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Survey and Health Assement of the exposue of 2-year-olds to chemical substances in Consumer Product

Table 3.2 Substances identified in the screening analyses performed for the 10 consumer products in this project. It is stated if the substances are classified in accordance with the list of hazardous substances or the Danish Ministry of the Environment’s self-classification, and if the substances are on the EU candidate list of potential endocrine disruptors

Substance name CAS no. Candidate list of potential endocrine disruptors LIST OF HAZARDOUS SUBSTANCES Classification DANISH MINISTRY OF the ENVIRONMENT self-classification Total exposure (µg/kg bodyweight.)
Diisononyl phthalate, DINP 28553-12-0 Group 2 - - High[8]
Long-chain aliphatic hydrocarbons > C24 N/A       86560.9
Aliphatic hydrocarbons C10-C24 N/A       52704.5
Diethylhexyl phthalate, DEHP 117-81-7 Group 1 REP2;R60-61  - 3244.5
Dibutyl phthalate, DBP 84-74-2 Group 1 REP2;R61 REP3;R62 N;R50  N;R51/53 1872.4
Phthalates with large alkyl groups (unknown) N/A       772.6
1.4-Dioxane-2.5-dione, 3.6-dimethyl- 95-96-5 - - XN;R22 741.9
Butylisobutyl phthalate 17851-53-5 - - N;R51/53 715.6
Limonene 138-86-3 - One of the 26 perfume substances - 631.5
2.4-bis (1-phenylethyl)-phenol 2769-94-0 - - R43 N;R50/53 478.5
Butylated hydroxytoluene (BHT) 128-37-0 - - XN;R22 N;R50/53 376.8
p,p'-Diphenyl methane diisocyanate or Diphenyl methane diisocyanate 101-68-8 or 26447-40-5 - XN;R20 XI;R36/37/38 R42/43 R43 175.7
Total aliphatic hydrocarbons         140.4
Total fluoro compounds (FTOH, PFOA, PFOS, N-Me-FOSE)   Observed hormonal effects     117.8
Phthalate (phthalic acid, butyl-isobutyl ester or phthalic acid, di-isobutyl ester) 17851-53-5 or 84-69-5 - - N;R51/53 or N;R50/53 103.4
2.2'-Oxydiethanol 111-46-6 - XN;R22 - 62.7
2.4-di-tert-butylphenol 96-76-4 - - N;R51/53 61.1
Tert. Butylphenol 98-54-4 Group 2 - R43 56.2
Bisphenol A 80-05-7 Group 1 XI;R37-41 R43 REP3;R62  - 55.8
Isocyanate benzene 103-71-9 - - XN;R22 R43 44.5
Formaldehyde 50-00-0 - T;R23/24/25 C;R34 CARC3;R40 R43  - 40.7
DNOP 117-84-0 - - - 37.5
2.4-Diisocyanato-1-methylbenzene (2.4-Diisocyanate toluene) 584-84-9 - TX;R26 XI;R36/37/38 CARC3;R40 R42/43 R52/53  - 35.5
2-Ethylhexyl fumarate 141-02-6 - - R43 34.5
2,5-Dichloraniline, 2,3-dichloraniline or 1.4-dichloranilline 95-82-3, 608-27-5 or 95-76-1 Group 1 (3,4 dichlor-aniline) T;R23/24/25 XI;R41 R43 N;R50/53  - 27.8
Dipropyl phthalate
Phthalic acid, dipropylester		 131-16-8 Group 3 - - 26.5
Isophorone diisocyanate or equivalent 4098-71-9 - T;R23 XI;R36/37/38 R42/43 N;R51/53  - 17.9
Diglycidyl bisphenol A 1675-54-3 Group 2 XI;R36/38 R43  - 8.6
2-Ethylhexyl maleate 142-16-5 - - R43 7.8
Oleamide (3-Amino-4-methoxy-N-phenyl-benzamide) 301-02-0 - - R43 N;R51/53 7.2
Methyl hydroxyl stearate 141-23-1 - - N;R51/53 6.2
1-Amino-4-hydroxy-2-phenoxy anthraquinone 17418-58-5 - - MUT3;R40 5.4
Aniline 62-53-3 - T;R23/24/25-48/23/24/25 CARC3;R40 XI;R41 R43 MUT3;R68 N;R50  - 5.1
3-Amino-4-methoxy-N-phenylbenzamide 120-35-4 - - MUT3;R40 4.7
2-Butoxy-ethanol phosphate 78-51-3 - - R52/53 4.7
Triphenyl phosphate 115-86-6 - - N;R50/53 3.6
N,N-dimethyl-1-tridecanamin 17373-29-4 - - XN;R22 R43 N;R50/53 3.5
Trimethylpyridine 695-98-7 - - XN;R22 3.0
Methyl (2E,4E,6E)-2-cyan-7-(dimethylamine)-2.4.6-heptatrieneoate and Toluene 2.4-Diiso cyanate 58064-21-4 and 584-84-9 - TX;R26 XI;R36/37/38 CARC3;R40 R42/43 R52/53  - 2.9
1.6-Diisocyanatohexane 822-06-0 - T;R23 XI;R36/37/38 R42/43  - 2.8
Non-identified isocyante     Isocyanates may have the classification: TX;R26 XI;R36/37/38 CARC3;R40 R42/43 R52/53   2.8
DEP 84-66-2 Group 3 - - 2.8
1.2-Dichlorobenzene, 1.3-dichlorobenzene or 1.4-dichlorobenzene 95-50-1, 541-73-1 or 106-46-7 - XN;R22 XI;R36/37/38 N;R50/53 or XN;R22 N;R51/53 or XI;R36 CARC3;R40 N;R50/53 - 2.5
Tinuvin (R) 292 41556-26-7 - - N;R51/53 2.3
Linalool 78-70-6 - One of the 26 perfume substances - 2.1
Bis(2.2.6.6-tetramethyl-4-piperidinyl) sebacate (Tinuvin 770) 52829-07-9 - - N;R51/53 2.0
Triethylenglycol monododecyl ether, Tetraethylenglycol monododecyl ether or Pentaethylenglycol monododecyl ether 3055-94-5, 5274-68-0 or 3055-95-6 - - N;R50/53 1.8
Diisobutyl phthalate (DIBP) 84-69-5 - Approved classification; Rep 2; R-61, Rep 3, R62 N;R50/53 1.8
Melamine 108-78-1 - - R43 1.7
2,3-Dihydroxypropyl hexadecanoic acid ester 542-44-9 - - N;R50/53 1.6
Phenol 108-95-2 - T;R23/24/25 C;R34 XN;R48/20/21/22 MUT3;R68  - 1.6
2-Methoxybenzamine 90-04-0 - CARC2;R45 T;R23/24/25 MUT3;R68  - 1.3
Isophoron or Methyltetrahydro-2H-pyran-2-on 78-59-1 or 106251-09-6 - XN;R21/22 XI;R36/37 CARC3;R40 - 1.1
Kodaflex txib or equivalent 6846-50-0 - - R43 1.1
Toluene 108-88-3 - F;R11 XI;R38 XN;R48/20-65 REP3;R63 R67  - 1.1
Hexadecyl dimethylamine 112-69-6 - - R43 N;R51/53 1.0
2.6-Dibrom-4-nitroaniline or 4,6-Dibromo-2-nitroaniline 827-94-1 or 827-23-6 - - R43 N;R51/53 0.9
Isophoron 78-59-1 - XN;R21/22 XI;R36/37 CARC3;R40  - 0.9
4-Chloro-2.5-dimethoxy-benzamine or 5-Chloro-2,4-dimethoxy-benzamine 6358-64-1 or 97-50-7 - - MUT3;R40 R43 0.8
3-(4-methoxyphenyl)-2-Propenoic acid 2-ethylhexyl ester 5466-77-3 - - N;R50/53 0.8
Styrene 100-42-5 Group 1 R10 XN;R20 XI;R36/38 - 0.8
1-Methylnaphthalene (and isomers) 90-12-0 - - XN;R22 R43 N;R50/53 0.7
6-Chlor-2.4-dinitroaniline 3531-19-9 - - R43 N;R51/53 0.7
2.6-Dichlor-4-nitroaniline 99-30-9 - - R43 N;R51/53 0.6
Butyl octyl phthalate 84-78-6 - - N;R51/53 0.5
DIBP 84-69-5 - -Approved classification: Rep 2; R61; Rep 3; R62 N;R50/53 0.5
Triphenyl phosphite (Stabilizer P 36) 101-02-0 - XI;R36/38 N;R50/53  - 0.5
bis(2-Methylpropyl)-hexanedoic acid ester 141-04-8 - - N;R51/53 0.5
di-p-Tolylsulfone 599-66-6 - - R43 N;R51/53 0.5
1.2-Dibrom-4-nitrobenzene or Tridecyl bromide 5411-50-7 or 765-09-3 - - XN;R22 N;R51/53 0.5
Ethylhexyl chlorformate 24468-13-1 - - XN;R22 0.4
5-Hexene-2-on 109-49-9 - - XN;R22 0.3
Xylene 1330-20-7 - R10 XN;R20/21 XI;R38 - 0.3
2-Brom-4.6-dinitrobenzenamine (2-Brom-4.6-dinitroaniline) 1817-73-8 - - N;R51/53 0.2
Isocyanato benzene or 1H-Benzotriazole 103-71-9 or 95-14-7 - - XN;R22 R43 0.2
Benzaldehyde 100-52-7 - XN;R22 - 0.2
N-(Phenylmethyl)benzenmethanamine 103-49-1 - - XN;R22 0.2
N-butyl-1-butanamine 111-92-2 - R10 XN;R20/21/22  - 0.1
2-(Methylthio)benzothiazole 615-22-5 - - XN;R22 R43 0.1
Phenoxybenzamine 59-96-1 - - MUT3;R40 Carc3;R40 R43 N;R50/53 0.1
Salicylic acid benzyl ester 118-58-1 - One of the 26 perfume substances R43 N;R50/53 0.1
Camphene 79-92-5 - - N;R50/53 0.1
2(3H)-Benzothiazolone 934-34-9 - - XN;R22 0.1
p-Nitroaniline or m-Nitroaniline 100-01-6 or 99-09-2 - T;R23/24/25 R33 R52/53  - 0.1
Dioctyl ether 629-82-3 - - N;R51/53 0.0
2-Mercaptobenzothiazole 149-30-4 - R43 N;R50/53  - 0.0
o-Toluidine 95-53-4 - CARC2;R45 T;R23/25 XI;R36 N;R50 - 0.0

Carc = Carcinogenic, MUT = Mutagenic, Rep = Reproductive toxicity, Xi = Irritant, XN = Harmful, Tx = Very toxic, T = Toxic, N = Dangerous for the environment
R10 Flammable
R20 Harmful by inhalation, R22 Harmful if swallowed, R21/22 Harmful in contact with skin and if swallowed., R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R23 Toxic by inhalation, R23/24/25 Toxic by inhalation, in contact with skin and if swallowed
R26 Very toxic by inhalation
R36 Irritating to eyes, R37 Irritating to respiratory system, R36/37 Irritating to eyes and respiratory system, R36/38 Irritating to eyes and skin R36/37/38 Irritating to eyes, respiratory system and skin
R41 Risk of serious damage to eyes
R40 Limited evidence of a carcinogenic effect, R45 May cause cancer
R42 May cause sensitisation by inhalation, R43 May cause sensitisation by skin contact, R42/43 May cause sensitisation by inhalation and skin contact
R48 Danger of serious damage to health by prolonged exposure
R50 Very toxic to aquatic organisms, R51 Toxic to aquatic organisms, R52 Harmful to aquatic organisms, R50/53 Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment, R51/53 Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment R52/53 Harmful to aquatic organisms; may cause long-term adverse effects in the aquatic environment
R60 May impair fertility, R61 May cause harm to the unborn child, R62 Possible risk of impaired fertility, R63 Possible risk of harm to the unborn child
R67 Vapours may cause drowsiness and dizziness
R68 Possible risk of irreversible effects

[8] The screening analyses could not provide a more precise number because the concentration in the analyses was too high (the apparatus is most precise at low concentrations)

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Version 1.0 November 2009, © Danish Environmental Protection Agency