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Survey and release of chemical substances in "slimy" toys 
    
Enclosure C: Headspace analysis results from screening 
Analysis results from headspace analysis at 20C  
| ID no. | 
DK-01, exterior | 
 
| Chemical Technology label | 
30396-1 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Toluene | 
108-88-3 | 
4.2 | 
 
| Hexanal | 
66-25-1 | 
< 0.1 | 
 
| Ethylbenzene | 
100-41-4 | 
1.3 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
0.2 | 
 
  | α Pinene | 
80-56-8 | 
0.1 | 
 
| C10H14-aromatic hydrocarbons | 
- | 
0.5 | 
 
C11-C14 aliphatic hydrocarbons +  Decahydro naphthalenes 
 methyl decahydronaphthalenes 
 dimethyl decahydronaphthalenes
 | 
- | 
94 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
DK-02, exterior | 
 
| Chemical Technology label | 
30396-2 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Toluene | 
108-88-3 | 
18 | 
 
| Hexanal | 
66-25-1 | 
0.6 | 
 
| Ethylbenzene | 
100-41-4 | 
11 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
2.8 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
0.6 | 
 
  | α Pinene | 
80-56-8 | 
3.4 | 
 
| β Pinene | 
127-91-3 | 
0.6 | 
 
| 3-Carene | 
13466-78-9 | 
1.4 | 
 
| 2-Ethyl-1-hexanol | 
104-76-7 | 
0.6 | 
 
| d-Limonene | 
5989-27-5 | 
0.9 | 
 
| Aliphatic hydrocarbons etc. | 
- | 
60 | 
 
 
 
Comments
 The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount. 
| ID no. | 
DK-03, exterior | 
 
| Chemical Technology label | 
30396-3 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Toluene | 
108-88-3 | 
5.9 | 
 
| Hexanal | 
66-25-1 | 
0.1 | 
 
| Ethylbenzene | 
100-41-4 | 
2.2 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
0.4 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
0.1 | 
 
| α Pinene | 
80-56-8 | 
0.7 | 
 
| β Pinene | 
127-91-3 | 
0.1 | 
 
| 3-Carene | 
13466-78-9 | 
0.4 | 
 
| 2-Ethyl-1-hexanol | 
104-76-7 | 
0.2 | 
 
| d-Limonene | 
5989-27-5 | 
0.2 | 
 
C11-C14 aliphatic hydrocarbons + decahydro naphthalenes  methyl decahydronaphthalenes 
 dimethyl decahydronaphthalenes
 | 
- | 
90 | 
 
 
 
Comments
 The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount. 
| ID no. | 
K-01, exterior | 
 
| Chemical Technology label | 
30396-5 A | 
 
| Component | 
CAS no. | 
% m/m | 
 
| C7H14 and C7H16 aliphatic hydrocarbons | 
- | 
1.8 | 
 
| Toluene | 
108-88-3 | 
66 | 
 
| C8 + C9 aliphatic hydrocarbons | 
- | 
8.1 | 
 
| Ethylbenzene | 
100-41-4 | 
13 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
2.9 | 
 
| α Pinene | 
80-56-8 | 
3.8 | 
 
| C9H12 + C10H14 aromatic hydrocarbons | 
- | 
3.3 | 
 
| Eucalyptol (C10H18O) | 
470-82-6 | 
0.2 | 
 
| C10H16 | 
- | 
1.0 | 
 
| ID no. | 
K-01, liquid | 
 
| Chemical Technology label | 
30396-5 B | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Toluene | 
108-88-3 | 
70 | 
 
| Ethylbenzene | 
100-41-4 | 
6 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
24 | 
 
 
 
Comments
 The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount. 
| ID no. | 
BR-01, exterior | 
 
| Chemical Technology label | 
30396-7 A | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Toluene | 
108-88-3 | 
7.1 | 
 
| Hexanal | 
66-25-1 | 
0.3 | 
 
| C8H16 | 
e.g. 1678-91-7 | 
1.3 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
74 | 
 
| o-Xylene | 
95-47-5 | 
 
| C9H12 aromatic hydrocarbons | 
- | 
5.9 | 
 
| 3-Carene | 
80-56-8 | 
0.2 | 
 
| C11-C14 aliphatic hydrocarbons | 
- | 
10.8 | 
 
| ID no. | 
BR-01, liquid | 
 
| Chemical Technology label | 
30396-7 B | 
 
| Component | 
CAS no. | 
% m/m | 
 
| 1.2-Propandiol | 
4254-15-3 | 
7 | 
 
| Toluene | 
108-88-3 | 
8 | 
 
| Ethylbenzene | 
100-41-4 | 
79 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| C9H12 aromatic hydrocarbons | 
- | 
3 | 
 
| C10-C14 aliphatic hydrocarbons | 
- | 
3 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
F-01, exterior | 
 
| Chemical Technology label | 
30396-8 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| 2-Ethylbutanal | 
97-96-1 | 
0.2 | 
 
| Butanal | 
123-72-8 | 
0.2 | 
 
| Butanol | 
71-36-3 | 
0.2 | 
 
| Toluene | 
108-88-3 | 
6.0 | 
 
| C8H16 aliphatic hydrocarbons | 
- | 
0.4 | 
 
| Ethylbenzene | 
100-41-4 | 
4.2 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanol | 
108-93-0 | 
0.3 | 
 
| Cyclohexanone | 
108-94-1 | 
0.4 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
1.8 | 
 
| α Pinene | 
80-56-8 | 
0.3 | 
 
| C9H12-aromatic hydrocarbons | 
  | 
0.6 | 
 
| 3-Carene | 
13466-78-9 | 
0.1 | 
 
| C10H14-aromatic hydrocarbons | 
- | 
0.6 | 
 
| C11-C14 aliphatic hydrocarbons | 
- | 
85 | 
 
| C10H16O | 
e.g. 5948-04-9 | 
0.2 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
TO-01, exterior | 
 
| Chemical Technology label | 
30396-9 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| 2-Ethylbutanal | 
97-96-1 | 
2.4 | 
 
| Butanal | 
123-72-8 | 
0.6 | 
 
| 3-Methylbutanal | 
590-86-3 | 
0.3 | 
 
| 1-Methoxy-2-propanol | 
107-98-2 | 
1.0 | 
 
| Toluene | 
108-88-3 | 
2.3 | 
 
| Hexanal | 
66-25-1 | 
2.6 | 
 
| C9H20 aliphatic hydrocarbons | 
- | 
5.3 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
0.5 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
63 | 
 
| 2-Cyclohexen-1-one | 
930-68-7 | 
0.1 | 
 
| 2-Heptenal | 
18829-55-5 | 
0.5 | 
 
| 2-Okten-1-ol | 
18409-17-1 | 
0.6 | 
 
| Octanal | 
124-13-0 | 
1.2 | 
 
| 2-Ethyl-1-hexanol | 
104-76-7 | 
3.6 | 
 
| C10-C14 aliphatic hydrocarbons | 
- | 
16 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
TO-02, exterior | 
 
| Chemical Technology label | 
30396-10 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| 1-Propanol | 
71-23-8 | 
1.1 | 
 
| Butanal | 
123-72-8 | 
0.7 | 
 
| Toluene | 
108-88-3 | 
17 | 
 
| N,N-Dimethyl formamide | 
68-12-2 | 
0.4 | 
 
| Octane | 
111-65-9 | 
1.1 | 
 
| Hexanal | 
66-25-1 | 
1.5 | 
 
| Ethylbenzene | 
100-41-4 | 
10 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| n-Butyl ether | 
142-96-1 | 
1.5 | 
 
| Styrene | 
100-42-5 | 
5.1 | 
 
| Cyclohexanone | 
108-94-1 | 
30 | 
 
| C9H12-aromater | 
- | 
7.7 | 
 
| Octanal | 
124-13-0 | 
0.7 | 
 
| 2-Ethyl-1-hexanol | 
104-76-7 | 
7.7 | 
 
| C10H14-aromatic hydrocarbons | 
- | 
15 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
TO-03, lip-gloss | 
 
| Chemical Technology label | 
30396-11 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| 2-Propanol | 
67-63-0 | 
20 | 
 
| 2-Methyl-1-propanol | 
78-83-1 | 
6.9 | 
 
| Toluene | 
108-88-3 | 
30 | 
 
| Ethylbenzene | 
100-41-4 | 
16 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene  | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
2.3 | 
 
| α Pinene | 
80-56-8 | 
1.1 | 
 
| 3-Carene | 
13466-78-9 | 
2.3 | 
 
| 3.3.5-Trimethylcyclohexen-1-ol | 
e.g. 78-59-1 | 
5.7 | 
 
| C10+C11+C12+C13 aliphatic hydrocarbons | 
- | 
16 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
TO-03, gel | 
 
| Chemical Technology label | 
30396-11 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| 1-Propanol | 
71-23-8 | 
0.7 | 
 
| 2-Methyl-1-propanol | 
78-83-1 | 
1.3 | 
 
| 1-Butanol | 
71-36-3 | 
2.6 | 
 
| 1-Methoxy-2-propanol | 
107-98-2 | 
0.4 | 
 
| 2-Propenoic acid 2 methyl-methyl ester (methyl-methacrylate) | 
80-62-6 | 
7.2 | 
 
| Toluene | 
108-88-3 | 
6.9 | 
 
| 1.2-Propandiol | 
4254-15-3 | 
66 | 
 
| Ethylbenzene | 
100-41-4 | 
0.7 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
1.0 | 
 
| o-Xylene | 
95-47-5 | 
1.0 | 
 
| Styrene | 
100-42-5 | 
2.0 | 
 
| Cyclohexanone | 
108-94-1 | 
3.3 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
0.7 | 
 
| α Pinene | 
80-56-8 | 
0.4 | 
 
| D-Limonene | 
5989-27-5 | 
0.4 | 
 
| 3.3.5-Trimethylcyclohexen-1-ol | 
e.g. 78-59-1 | 
2.3 | 
 
| 2-Phenoxy ethanol | 
122-99-6 | 
3.9 | 
 
  
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
G-01, exterior | 
 
| Chemical Technology label | 
30396-12 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Butandiol + alcohol e.g. ethanol, 2-propanol | 
110-63-4 + e.g. 64-17-5, 67-63-0
  | 
35 | 
 
| Butanal | 
123-72-8 | 
2.8 | 
 
| Butanol | 
  | 
1.0 | 
 
| Toluene | 
108-88-3 | 
10 | 
 
| Hexanal | 
66-25-1 | 
0.4 | 
 
| Ethylbenzene | 
100-41-4 | 
39 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
3.9 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
0.6 | 
 
| α Pinene | 
80-56-8 | 
0.7 | 
 
| Benzaldehyde | 
100-52-7 | 
1.3 | 
 
| 3-Carene | 
13466-78-9 | 
0.3 | 
 
| D-Limonene | 
5989-27-5 | 
0.4 | 
 
| C10H14-aromatic hydrocarbons | 
- | 
3.8 | 
 
| Nonanal | 
124-19-6 | 
0.5 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
K-03, exterior | 
 
| Chemical Technology label | 
30396-13 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Butandiol + alcohol, e.g. ethanol, 2-propanol | 
110-63-4+  
  e.g. 64-17-5, 67-63-0 | 
55 | 
 
| Ethyl acetate | 
141-78-6 | 
1.9 | 
 
| Tetrahydrofuran | 
109-99-9 | 
3.4 | 
 
| Toluene | 
108-88-3 | 
7.2 | 
 
| Hexanal | 
66-25-1 | 
1.8 | 
 
| Ethylbenzene | 
100-41-4 | 
16 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| Cyclohexanone | 
108-94-1 | 
2.5 | 
 
| C10-C13 aliphatic hydro carbons | 
- | 
15 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
TI-01, exterior | 
 
| Chemical Technology label | 
30396-16 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Butandiol + alcohol, e.g. ethanol, 2-propanol | 
110-63-4+  
  e.g. 64-17-5, 67-63-0 | 
4.3 | 
 
| 2-Butanon | 
78-93-3 | 
2.3 | 
 
| Tetrahydrofuran | 
109-99-9 | 
0.4 | 
 
| Butanol | 
71-36-3 | 
3.0 | 
 
| 2-Pentanon | 
107-87-9 | 
1.1 | 
 
| C7+C8+C9 aliphatic hydrocarbons | 
  | 
29 | 
 
| Toluene | 
108-88-3 | 
10 | 
 
| 2-Hexanone | 
591-78-6 | 
2.7 | 
 
| Hexanal | 
66-25-1 | 
0.7 | 
 
| Ethylbenzene | 
100-41-4 | 
14 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| n-Butyl ether | 
142-96-1 | 
2.2 | 
 
| 2-Heptanon | 
110-43-0 | 
3.3 | 
 
| Heptanal | 
111-71-7 | 
1.3 | 
 
| α Pinene | 
80-56-8 | 
1.2 | 
 
| C9H12-aromatoc compounds (sum) | 
  | 
4.5 | 
 
| 2-Oktanon | 
111-13-7 | 
2.4 | 
 
| Octanal | 
124-13-0 | 
2.1 | 
 
| 3-Carene | 
13466-78-9 | 
0.6 | 
 
| Nonanol | 
143-08-8 | 
1.1 | 
 
| C11H22 | 
  | 
5.0 | 
 
| Nonanal | 
124-19-6 | 
1.3 | 
 
| 3.5.5-Trimethylcyclohexen-1-one | 
78-59-1 | 
1.2 | 
 
| 2-Decanon | 
693-54-9 | 
0.4 | 
 
| Decanal | 
112-31-2 | 
0.4 | 
 
| Undecanal | 
112-44-7 | 
0.9 | 
 
| Dodecanal | 
112-54-9 | 
0.8 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
TI-01, liquid | 
 
| Chemical Technology label | 
30396-16,B | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Dichloromethane | 
75-09-2 | 
3 | 
 
| 1.1-Dimethoxypropan | 
4744-10-9 | 
5 | 
 
| 2-Butanon | 
78-93-3 | 
9 | 
 
| Tetrahydrofuran | 
109-99-9 | 
1 | 
 
| 2-Pentanon | 
107-87-9 | 
9 | 
 
| Toluene | 
108-88-3 | 
10 | 
 
| 2-Hexanone | 
591-78-6 | 
8 | 
 
| Ethylbenzene | 
100-41-4 | 
9 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| n-Butyl ether | 
142-96-1 | 
2 | 
 
| 3-Heptanon | 
106-35-4 | 
1 | 
 
| 2-Heptanon | 
110-43-0 | 
10 | 
 
| Cyclohexanone | 
108-94-1 | 
1 | 
 
| Heptanal | 
111-71-7 | 
3 | 
 
| Heptanol | 
53535-33-4 | 
3 | 
 
| 2-Oktanon | 
111-13-7 | 
6 | 
 
| Octanal | 
124-13-0 | 
5 | 
 
| Nonanol | 
143-08-8 | 
1 | 
 
| C11H22 | 
- | 
7 | 
 
| Nonanal | 
124-19-6 | 
3 | 
 
| 3.5.5-Trimethylcyclohexen-1-one | 
78-59-1 | 
3 | 
 
| Decanal | 
112-31-2 | 
1 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of total VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
R-01, exterior | 
 
| Chemical Technology label | 
30396-17 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Ethanol | 
64-17-5 | 
0.2 | 
 
2.6-Dimethyl-1.4-dioxan (C6H12O2)  or similar
 | 
e.g. 10138-17-7 | 
0.9 | 
 
| Toluene | 
108-88-3 | 
1.0 | 
 
| Ethylbenzene | 
100-41-4 | 
0.8 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
0.8 | 
 
| C11-C14-aliphatic hydrocarbons | 
- | 
96 | 
 
| ID no. | 
R-01, liquid | 
 
| Chemical Technology label | 
30396-17 B | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Ethanol | 
64-17-5 | 
27 | 
 
| Cyclohexanone | 
108-94-1 | 
6 | 
 
| 2-Butoxy-ethanol | 
111-76-2 | 
66 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
| ID no. | 
A-01, exterior | 
 
| Chemical Technology label | 
30396-18 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| C6H12O2 | 
e.g. 21460-36-6 +  
  10138-17-7 | 
1.7 | 
 
| Toluene | 
108-88-3 | 
2.1 | 
 
| Ethylbenzene | 
100-41-4 | 
45 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
| C9H12 aromatic hydrocarbons | 
- | 
3.2 | 
 
| 1-Propenylbenzen | 
873-66-5 | 
  | 
 
| C10 – C16 aliphatic hydrocarbons | 
- | 
46 | 
 
| ID no. | 
A-01, liquid | 
 
| Chemical Technology label | 
30396-18 | 
 
| Component | 
CAS no. | 
% m/m | 
 
| Ethylbenzene | 
100-41-4 | 
100 | 
 
| m-, p-Xylene | 
108-88-3/106-42-3 | 
 
| o-Xylene | 
95-47-5 | 
 
 
 
Comments
The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.  
  
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 Version 1.0 March 2006, © Danish Environmental Protection Agency 
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