting substances in Denmark are transported for treatment at chemical waste
processing plants in Denmark. This data is included in the evaluation, but is not offset
in the consumption figures, as was the case in all previous surveys.
Greenhouse gases
The evaluation of the actual emissions of the greenhouse gases HFCs, PFCs and SF6
has been carried out in continuation of foregoing assessments which have become
increasingly more accurate as advances have been made in internationally approved
guidelines (IPCC Guidelines) and the ability to gather more detailed data.
The evaluation of actual emissions includes the quantification and determination of any
import and export of HFCs, PFCs, and SF6 contained in products, and takes into
account the substances in stock form. This is in accordance with the latest and most
accurate method of determination (Tier 2) among the available methods provided in the IPCC
Guidelines /4/.
Consumption and emissions
The evaluation of consumption and determination of emissions and stock have been
carried out based on information from six sources:
 | Importers, agency enterprises, wholesalers, and suppliers |
 | Consuming enterprises, and trade and industry associations |
 | Recycling enterprises and chemical waste recycling plants |
 | Statistics Denmark |
 | Danish Refrigeration Installers Environmental Scheme (KMO) |
 | Previous evaluations of HFCs, PFCs and SF6 /2,
11/. |
Information for evaluation is firstly gathered by means of a questionnaire survey. The
responses to the questionnaires are supplemented where necessary with information gathered
by telephone.
The results of the project are primarily based on the information received from
enterprise and importer respondents etc.
The information gathered from importers and suppliers is recorded with information on
consumer enterprises in order to monitor any disagreements between purchase and sales
information and application of the substances. In some cases the application of individual
substances can be estimated on the basis of two sources, given that the majority of the
consuming enterprises are known. In cases where not all the user enterprises specify the
application of substances, the consumption of individual substances is estimated from the
information provided by importers, suppliers, and any industry-related organisations, such
as the Danish Refrigeration Installers Environmental Scheme (KMO).
Occasionally there are disagreements in the information provided by suppliers and user
enterprises. This is partly due to imports from other EU countries, changes in stocks of
substances, or a lack of correspondence between the quantities sold and consumed. It can
also be due to a degree of uncertainty in the method of determination used by enterprises.
Sales and consumption information has been harmonised.
The average degree of uncertainty in the reports consumption figures (sold and
bought quantities) is estimated at approx. 10-15%, and slightly greater for data regarding
the areas of application. The degree of uncertainty in the determination of actual
emissions is estimated at 20-25% depending on import/export information on the actual
products.
The evaluation has been conducted using two different methods /2/:
 | The potential emission (ozone-depleting substances) |
 | The actual emission (HFCs, PFCs and SF6) |
The ozone-depleting substances are not included in the determinations of emissions of
greenhouse gases, since ozone-depleting substances are regulated by the Montreal Protocol.
When evaluating the emission of ozone-depleting substances, the net consumption is
considered equivalent to the potential emission. Thus:
Potential emission = import + production - export - destruction/treatment.
The evaluation of greenhouse gas emissions is based on a calculation of the actual
emission. The actual emission is the emission in the evaluation year, accounting for
the time lapse between consumption and emission. The actual emission includes Danish
emissions from production, from products during their lifetimes, and from waste products.
The actual emissions for the specific areas of application are determined on the grounds
of the following analyses:
Tier 2 Top-down analysis.
In the Tier 2 top-down analysis the emission is determined on the basis of
information on consumption in the various areas of application and calculated or estimated
emissions in the area of application (emission factors).
Tier 2 Bottom-up analysis.
In the bottom-up analysis an estimation is made of the emission from a specific
application area based on information from producers using substances in production and
products; information on import and export of products; information on the technological
developments within the application areas; information on the average amount of greenhouse
gases contained in products; and information on the lifetime of products and the actual
emission during the consumption phase and disposal phase.
The Tier 2 Bottom-up analysis was first employed in the evaluation of emissions
from HFCs, PFCs, and SF6 in 1998, and it covered the following activities /2/:
 | Screening of the market for products in which greenhouse gases are used. |
 | Determination of averages for the content of greenhouse gases per product unit. |
 | Determination of emissions during the lifetime of products and disposal. |
 | Identification of technological development trends that have significance for the
emission of greenhouse gases. |
 | Calculation of import and export on the basis of defined key figures, and information
from Statistics Denmark on foreign trade and industry information. |
The results from this analysis are built on further in the evaluation of the actual
emissions for the present year.
Consumption and emissions of greenhouse gases are wherever possible carried out for
individual substances, even though the consumption of certain HFCs has been very limited.
This has been done to ensure transparency of evaluation in the determination of GWP
values. However, the continued use of a category for "Other HFCs" has been
necessary since not all importers and suppliers have specified records of sales for
individual substances.
Uncertainty varies from substance to substance. Uncertainty is greatest for HFC-134a
due to its widespread application in products that are imported and exported. The greatest
uncertainty in the distribution of substances in the areas of application is judged to
arise from the consumption of HFC-404a and HFC-134a in commercial refrigerators and mobile
refrigerators. The distribution is significant in the differences in the emission
determinations in the short term (approx. five years), but balances out in the long term.
This is because the distribution is only significant for the rate at which emissions are
released.
Appendix 5 shows an overview of all the application areas evaluated with descriptions
of the bases of determination.
The following terms and abbreviations are used throughout this report.
 | User enterprise: A producer that uses ozone-depleting substances or strong
greenhouse gases in connection with production processes in the enterprise. |
 | Emission factor: The factor used in the calculation of the emission from a product
or a production process. |
 | Consumption: Consumption includes the quantity of substances in imports registered
in Denmark during the year of evaluation. These figures are provided by wholesalers and by
producers in Denmark |
 | Importer: Trade enterprises in Denmark that sell the relevant substances on the
Danish market. |
 | KMO: The Danish Refrigeration Installers Environmental Scheme |
 | Stock: The amount of substance contained in products in Denmark. |
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