Fate of Pyrethroids in Farmland Ponds

17 Symbols, part II

c Concentration value μg/l
ccal Calculated concentration value μg/l
cd Dissolved substance concentration μg/l
cd,sed Dissolved substance concentration in the sediment pore water μg/l
cd,wc Dissolved substance concentration in the water column μg/l
cs Concentration of sorbed substance μg/kg
cSMLd Dissolved concentration in the surface micro layer μg/l
ctot Total (dissolved + absorbed) substance concentration μg/l
ctot,wc Total substance concentration in the water column μg/l
D Diffusion coefficient m2/h
Dlayer Diffusion coefficient in laminar layer (water column/sediment) m2/h
dosage Amount sprayed per m2 μg/m2
Dsed Diffusion coefficient for sediment pore diffusion m2/h
DSML Diffusion coefficient in the surface micro layer m2/h
DT50 Half life time for degradation d
Dgr Rate of degradation μg/(l h)
f Probability density function -
h Probability density function for both variability and uncertainty -
k First order degradation coefficient (1/h)
Kom Adsorption coefficient in relation to organic matter l/kg
Kd Adsorption coefficient in relation to dry bulk concentration l/kg
kdsus Adsorption coefficient between water and sedimenting solids kg/l
keff Effective 1. order removal constant 1/h
Klayer Resistance of the laminar layer (water column/sediment) m
Kow Octanol/water distribution coefficient -
kvol First order volatilization rate from water surface into the air l/(m2h)
L1 Vertical length scale for substance (S1) diffusion in sediment m
L2 Vertical length scale for substance (S2) diffusion in sediment m
Ldosage The thickness of the sprayed layer on the water surface m
Lh Vertical length scale for sediment surface heterogeneity m
Llayer Thickness of laminar layer between water column and sediment m
LSML Thickness of the SML m
Lwc Water depth (equal water column high) m
M Number of comparisons in the objective function O -
MW Molecular weight g/mol
N Number of parameters in the density distribution -
n Number of replicates -
O Objective function for parameter calibration -
formula Parameter vector in probability density function -
Psat Vapor pressure Pa
R Retention factor i form of the ratio between cd and ctot -
Rate The substance uptake rate between water column and sediment μg/(m2h)
Rmacro,wc Retention factor in the water column due to macroscopic surfaces -
Rsed Retention factor in the sediment -
RSML Retention factor in the surface micro layer -
R,sed Retention factor in the sediment pore water due to the pore walls -
Rsus,wc Retention factor in the water column caused by suspended solids -
S1 Substance 1 μg/l
S2 Substance 2 μg/l
sed Rate of removed substance by sedimentation per unit bottom area μg/(m2 h)
Sw Solubility μg/l
t Time since application of pesticide on the water surface h
vola Volatilization rate from water surface into the air μg/(m2 h)
vsed Sedimentation flux of suspended solids Kg/(m2h)
x Downward distance from water or sediment surface m
formula Density function for each element in the parameter vector ( formula ) -

Greek letters

μ True concentration mean value μg/l
μest Estimated concentration mean value μg/l
σ Standard deviation for concentration measurements μg/l
σhigh Standard deviation for concentration measurements related for high dosage μg/l
σlow Standard deviation for concentration measurements related for low dosage μg/l
θ Volume fraction of water -
ρ Dry bulk density kg/l
formula Parameter vectors for the probability density functions formula -

 



Version 1.0 September 2004, © Danish Environmental Protection Agency