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Survey of chemical substances in toys for animals
Appendix C
1 Survey of analyses
| Analysis |
Items |
Method |
Samples |
| Phthalate determination |
PVC with phthalate |
GC/MS |
2, 5, 7, 11, 13, 18, 19, 23, 30, 33, 36, 41, 49 |
| Screening, heavy metals |
PVC |
XRF |
2, 5, 7, 11, 13, 18, 19, 23, 30, 33, 36, 41, 49 |
| Migration, heavy metals |
PVC |
EN 71-3 |
Number and items depend on the screening |
| Tin content |
Transparent PVC |
XRF |
13, 19 |
| Cr/Cd |
Yellow/orange/red colours in latex, natural rubber etc. |
XRF |
1, 12, 20, 21, 24, 26, 27, 34, 48 |
| Br (flame retardants) |
Textiles and fur |
XRF |
3, 6, 8, 9, 16, 18, 24, 2 * 31 (turtle + egg), 32, 35, 36, 37, 45, 47 |
| Chromate (Cr VI) |
Fur animal |
(EN420) |
28, 39, 43 |
| Screening, organic compounds |
CH-elastomer |
GC/MS Headspace |
1, 4, 7, 12, 14, 15, 20, 21, 22, 24, 26, 27, 34, 38, 40, 44, 46, 48, 50 |
| Quantification of organic compounds |
Depends on the screening |
Depends on substances |
Depends on the screening
Estimate approximately
10 pieces |
| Azo dyes
Screening
|
Strongly coloured textiles |
(staining) EN ISO 105-E04 |
3, 3 x 16, 31, 32 |
| Azo dyes |
Strongly coloured textiles |
EN 14362-1 og –2:2003 |
Depends on the screening |
| Formaldehyde |
Textiles + filling |
EN ISO 14184-1 |
3, 6, 8, 9, 16, 18, 24, 2 * 31 (turtle + egg), 32, 35, 36, 37, 45, 47 + filling
: 3, 16, 24, 31 |
| Characterisation of smell |
CH-elastomer |
Possibly GC/MS headspace |
34 |
| Mercaptobenzothiazol, etc. |
Latex/rubber |
HPLC after watery extraction |
7, 21, 26, 27, 34, 40, 46, 48, 50 |
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Version 1.0 June 2005, © Danish Environmental Protection Agency
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