Oprensning af klorerede opløsningsmidler ved stimuleret reduktiv deklorering - bilagsrapport

Bilag D Produktblad på HRCTM og HRC Primer

MATERIAL SAFETY DATA SHEET

Last Revised: July 1, 2000

Section 1 - Material Identification

Supplier: Applied Power Concepts, Inc.
  411 East Julianna St.
  Anaheim, CA 92801
   
Telephone: (714) 502-1150
Facsimile: (714) 502-2450
   
Chemical Name: Propanoic acid, 2-[2-[2-(2-hydroxy-1-oxopropoxy)-1-oxopropoxy]
  -1-oxopropoxy]-1,2,3-propanetriyl ester
   
Chemical Family: Organic Chemical
   
Trade Name: Glycerol tripolylactate
   


Section 2 - Hazardous Ingredients

CAS #. 201167-72-8

One should anticipate the potential for eye irritation and skin irritation with large scale exposure or in sensitive individuals.


Section 3 - Physical Data

Melting Point: NA    
Boiling Point: ND    
Flash Point: ND    
Density: 1.347    
Solubility: Acetone and DMSO  
Appearance: Pale white semi-solid  
Odor: Not detectable    
Vapor Pressure: None    
       

Section 4 - Fire and Explosion Hazard Data

Extinguishing Media: Carbon Dioxide, Dry Chemical Powder or Appropriate Foam.

Water may be used to keep exposed containers cool.

For large quantities involved in a fire, one should wear full protective clothing and a NIOSH approved self contained breathing apparatus with full face piece operated in the pressure demand or positive pressure mode as for a situation where lack of oxygen and excess heat are present.

 

Section 5 - Toxicological Information

Acute Effects: May be harmful by inhalation, ingestion, or skin absorption.

May cause irritation. To the best of our knowledge, the chemical, physical, and toxicological properties of the glycerol tripolylactate have not been investigated. Listed below are the toxicological information for glycerol and lactic acid.

RTECS#: MA8050000  
          Glycerol  
     
Irritation data: SKN-RBT 500 MG/24H MLD 85JCAE-,207,1986
  EYE-RBT 126 MG MLD BIOFX* 9-4/1970
  EYE-RBT 500 MG/24H MLD 85JCAE-,207,1986
     
Toxicity data: ORL-MUS LD50:4090 MG/KG FRZKAP (6),56,1977
  SCU-RBT LD50:100 MG/KG NIIRDN 6,215,1982
  ORL-RAT LD50:12600 MG/KG FEPRA7 4,142,1945
  IHL-RAT LC50: >570 MG/M3/1H BIOFX* 9-4/1970
  IPR-RAT LD50: 4420 MG/KG RCOCB8 56,125,1987
  IVN-RAT LD50:5566 MG/KG ARZNAD 26,1581,1976
  IPR-MUS LD50: 8700 MG/KG ARZNAD 26,1579,1978
  SCU-MUS LD50:91 MG/KG NIIRDN 6,215,1982
  IVN-MUS LD50: 4250 MG/KG JAPMA8 39,583,1950
  ORL-RBT LD50: 27 GM/KG DMDJAP 31,276,1959
  SKN-RBT LD50:>10GM/KG BIOFX* 9-4/1970
  IVN-RBT LD50: 53 GM/KG NIIRDN 6,215,1982
  ORL-GPG LD50: 7750 MG/KG JIHTAB 23,259,1941

Target Organ data: Behavioral (headache), gastrointestinal (nausea or vomiting), Paternal effects (spermatogenesis, testes, epididymis, sperm duct), effects of fertility (male fertility index, post-implantation mortality).

RTECS#: OD2800000  
Lactic acid  
     
Irritation data: SKN-RBT 5MG/24H SEV 85JCAE -,656,86
  EYE-RBT 750 UG SEV AJOPAA 29,1363,46
     
Toxicity data: ORL-RAT LD50:3543 MG/KG FMCHA2-,C252,91
  SKN-RBT LD50:>2 GM/KG FMCHA2-,C252,91
  ORL-MUS LD50: 4875 MG/KG FAONAU 40,144,67
  ORL-GPG LD50: 1810 MG/KG JIHTAB 23,259,41
  ORL-QAL LD50: >2250 MG/KG FMCHA2-,C252,91

Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See actual entry in RTECS for complete information on lactic acid and glycerol.

 

Section 6 - Health Hazard Data

Handling: Avoid continued contact with skin. Avoid contact with eyes.

In any case of any exposure which elicits a response, a physician should be consulted immediately.

First Aid Procedures: 

Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen.  Call a physician.

Ingestion: No effects expected. Do not give anything to an unconscious person. Call a physician immediately.

Skin Contact: Flush with plenty of water. Contaminated clothing may be washed or dry cleaned normally.

Eye contact: Wash eyes with plenty of water for at least 15 minutes lifting both upper and lower lids. Call a physician.


Section 7 - Reactivity Data

Conditions to Avoid: Strong oxidizing agents, bases and acids Hazardous Polymerization: None known

Further Information: Hydrolyses in water to form Lactic Acid and Glycerol.


Section 8 - Spill, Leak or Accident Procedures

After Spillage or Leakage: Neutralization is not required.

This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber.

Disposal: Laws and regulations for disposal vary widely by locality. Observe all applicable regulations and laws. This material, may be disposed of in solid waste. Material is readily degradable and hydrolyses in several hours.

No requirement for a reportable quantity (CERCLA) of a spill is known.


Section 9 - Special Protection or Handling

Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass containers.

Protective Gloves: Vinyl or Rubber

Eyes: Splash Goggles or Full Face Shield. Area should have approved means of washing eyes.

Ventilation: General exhaust.

Storage: Store in cool, dry, ventilated area. Store in cool, dry, ventilated area.Protect from imcompatible materials.


Section 10 - Other Information

This material will degrade in the environment by hydrolysis to lactic acid and glycerol. Materials containing reactive chemicals should be used only by personnel with appropriate chemical training.

The information contained in this document is the best available to the supplier as of the time of writing. Some possible hazards have been determined by analogy to similar classes of material. No separate tests have been performed on the toxicity of this material. The items in this document are subject to change and clarification as more information becomes available.

Applied Power Concepts, Inc.
411 E. Julianna Street
Anaheim, CA 92801
TEL (714) 502-1150
FAX (714) 502-2450

November 21, 2000

Certificate of Analysis
HRC Primer

Glycerol Polylactate: 50.0%

Lactic Acid: 40.0%

Glycerin: 10.0%

Viscosity: 1,020 Cp

Density: 1.02 g/ml

Solubility: Water Soluble

Note: Lactic acid and glycerin are used as viscosity control agents.