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Survey and Health Assessment of Products for Interior Car Care
Table 8.1 Time-weighted concentrations of compounds from products
| Substance |
CAS no. |
Limit value (mg/m³)
DWEA 2007 |
Factor volumen |
Weighed amount (g) |
Factor used amount |
Average conc. The first 15 min. (mg/m³) |
Time-weighted concentration
(mg/m³)
Time stated in minutes |
| Product no. 1: Vinyl make-up |
8,3 |
2,5 |
8,1 |
|
15 |
30 |
75 |
195 |
315 |
C4-C7 and C10-C14 aliphatic
hydrocarbons |
|
180** |
|
|
|
90 |
2.8 |
4.5 |
6.5 |
7.8 |
8.4 |
| |
|
|
|
|
|
|
|
|
|
|
|
| Product no. 5: Fabric waterproofing |
8,3 |
4,6 |
17,0 |
|
15 |
30 |
65 |
190 |
310 |
| Butane |
106-97-8 |
1200 |
|
|
|
19 |
0.59 |
1.01 |
1.47 |
1.74 |
1.75 |
| 2-Propanol |
67-63-0 |
490 |
|
|
|
1.2 |
0.04 |
0.06 |
0.07 |
0.09 |
0.10 |
| Ethyl acetate |
141-78-6 |
540 |
|
|
|
14 |
0.44 |
0.65 |
0.86 |
0.95 |
0.96 |
| Heptane1 / propane/ C5-C8 aliphatic hydrocarbons |
142-82-5 |
820 (E) / 1800 / 180 |
|
|
|
223 |
6.9 |
11.7 |
18.5 |
23.4 |
23.5 |
| Butyl acetate |
123-86-4 |
710 |
|
|
|
80 |
2.5 |
3.6 |
4.8 |
5.3 |
5.4 |
| Limonene* 2 |
138-86-3 |
418 |
|
|
|
19 |
0.58 |
0.76 |
0.92 |
0.98 |
0.99 |
| |
|
|
|
|
|
|
|
|
|
|
|
| Product no. 10: Vinyl cleaner |
8,3 |
6,4 |
8,1 |
|
15 |
30 |
65 |
195 |
320 |
| Butane |
106-97-8 |
1200 |
|
|
|
1.5 |
0.05 |
0.10 |
0.17 |
0.21 |
0.21 |
| 2-Propanol |
67-63-0 |
490 |
|
|
|
14 |
0.45 |
0.84 |
1.33 |
1.66 |
1.68 |
| 1-Propanol |
71-23-8 |
500 (H) |
|
|
|
0.2 |
0.01 |
0.01 |
0.02 |
0.03 |
0.03 |
| Limonene* 2 |
138-86-3 |
418 |
|
|
|
0.8 |
0.02 |
0.04 |
0.05 |
0.06 |
0.06 |
| Product no. 24: Glass cleaner |
8,3 |
3,1 |
12,2 |
|
15 |
30 |
60 |
195 |
315 |
| 2-Propanol |
67-63 -0 |
490 |
|
|
|
1.5 |
0.05 |
0.09 |
0.13 |
0.17 |
0.17 |
| 1-Methoxy-2-propanol |
107-98-2 |
185 (E) |
|
|
|
5 |
0.15 |
0.25 |
0.33 |
0.39 |
0.40 |
| 1-butoxy-2-propanol* |
5131-66-8 |
541 |
|
|
|
23 |
1.06 |
1.36 |
1.76 |
2.07 |
2.09 |
| 2-butoxy ethanol |
111-76-2 |
98 (EH) |
|
|
|
11 |
0.34 |
0.55 |
0.83 |
1.08 |
1.09 |
* Indicates substances with a tentative limit value. Tentative limit values are temporary and only advisory limit values.
** The limit value of the Danish Working Environment Authority of 180 mg/m³ applies to petroleum redistilled C9-C14 with < 5% aromatic compounds. The limit value is therefore not fully adequate for the found fractions of aliphatic hydrocarbons, but a precautionary approach has been chosen, i.e. the lowest limit value has been chosen.
E Indicates that there is an EU limit value. The tentative limit value is stated in ppm and converted to mg/m³ according to the instructions in the Danish Working Environment Authority limit value list, 2007.
H Indicates that the substance can be absorbed by the skin.
1 According to the evaporation tests in the box, C5-C8 aliphatic hydrocarbons were measured in large amounts. According to the safety data sheet it contains up 40% heptane and 20-40% butane/propane. It is therefore anticipated that the measured aliphatic hydrocarbons are a mixture of heptane and propane as butane is identified separately. Therefore, it is the limit value of 820 mg/m3 the measured values have to be compared with.
2 The limit value of Limonene covers the D as well as the L version (CAS 138-86-3). D as well as L-Limonene was identified in the analyses. D-Limonene (CAS 5989-27-5) is used as standard for identification.
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Version 1.0 December 2010, © Danish Environmental Protection Agency
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