Survey and release of chemical substances in "slimy" toys

Enclosure C: Headspace analysis results from screening

Analysis results from headspace analysis at 20C

ID no. DK-01, exterior
Chemical Technology label 30396-1
Component CAS no. % m/m
Toluene 108-88-3 4.2
Hexanal 66-25-1 < 0.1
Ethylbenzene 100-41-4 1.3
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 0.2
α Pinene 80-56-8 0.1
C10H14-aromatic hydrocarbons - 0.5
C11-C14 aliphatic hydrocarbons +
Decahydro naphthalenes
methyl decahydronaphthalenes
dimethyl decahydronaphthalenes
- 94

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. DK-02, exterior
Chemical Technology label 30396-2
Component CAS no. % m/m
Toluene 108-88-3 18
Hexanal 66-25-1 0.6
Ethylbenzene 100-41-4 11
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 2.8
2-Butoxy-ethanol 111-76-2 0.6
α Pinene 80-56-8 3.4
β Pinene 127-91-3 0.6
3-Carene 13466-78-9 1.4
2-Ethyl-1-hexanol 104-76-7 0.6
d-Limonene 5989-27-5 0.9
Aliphatic hydrocarbons etc. - 60

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.
ID no. DK-03, exterior
Chemical Technology label 30396-3
Component CAS no. % m/m
Toluene 108-88-3 5.9
Hexanal 66-25-1 0.1
Ethylbenzene 100-41-4 2.2
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 0.4
2-Butoxy-ethanol 111-76-2 0.1
α Pinene 80-56-8 0.7
β Pinene 127-91-3 0.1
3-Carene 13466-78-9 0.4
2-Ethyl-1-hexanol 104-76-7 0.2
d-Limonene 5989-27-5 0.2
C11-C14 aliphatic hydrocarbons + decahydro naphthalenes
methyl decahydronaphthalenes
dimethyl decahydronaphthalenes
- 90

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.
ID no. K-01, exterior
Chemical Technology label 30396-5 A
Component CAS no. % m/m
C7H14 and C7H16 aliphatic hydrocarbons - 1.8
Toluene 108-88-3 66
C8 + C9 aliphatic hydrocarbons - 8.1
Ethylbenzene 100-41-4 13
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 2.9
α Pinene 80-56-8 3.8
C9H12 + C10H14 aromatic hydrocarbons - 3.3
Eucalyptol (C10H18O) 470-82-6 0.2
C10H16 - 1.0
ID no. K-01, liquid
Chemical Technology label 30396-5 B
Component CAS no. % m/m
Toluene 108-88-3 70
Ethylbenzene 100-41-4 6
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 24

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.
ID no. BR-01, exterior
Chemical Technology label 30396-7 A
Component CAS no. % m/m
Toluene 108-88-3 7.1
Hexanal 66-25-1 0.3
C8H16 e.g. 1678-91-7 1.3
m-, p-Xylene 108-88-3/106-42-3 74
o-Xylene 95-47-5
C9H12 aromatic hydrocarbons - 5.9
3-Carene 80-56-8 0.2
C11-C14 aliphatic hydrocarbons - 10.8
ID no. BR-01, liquid
Chemical Technology label 30396-7 B
Component CAS no. % m/m
1.2-Propandiol 4254-15-3 7
Toluene 108-88-3 8
Ethylbenzene 100-41-4 79
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
C9H12 aromatic hydrocarbons - 3
C10-C14 aliphatic hydrocarbons - 3

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. F-01, exterior
Chemical Technology label 30396-8
Component CAS no. % m/m
2-Ethylbutanal 97-96-1 0.2
Butanal 123-72-8 0.2
Butanol 71-36-3 0.2
Toluene 108-88-3 6.0
C8H16 aliphatic hydrocarbons - 0.4
Ethylbenzene 100-41-4 4.2
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanol 108-93-0 0.3
Cyclohexanone 108-94-1 0.4
2-Butoxy-ethanol 111-76-2 1.8
α Pinene 80-56-8 0.3
C9H12-aromatic hydrocarbons   0.6
3-Carene 13466-78-9 0.1
C10H14-aromatic hydrocarbons - 0.6
C11-C14 aliphatic hydrocarbons - 85
C10H16O e.g. 5948-04-9 0.2

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. TO-01, exterior
Chemical Technology label 30396-9
Component CAS no. % m/m
2-Ethylbutanal 97-96-1 2.4
Butanal 123-72-8 0.6
3-Methylbutanal 590-86-3 0.3
1-Methoxy-2-propanol 107-98-2 1.0
Toluene 108-88-3 2.3
Hexanal 66-25-1 2.6
C9H20 aliphatic hydrocarbons - 5.3
m-, p-Xylene 108-88-3/106-42-3 0.5
o-Xylene 95-47-5
Cyclohexanone 108-94-1 63
2-Cyclohexen-1-one 930-68-7 0.1
2-Heptenal 18829-55-5 0.5
2-Okten-1-ol 18409-17-1 0.6
Octanal 124-13-0 1.2
2-Ethyl-1-hexanol 104-76-7 3.6
C10-C14 aliphatic hydrocarbons - 16

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. TO-02, exterior
Chemical Technology label 30396-10
Component CAS no. % m/m
1-Propanol 71-23-8 1.1
Butanal 123-72-8 0.7
Toluene 108-88-3 17
N,N-Dimethyl formamide 68-12-2 0.4
Octane 111-65-9 1.1
Hexanal 66-25-1 1.5
Ethylbenzene 100-41-4 10
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
n-Butyl ether 142-96-1 1.5
Styrene 100-42-5 5.1
Cyclohexanone 108-94-1 30
C9H12-aromater - 7.7
Octanal 124-13-0 0.7
2-Ethyl-1-hexanol 104-76-7 7.7
C10H14-aromatic hydrocarbons - 15

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. TO-03, lip-gloss
Chemical Technology label 30396-11
Component CAS no. % m/m
2-Propanol 67-63-0 20
2-Methyl-1-propanol 78-83-1 6.9
Toluene 108-88-3 30
Ethylbenzene 100-41-4 16
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 2.3
α Pinene 80-56-8 1.1
3-Carene 13466-78-9 2.3
3.3.5-Trimethylcyclohexen-1-ol e.g. 78-59-1 5.7
C10+C11+C12+C13 aliphatic hydrocarbons - 16

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. TO-03, gel
Chemical Technology label 30396-11
Component CAS no. % m/m
1-Propanol 71-23-8 0.7
2-Methyl-1-propanol 78-83-1 1.3
1-Butanol 71-36-3 2.6
1-Methoxy-2-propanol 107-98-2 0.4
2-Propenoic acid 2 methyl-methyl ester (methyl-methacrylate) 80-62-6 7.2
Toluene 108-88-3 6.9
1.2-Propandiol 4254-15-3 66
Ethylbenzene 100-41-4 0.7
m-, p-Xylene 108-88-3/106-42-3 1.0
o-Xylene 95-47-5 1.0
Styrene 100-42-5 2.0
Cyclohexanone 108-94-1 3.3
2-Butoxy-ethanol 111-76-2 0.7
α Pinene 80-56-8 0.4
D-Limonene 5989-27-5 0.4
3.3.5-Trimethylcyclohexen-1-ol e.g. 78-59-1 2.3
2-Phenoxy ethanol 122-99-6 3.9

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. G-01, exterior
Chemical Technology label 30396-12
Component CAS no. % m/m
Butandiol + alcohol e.g. ethanol, 2-propanol 110-63-4 + e.g. 64-17-5, 67-63-0
35
Butanal 123-72-8 2.8
Butanol   1.0
Toluene 108-88-3 10
Hexanal 66-25-1 0.4
Ethylbenzene 100-41-4 39
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 3.9
2-Butoxy-ethanol 111-76-2 0.6
α Pinene 80-56-8 0.7
Benzaldehyde 100-52-7 1.3
3-Carene 13466-78-9 0.3
D-Limonene 5989-27-5 0.4
C10H14-aromatic hydrocarbons - 3.8
Nonanal 124-19-6 0.5

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. K-03, exterior
Chemical Technology label 30396-13
Component CAS no. % m/m
Butandiol + alcohol, e.g. ethanol, 2-propanol 110-63-4+
e.g. 64-17-5, 67-63-0
55
Ethyl acetate 141-78-6 1.9
Tetrahydrofuran 109-99-9 3.4
Toluene 108-88-3 7.2
Hexanal 66-25-1 1.8
Ethylbenzene 100-41-4 16
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
Cyclohexanone 108-94-1 2.5
C10-C13 aliphatic hydro carbons - 15

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. TI-01, exterior
Chemical Technology label 30396-16
Component CAS no. % m/m
Butandiol + alcohol, e.g. ethanol, 2-propanol 110-63-4+
e.g. 64-17-5, 67-63-0
4.3
2-Butanon 78-93-3 2.3
Tetrahydrofuran 109-99-9 0.4
Butanol 71-36-3 3.0
2-Pentanon 107-87-9 1.1
C7+C8+C9 aliphatic hydrocarbons   29
Toluene 108-88-3 10
2-Hexanone 591-78-6 2.7
Hexanal 66-25-1 0.7
Ethylbenzene 100-41-4 14
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
n-Butyl ether 142-96-1 2.2
2-Heptanon 110-43-0 3.3
Heptanal 111-71-7 1.3
α Pinene 80-56-8 1.2
C9H12-aromatoc compounds (sum)   4.5
2-Oktanon 111-13-7 2.4
Octanal 124-13-0 2.1
3-Carene 13466-78-9 0.6
Nonanol 143-08-8 1.1
C11H22   5.0
Nonanal 124-19-6 1.3
3.5.5-Trimethylcyclohexen-1-one 78-59-1 1.2
2-Decanon 693-54-9 0.4
Decanal 112-31-2 0.4
Undecanal 112-44-7 0.9
Dodecanal 112-54-9 0.8

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. TI-01, liquid
Chemical Technology label 30396-16,B
Component CAS no. % m/m
Dichloromethane 75-09-2 3
1.1-Dimethoxypropan 4744-10-9 5
2-Butanon 78-93-3 9
Tetrahydrofuran 109-99-9 1
2-Pentanon 107-87-9 9
Toluene 108-88-3 10
2-Hexanone 591-78-6 8
Ethylbenzene 100-41-4 9
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
n-Butyl ether 142-96-1 2
3-Heptanon 106-35-4 1
2-Heptanon 110-43-0 10
Cyclohexanone 108-94-1 1
Heptanal 111-71-7 3
Heptanol 53535-33-4 3
2-Oktanon 111-13-7 6
Octanal 124-13-0 5
Nonanol 143-08-8 1
C11H22 - 7
Nonanal 124-19-6 3
3.5.5-Trimethylcyclohexen-1-one 78-59-1 3
Decanal 112-31-2 1

Comments

The stated % m/m is equivalent to the percentage part of total VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. R-01, exterior
Chemical Technology label 30396-17
Component CAS no. % m/m
Ethanol 64-17-5 0.2
2.6-Dimethyl-1.4-dioxan (C6H12O2)
or similar
e.g. 10138-17-7 0.9
Toluene 108-88-3 1.0
Ethylbenzene 100-41-4 0.8
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
2-Butoxy-ethanol 111-76-2 0.8
C11-C14-aliphatic hydrocarbons - 96
ID no. R-01, liquid
Chemical Technology label 30396-17 B
Component CAS no. % m/m
Ethanol 64-17-5 27
Cyclohexanone 108-94-1 6
2-Butoxy-ethanol 111-76-2 66

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

ID no. A-01, exterior
Chemical Technology label 30396-18
Component CAS no. % m/m
C6H12O2 e.g. 21460-36-6 +
10138-17-7
1.7
Toluene 108-88-3 2.1
Ethylbenzene 100-41-4 45
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5
C9H12 aromatic hydrocarbons - 3.2
1-Propenylbenzen 873-66-5  
C10 – C16 aliphatic hydrocarbons - 46
ID no. A-01, liquid
Chemical Technology label 30396-18
Component CAS no. % m/m
Ethylbenzene 100-41-4 100
m-, p-Xylene 108-88-3/106-42-3
o-Xylene 95-47-5

Comments

The stated % m/m is equivalent to the percentage part of totally collected VOC-content of the component, assuming that all detected components have the same response for the same amount.

 



Version 1.0 March 2006, © Danish Environmental Protection Agency